We study inclusive dijet azimuthal decorrelations in proton-proton collisions at the CERN LHC invoking the hypothesis of parton Reggeization in t-channel exchanges at high energies. In the parton Reggeization approach, the main contribution to the azimuthal angle difference between the two most energetic jets is due to the Reggeon-Reggeon-particle-particle scattering, when the fusion of two Reggeized gluons into a pair of Yang-Mills gluons dominates. Using a high-energy factorization scheme with the Kimber-Martin-Ryskin unintegrated parton distribution functions and the Fadin-Lipatov effective vertices we obtain good agreement of our calculations with recent measurements by the ATLAS and CMS Collaborations at the CERN LHC.