The Lower Silurian Longmaxi formation is one of the most promising shale gas reservoirs in China. A comprehensive understanding of the shale geomechanical and petrophysical properties is crucial for the successful exploration and extraction of shale gas. We select four representative locations to acquire Longmaxi formation shale samples for the laboratory experiments, to investigate the geomechanical and petrophysical properties through a series of X-ray diffraction (XRD), scanning electron microscope (SEM), uniaxial compression, triaxial compression, tensile strength, and fracture toughness measurements. Laboratory results indicate that: (1) The quartz is the dominant mineral, and phyllosilicate mineral contents vary largelly from 7.30% to 47.80% in Longmaxi shale, which enables a higher brittleness index and fracbility. SEM results show that the high gas storage potential and well micro-fractures development of Longmaxi shale rocks. (2) The phyllosilicate content is vital in determining the uniaxial compressive strength, triaxial strength and elastic properties due to its weaker mechanical properties than tectosilicate minerals; (3) Fracture toughness of Longmaxi shale are relatively higher than shale formations in the USA, which indicate a higher potential to form fracture networks during hydraulic fracturing operations. (4) The anisotropy affects Longmaxi shale mechanical properities extensively due to the high-density bedding planes, which may further influence the fracture network formation during hydraulic fracturing operations. Our results revealed significant non-linear mechanical response as a consequence of shale fabric and mineralogy, which provides necessary information for the in-situ hydraulic fracturing and wellbore stability application during shale gas development in Longmaxi shale formation. •Nanopores and high thermal maturities of Longmaxi shale indicate a high gas storage potential.•The micro-fractures are beneficial for hydraulic fracturing stimulations to enhance reservoir permeability.•The geomechanics properties of Longmaxi shale vary largely due to the differences in mineralogical compositions.•The anisotropy cannot be neglected in analyzing Longmaxi shale geomechanical and petrophysical properties.