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  • Control of the Helicity of ...
    Louzao, Iria; Seco, José M; Quiñoá, Emilio; Riguera, Ricardo

    Angewandte Chemie (International ed.), February 15, 2010, Letnik: 49, Številka: 8
    Journal Article

    Helix sense selection: Tuning the conformational equilibrium of the pendants of poly(phenylacetylene)s allows selection of the helicity of the polymer in a reversible way. Complexation with appropriate metal cations (e.g. Ba2+) or changing the polarity of the solvent permits the reversible selection of the desired helix sense. A full picture of the mechanism explaining this phenomenon is presented.