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  • Template Assembly of Polyio...
    Blake, Alexander J.; Gould, Robert O.; Li, Wan-Sheung; Lippolis, Vito; Parsons, Simon; Radek, Christian; Schröder, Martin

    Angewandte Chemie (International ed.), 02/1998, Letnik: 37, Številka: 3
    Journal Article

    The cations Pd2Cl2L2+ and KL2′+ (L = 18aneN2S4, L′ =15aneO5) have been used as templates for the synthesis of unique three‐dimensional polyiodide networks. The metal cations in Pd2Cl2L1.5I5(I3)2 are linked into infinite chains by pairwise hydrogen bonding; the resulting cationic polymers run through channels formed by the extended polyiodide network. KL2′I9 shows a three‐dimensional network of puckered cubic cages of I9− ions whose cavities are occupied by the metal cations (section from the structure shown on the right).