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  • A Phosphole Oxide-Containin...
    Hong, Eugene Yau-Hin; Poon, Chun-Ting; Yam, Vivian Wing-Wah

    Journal of the American Chemical Society, 05/2016, Letnik: 138, Številka: 20
    Journal Article

    A novel class of luminescent phosphole oxide-containing alkynylgold­(III) complex has been synthesized, characterized, and applied as active material in the fabrication of solution-processable resistive memory devices. Incorporation of the phosphole oxide moiety in gold­(III) system has been demonstrated to provide an extra charge-trapping site, giving rise to intriguing ternary memory performances with distinct and low switching threshold voltages, high OFF/ON1/ON2 current ratio of 1/103/107, and long retention time for the three states. The present study offers vital insights for the future development of multilevel memory devices using small-molecule organometallic compounds.