Multi-solution problems extensively exist in practice. Particularly, the traveling salesman problem (TSP) may possess multiple shortest tours, from which travelers can choose one according to their specific requirements. However, very few efforts have been devoted to the multi-solution problems in the discrete domain. In order to fill this research gap and to effectively tackle the multi-solution TSP, we propose a niching memetic algorithm in this article. The proposed algorithm is characterized by a niche preservation technique to enable the parallel search of multiple optimal solutions; an adaptive neighborhood strategy to balance the exploration and exploitation; a critical edge-aware method to provide effective guidance to the reproduction; and a selective local search strategy to improve the search efficiency. To evaluate the performance of the proposed algorithm, we conduct comprehensive experiments on a recently published multi-solution optimization test suite. The experimental results show that our algorithm outperforms other compared algorithms. Furthermore, the proposed algorithm is adopted to tackle problems from the well-known TSPLIB library to obtain a set of distinct but good solutions.