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Kolonko, Kristopher J.; Biddle, Margaret M.; Guzei, Ilia A.; Reich, Hans J.
Journal of the American Chemical Society, 08/2009, Letnik: 131, Številka: 32Journal Article
Multinuclear NMR spectroscopic studies at low temperature (−110 to −150 °C) revealed that lithium p-fluorophenolate and the lithium enolates of cyclohexanone, cyclopentanone and 4-fluoroacetophenone have tetrameric structures in THF/Et2O and THF/Et2O−HMPA by study of the effects of the addition of HMPA. The Z and E isomers of the lithium enolate of 1,3-bis-(4-fluorophenyl)-2-propanone (5F-Li) show divergent behavior. The Z isomer is completely dimeric in pure diethyl ether, and mostly dimeric in 3:2 THF/ether, where monomer could be detected in small amounts. TMTAN and PMDTA convert Z-5F-Li to a monomeric amine complex, and HMPA converts it partially to monomers, and partially to lithiate species (RO)2Li− and (RO)3Li2−. Better characterized solutions of these lithiates were prepared by addition of phosphazenium enolates (using P4-tBu base) to the lithium enolate in 1:1 ratio to form triple ion (RO)2Li− P4H+, or 2:1 ratio to form the higher lithiate (RO)3Li2− (P4H+)2) (quadruple ions). The E isomer of 5F-Li is also dimeric in 3:2 THF/Et2O solution, but is not detectably converted to monomer either by PMDTA or HMPA. In contrast to Z-5F-Li, the E isomer is tetrameric in diethyl ether even in the presence of excess HMPA. Thus for the two isomers of 5F six different enolate structures were characterized: tetramer, dimer, CIP-monomer, SIP-monomer, triple ion, and quadruple ion.
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