Akademska digitalna zbirka SLovenije - logo
E-viri
Celotno besedilo
Recenzirano Odprti dostop
  • Evidence for interface-rate...
    Coffman, D. Keith; Ma, Yonghui; Barr, Christopher; Ouyang, Jia-Hu; Hattar, Khalid; Dillon, Shen J.

    Journal of the European Ceramic Society, October 2022, 2022-10-00, Letnik: 42, Številka: 13
    Journal Article

    The sintering behavior of single Al2O3 particles resting on GdAlO3 is characterized using in situ transmission electron microscopy imaging. In bicrystal experiments, particles with lower Al2O3-GdAlO3 phase boundary energies shrink via Ostwald ripening with no evidence of densification that would result from an atomic flux along the interface. Particles with higher Al2O3-GdAlO3 phase boundary energies undergo intermittent rigid body motion associated with an interfacial flux mediated by interfacial line defects, e.g. disconnections. Long incubation periods elapse between these comparatively rapid rigid body motion events. The interfacial diffusivity during each event agrees with the magnitude of interfacial diffusion obtained from independent measurements of interfacial diffusivity. The results from the model experiments suggest that capillarity driven interfacial strain mediation, e.g. densification during sintering, is interface rate limited at the driving forces investigated.