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  • Chiral Ru/PNNP complexes in...
    Bonaccorsi, Cristina; Althaus, Martin; Becker, Claus; Togni, Antonio; Mezzetti, Antonio

    Pure and applied chemistry, 02/2006, Letnik: 78, Številka: 2
    Journal Article

    The asymmetric hydroxylation and fluorination catalyst Ru(OEt (PNNP) (PNNP = chiral tetradentate ligand with a P donor set) reacts with 1,3-dicarbonyl compounds to give dicationic adducts and, upon deprotonation, the corresponding enolato complexes. The relevance of these species to catalytic O- and F-transfer is investigated.