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  • gem-Dimethyl 4-Pentenyl Gly...
    Fortin, Michael; Kaplan, Justin; Pham, Khoa; Kirk, Sharon; Andrade, Rodrigo B

    Organic letters, 08/2009, Letnik: 11, Številka: 16
    Journal Article

    Two classes of gem-dimethyl 4-n-pentenyl glycosides (i.e., C2-series and C3-series) have been prepared and studied in both the glycosylation and hydrolysis manifolds utilizing NBS as the sole stoichiometric activator. These novel glycosylating agents, which are analogues of Fraser-Reid’s 4-n-pentenyl glycosyl donors, show increased reactivity in side-by-side studies by virtue of the gem-dimethyl effect.