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  • Synthesis of Superhard and ...
    Blank, Vladimir D.; Buga, Sergei G.; Dubitsky, Gennadi A.; Serebryanaya, Nadejda R.; Prokhorov, Vyatcheslav M.; Mavrin, Boris N.; Denisov, Victor N.; Chernozatonskii, Leonid A.; Berezina, Sofia; Levin, Vadim M.

    Zeitschrift für Naturforschung. B, A journal of chemical sciences, 12/2006, Letnik: 61, Številka: 12
    Journal Article

    Solid fullerenes C and C have been treated at high pressure of 15 GPa and high temperatures of 520 - 1820 K for a time of exposure of 60 s and a quenching rate of 300 K s using a toroid-type apparatus. X-ray diffraction and Raman spectra confirm the realization of 3D-polymerized phases in these solids at 15 GPa. The pressure/temperature maps of synthesis of metastable carbon phases on the basis of C and C have thus been extended to 15 GPa. The longitudinal and shear sound wave velocities were measured by acoustic microscopy techniques. A maximum sound wave velocity of (21±1)×10 m s was observed in the sample synthesized from C at T = 1170 K. The elastic constants were calculated using experimental data. The acoustic microscopy images of experimental samples have been investigated.