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Revés, Marc; Ferrer, Catalina; León, Thierry; Doran, Sean; Etayo, Pablo; Vidal-Ferran, Anton; Riera, Antoni; Verdaguer, Xavier
Angewandte Chemie (International ed.), December 3, 2010, Letnik: 49, Številka: 49Journal Article
Set the N free! The reactivity of the amino group of P‐stereogenic aminophosphines allows the further elaboration of the aminophosphine unit whilst preserving the original chirality of the phosphorus atom (see picture; Rh green). P‐stereogenic aminodiphosphine ligands can easily be prepared in optically pure forms, feature distinct structural and electronic characteristics, and can be used in asymmetric hydrogenation reactions.
