Akademska digitalna zbirka SLovenije - logo
E-viri
Recenzirano Odprti dostop
  • Observation of nitrous acid...
    Wang, Jiaqi; Zhang, Xiaoshan; Guo, Jia; Wang, Zhangwei; Zhang, Meigen

    The Science of the total environment, 06/2017, Letnik: 587-588
    Journal Article

    Seasonal characteristics of atmospheric nitrous acid (HONO) were investigated with high time-resolution field measurements at an urban site of Beijing in four select months (representing four different seasons) from September 2015 to July 2016. The HONO concentrations displayed a pronounced seasonal profile with a maximum in autumn (2.27±1.82ppb) and a minimum in winter (1.05±0.89ppb). Significant diurnal cycles were also observed during the whole campaign. We found that the nighttime build-up of HONO was attributed to the heterogeneous conversion of NO2 on wet surface. The calculated NO2 to HONO conversion frequencies varied from 0.005h−1 in spring to 0.010h−1 in summer, with an average value of 0.008h−1. The seasonality of these conversion frequencies was closely related to the RH levels in different seasons. During daytime, large additional HONO sources were calculated. The noontime additional source was the highest in autumn 3.82ppbh−1, followed by summer 3.05ppbh−1, spring 2.63ppbh−1 and winter 1.30ppbh−1. Correlation studies between the additional HONO source and related parameters demonstrated that the controlling processes responsible for HONO daytime formation varied in different seasons, and that the photo-enhanced formation on wet surface or the photolysis of adsorbed nitric acid and nitrate could be potential HONO sources in Beijing. Display omitted •Atmospheric HONO has been observed in Beijing over four different seasons.•Seasonality of HONO conversion frequencies was closely related to RH levels.•Daytime HONO formation was mainly controlled by the additional HONO source.•Correlation studies evidenced the key role of JNO2 for HONO formation.•Photolysis of adsorbed HNO3 and NO3− could be potential HONO source in autumn.