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  • Investigating local corrosi...
    Wang, Shengnan; Gu, Yanhong; Geng, Yinliang; Liang, Jian; Zhao, Jie; Kang, Ju

    Journal of alloys and compounds, 06/2020, Letnik: 826
    Journal Article

    In order to study the effect of defects on the corrosion behavior of MAO coatings, global electrochemical method including potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) was used to measure the corrosion resistance of MAO coatings. Local electrochemical measurements including local impedance spectroscopy (LEIS) and scanning vibrating electrode technique (SVET) were used to study the local corrosion mechanism. The confocal microscopy, scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to observe the microstructure and phases of the samples. Results of global electrochemical measurement demonstrate that the scratches cause the reduction of the impedance and the increase of the corrosion current density. LEIS results show the impedance value distribution of the coating with the scratch. With the changes over time, the minimum impedance value of the scratch decreases first and then increases from the third hour. SVET results show the corrosion current density distribution of the scratched coating. The maximum corrosion current density at the scratch increases first and then decreases. The results of local electrochemical measurements show that the corrosion rate at the scratch decreases when the reaction lasted 3 h. Confocal microscopy found that the scratch is expanding with increasing time, and the depth and cross-sectional area of the coating is 5 times deeper and 10 times larger than that of 7075Al with scratch at the first 6 h. The 6-day immersion test proved that the scratch coating still has the protective effect on the substrate. The main corrosion product is Al(OH)3. A physical model reflecting the mechanism of the scratch propagation and the formation of the corrosion product film is proposed. •Global and local electrochemical corrosion of scratched MAO coating on Al Alloy was studied.•The electrochemical impedance and current distribution of scratches were analyzed by LEIS and SVET.•A phenomenological model for the influence of scratch on the local corrosion of the MAO coated Al alloy was proposed.