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Wang, Bin; Nan, Zi-Ang; Liu, Jin; Lu, Zi-Xiu; Wang, Wei; Zhuo, Zhu; Li, Guo-Ling; Huang, You-Gui
Molecules (Basel, Switzerland), 06/2023, Letnik: 28, Številka: 13Journal Article
Single-crystal-to-single-crystal metalation of organic ligands represents a novel method to prepare metal-organic complexes, but remains challenging. Herein, a hierarchical self-assembly {(H L )·(N(C H ) ) ·(ClO ) ·(H O) } ( ) (L = tris(2-benzimidazolylmethyl) amine) consisting of -stacked cubes which are assembled from eight partially protonated L ligands is obtained. By soaking the crystals of compound in the aqueous solution of Co(SCN) , the ligands coordinate with Co ions stoichiometrically and ClO exchange with SCN via single-crystal-to-single-crystal transformation, leading to {(CoSCNL ) ·(NC H ) ·(SCN) ·(H O) } ( ).
