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Deng, Mucong; Feng, Yongan; Zhang, Wenquan; Qi, Xiujuan; Zhang, Qinghua
Nature communications, 03/2019, Letnik: 10, Številka: 1Journal Article
Over the past century, the search for lead-free, environmentally friendly initiating substances has been a highly challenging task in the field of energetic materials. Here, an organic primary explosive featuring a fused-ring structure, 6-nitro-7-azido-pyrazol3,4-d1,2,3triazine-2-oxide, was designed and synthesized through a facile two-step reaction from commercially available reagents. This organic initiating substance meets nearly all of the stringent criteria of environmentally friendly primary explosives for commercial applications: it is free of toxic metals and perchlorate, has a high density, high priming ability, unusual sensitivities towards non-explosive stimuli, excellent environmental resistance, decent thermal stability, high detonation performance, satisfactory flowability and pressure durability, and is low-cost and easy to scale-up. These combined properties and performance measures surpass the current and widely used organic primary explosive, DDNP. The fused-ring organic primary explosive reported herein may find real-world application as an initiating explosive device in the near future.
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JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
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