E-viri
Recenzirano
-
Hicks, Scott D; Petersen, Jennifer L; Bougher, Curt J; Abu-Omar, Mahdi M
Angewandte Chemie (International ed.), January 17, 2011, Letnik: 50, Številka: 3Journal Article
Chloride oxyanions are of interest because of their use as disinfectants and concerns over their accumulation in the environment. A water‐soluble manganese porphyrin catalyzes the dismutation of chlorite (ClO2−) to chlorine dioxide (ClO2) through a series of electron‐ and atom‐transfer reactions. A high‐valent manganese(IV) oxo species is observed and the ClO2 product inhibits the reaction.
