Searching for new ways of converting carbon dioxide into value-added products, such as fuels, is a relevant task of our time. Electrochemical reduction of carbon dioxide to carbon monoxide, hydrocarbons and alcohols is considered as one of the main approaches in this area. One of the most advanced approaches is the use of coordination polymers for homogeneous and heterogeneous catalysis of carbon dioxide reduction. We obtained coordination pectin biopolymers with different nickel ions contents (PG-NaNi). The structure and composition of the obtained biopolymers were characterized by such physicochemical methods as IR and ICP-AE spectroscopy. Morphology of PG-NaNi on a glassy carbon surface provides very high surface to volume ratio. Cyclic voltammetry on the modified glassy carbon working electrode in water solution saturated with carbon dioxide shows catalytic properties of PG-NaNi for CO2 reduction reaction.