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Field, Leslie D; Li, Hsiu L; Magill, Alison M
Inorganic chemistry, 01/2009, Letnik: 48, Številka: 1Journal Article
The treatment of the hydrazine complex cis-Fe(N2H4)(dmpe)22+ with base afforded the diazene complex cis-Fe(N2H2)(dmpe)2. This reaction is reversed by the treatment of the diazene complex with a mild acid, while treatment of the hydrazine complex with a mixture of KOBu t and Bu t Li afforded the dinitrogen complex Fe(N2)(dmpe)2.
