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  • Growth Process, Structure a...
    Tarasov, Anton S; Lyaschenko, Sergey A; Rautskii, Mikhail V; Lukyanenko, Anna V; Andryushchenko, Tatiana A; Solovyov, Leonid A; Yakovlev, Ivan A; Maximova, Olga A; Shevtsov, Dmitriy V; Bondarev, Mikhail A; Bondarev, Ilya A; Ovchinnikov, Sergei G; Varnakov, Sergey N

    Processes, 07/2023, Letnik: 11, Številka: 8
    Journal Article

    The growth and phase formation features, along with the influence of structure and morphology on the electronic, optical, and transport properties of Crsub.2GeC and Crsub.2-xMnsub.xGeC MAX phase thin films synthesized by magnetron sputtering technique, were studied. It was found that the Cr:Ge:C atomic ratios most likely play the main role in the formation of a thin film of the MAX phase. A slight excess of carbon and manganese doping significantly improved the phase composition of the films. Crsub.2GeC films with a thicknesses exceeding 40 nm consisted of crystallites with well-developed facets, exhibiting metallic optical and transport properties. The hopping conduction observed in the Crsub.2-xMnsub.xGeC film could be attributed to the columnar form of crystallites. Calculations based on a two-band model indicated high carrier concentrations N, P and mobility μ in the best-synthesized Crsub.2GeC film, suggesting transport properties close to single crystal material. The findings of this study can be utilized to enhance the growth technology of MAX phase thin films.