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Ayer, Suraj K; Roizen, J. L
Journal of organic chemistry, 03/2019, Letnik: 84, Številka: 6Journal Article
Owing to the pervasiveness of hydroxyl groups in natural isolates, alcohol derivatives are alluring directing groups. Herein, an alcohol-derived sulfamate ester guides the light-initiated xanthylation of primary, secondary, or tertiary centers. This process enables formal directed deuteration, azidation, thiolation, and vinylation reactions.
