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Wu, Chia-Hua; Karas, Lucas José; Ottosson, Henrik; Wu, Judy I-Chia
Proceedings of the National Academy of Sciences - PNAS, 10/2019, Letnik: 116, Številka: 41Journal Article
Baird’s rule explains why and when excited-state proton transfer (ESPT) reactions happen in organic compounds. Bifunctional compounds that are 4n + 2 π-aromatic in the ground state, become 4n + 2 π-antiaromatic in the first ¹ππ* states, and proton transfer (either inter- or intramolecularly) helps relieve excited-state antiaromaticity. Computed nucleus-independent chemical shifts (NICS) for several ESPT examples (including excited-state intramolecular proton transfers (ESIPT), biprotonic transfers, dynamic catalyzed transfers, and proton relay transfers) document the important role of excited-state antiaromaticity. o-Salicylic acid undergoes ESPT only in the “antiaromatic” S₁ (¹ππ*) state, but not in the “aromatic” S₂ (¹ππ*) state. Stokes’ shifts of structurally related compounds e.g., derivatives of 2-(2-hydroxyphenyl)benzoxazole and hydrogen-bonded complexes of 2-aminopyridine with protic substrates vary depending on the antiaromaticity of the photoinduced tautomers. Remarkably, Baird’s rule predicts the effect of light on hydrogen bond strengths; hydrogen bonds that enhance (and reduce) excited-state antiaromaticity in compounds become weakened (and strengthened) upon photoexcitation.
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