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Driller, Katrin Marie; Prateeptongkum, Saisuree; Jackstell, Ralf; Beller, Matthias
Angewandte Chemie (International ed.), January 10, 2011, Letnik: 50, Številka: 2Journal Article
Entering the iron age: The first general method for iron‐catalyzed monocarbonylation of alkynes has been developed. A range of structurally diverse cinnamides and acrylamides have been obtained smoothly starting from commercially available amines and alkynes in the presence of Fe3(CO)12 and ligand L (see scheme). The method is highly chemo‐ and regioselective and requires no expensive catalyst.
