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Shin, Ari; Kim, Bong-Kyu; Kim, Minkyoung; Jeong, Minkyung; Lee, Donggil; Ha, Hyunwoo; Lee, Soo Yeol; Kim, Chunjoong; Park, Soohyung; Kim, Hyun You; Nam, Chang-Yong; Han, Jun Hyun
Materials chemistry and physics, 02/2023, Letnik: 295Journal Article
Acid treatment is the most widely used surface modification method for enhancing the electroless metal deposition (EMD) on carbon reinforcement materials (CRMs) for metal matrix nanocomposites. However, specific microstructural and physicochemical origins of the enhanced EMD on carbon surfaces by acid treatments have been rarely studied. Here, we investigated the effects of the nitric acid treatment on graphite, a prototypical combination of acid treatment and CRM, on the fidelity of Cu EMD and their structural and chemical origins. Complementary materials characterizations and density functional theory calculations revealed the acid-induced formation of broken C–C/CC graphitic bonds and resulting surface micropores on graphite; this enabled a uniform dispersion of catalytic Sn/Pd nanoparticles during pre-EMD sensitization/activation processes via spontaneous binding of Sn and Pd ions and, consequently, a much more uniform Cu layer EMD compared to the untreated graphite. We proposed a general mechanism illustrating how the acid-induced microstructural and chemical modifications of carbon surface affected the spatial uniformity of catalytic metal reduction during EMD and, finally, the quality of deposited metal layer. The results clearly reveal the origins of the enhanced EMD on carbon materials by acid treatments, providing guidelines for optimizing EMD on general CRMs for high-performance metal matrix nanocomposites. Display omitted •Nitric acid treatment induces the formation of numerous, well-distributed fine pores on the graphite surface.•Sn and Pd ions are preferentially adsorbed on broken C–C/CC bonds and CO groups formed by acid treatment.•Nitric acid treatment leads to uniform formation of Sn/Pd nanoparticles during the sensitization and activation processes.•Well-dispersed small catalytic Sn/Pd nanoparticles enable a uniform deposition of a Cu layer on the graphite surface.
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JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
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in: SICRIS
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