Cover Picture: Probing a Major DNA Weakness: Resolving the Groove and Sequence Selectivity of the Diimine Complex Λ‐[Ru(phen)2phi]2+ (Angew. Chem. Int. Ed. 13/2024)

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Cover Picture: Probing a Major DNA Weakness: Resolving the Groove and Sequence Selectivity of the Diimine Complex Λ‐[Ru(phen)2phi]2+ (Angew. Chem. Int. Ed. 13/2024)

Prieto Otoya, Tayler D.; McQuaid, Kane T.; Hennessy, Joseph; Menounou, Georgia; Gibney, Alex; Paterson, Neil G.; Cardin, David J.; Kellett, Andrew; Cardin, Christine J.

Angewandte Chemie International Edition, March 22, 2024, Letnik: 63, Številka: 13

Journal Article

DNA binding by intercalation , showing both sequence and enantiospecificity, of a ruthenium diimine complex, is reported by Christine Cardin, Andrew Kellett et al. in their Research Article (e202318863). The right‐handed helix seen in the crystal structure shows variable degrees of twisting, including the first intercalation by a ruthenium complex from the DNA major groove. In solution, the lambda enantiomer was found to be more stabilising with a range of DNA sequences.

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