Multiple resonance (MR) emitters are promising for highly efficient organic light‐emitting diodes (OLEDs) with narrowband emission; however, they still face intractable challenges with concentration‐caused emission quenching, exciton annihilation, and spectral broadening. In this study, sterically wrapped MR dopants with a fluorescent MR core sandwiched by bulk substituents were developed to address the intractable challenges by reducing intermolecular interactions. Consequently, high photo‐luminance quantum yields of ≥90 % and small full width at half maximums (FWHMs) of ≤25 nm over a wide range of dopant concentrations (1–20 wt %) were recorded. In addition, we demonstrated that the sandwiched MR emitter can effectively suppress Dexter interaction when doped in a thermally activated delayed fluorescence sensitizer, eliminating exciton loss through dopant triplet. Within the above dopant concentration range, the optimal emitter realizes remarkably high maximum external quantum efficiencies of 36.3–37.2 %, identical small FWHMs of 24 nm, and alleviated efficiency roll‐offs in OLEDs. Sterically wrapped multiple resonance (MR) dopants with the MR‐core sandwiched by bulk substituents have been developed to suppress molecular interactions, realizing organic light‐emitting diodes with remarkably high maximum external quantum efficiencies of 36.3–37.2 %, identical small FWHMs of 24 nm and alleviated efficiency roll‐offs over a wide range of dopant concentrations (1–20 wt %).