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Kraft, Steven J; Sánchez, Raúl Hernández; Hock, Adam S
ACS catalysis, 05/2013, Letnik: 3, Številka: 5Journal Article
A single-site, iron catecholate-containing porous organic polymer was prepared and utilized as a stable and remarkably active catalyst for the hydrosilylation of ketones and aldehydes. In some instances, catalyst loadings of 0.043–2.1 mol % Fe were sufficient for complete hydrosilylation of aldehydes and ketones within 15 min at room temperature. The catalyst can be recycled at least three times without a drop in catalytic activity. This system is an example of an immobilized homogeneous catalyst with no homogeneous analogue.
