As computer and multimedia technology advances and as the variety of knowledge display forms expands, there are more ways for people to obtain knowledge and information. The best course in musicology is voice performance. A crucial issue is how to select and categorize valuable curriculum materials of varying quality levels. This paper implements an automatic classification and integration algorithm for vocal performance learning materials using machine learning technology and tests it on the corresponding dataset, beginning with multidimensional association rule mining technology and the premise that multimedia data contain numerous useful characteristics. Experiments demonstrate the classification precision and data integration capacity of the proposed algorithm. Vocal performance is the most engaging course in musicology. To cultivate corresponding talents, we can rely on college and university offline courses and the rapidly developing multimedia technology to train talents online. An important topic is how to efficiently select and classify curriculum materials of varying quality in order to provide them to students with different learning needs. We can achieve the automatic classification of the course content by leveraging the superior learning capabilities of artificial intelligence and machine learning technology. Consequently, this paper implements an automatic classification and integration algorithm for vocal performance learning materials using machine learning-related technology and conducts an experimental test on the corresponding dataset, beginning with multidimensional association rule mining technology and the perspective that multimedia information itself contains a large number of useful characteristics. Experiments demonstrate that the proposed algorithm has a high level of classification accuracy and data integration capability.