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Sun, Raymond Wai-Yin; Zhang, Ming; Li, Dan; Zhang, Zhi-Feng; Cai, Hong; Li, Mian; Xian, Yue-Jiao; Ng, Seik Weng; Wong, Alice Sze-Tsai
Chemistry, December 14, 2015, Letnik: 21, Številka: 51Journal Article
A dinuclear gold(I) pyrrolidinedithiocarbamato complex (1) with a bidentate carbene ligand has been constructed and shows potent in vitro cytotoxic activities towards cisplatin‐resistant ovarian cancer cells A2780cis. Its rigid scaffold enables a zinc(II)‐based metal–organic framework (Zn‐MOF) to be used as a carrier in facilitating the uptake and release of 1 in solutions. Instead of using a conventional dialysis approach for the drug‐release testing, in this study, a set of transwell assay‐based experiments have been designed and employed to examine the cytotoxic and antimigratory activities of 1@Zn‐MOF towards A2780cis. Gold medicine: A dinuclear gold(I) pyrrolidinedithiocarbamato complex with a bidentate carbene ligand has been constructed and shows potent in vitro cytotoxic and antimigratory activities towards cisplatin‐resistant ovarian carcinoma A2780cis. Its rigid scaffold enables a zinc(II)‐based metal–organic framework (Zn‐MOF) to be used in facilitating its uptake and release in solutions.
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in: SICRIS
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