This study aimed to understand the effects of core configuration on the mechanical properties of additively manufactured specimens made of commercial wood/PLA filament through 3D printing. The ...wood/PLA specimens with different infill rates and pattern types, such as square, hexagonal, and octagonal, were manufactured using a 3D printer. The process parameters in the production of the 3D-printed specimens were kept constant, except for the core configuration. The outside layer thickness was kept constant for all the specimens. The specimens with a hexagonal pattern had the highest mechanical properties, followed by the square and octagonal core patterns. In terms of infill rate, the mechanical properties sharply increased with increasing infill rate. In particular, when the infill rate increased from 20 to 50%, the rate of increase in the mechanical properties was significantly higher than that seen from 50 to 80%. The highest rate of the elastic recovery after the Brinell hardness tests was found in the specimens with hexagonal cores, followed by square- and octagonal-shaped cores.
The article “Enhancement of strength of adhesive bond between wood and metal using atmospheric plasma treatment” written by Jure Žigon, Janez Kovač, Rok Zaplotnik, Jaša Saražin, Milan Šernek, Marko ...Petrič and Sebastian Dahle, was originally published Online First without Open Access.
Due to climate changes, it is necessary to consider the use of other wood species to replace currently used woods. This work deals with the determination of the shear strength of bonded veneers ...(eight European wood species: spruce, larch, pine, beech, oak, poplar, birch, and alder) with Silekol® 311 melamine-urea-formaldehyde adhesive (MUF) with a variable coverage on the surface of the samples: 10, 15, 20, 25, 30, 50, 75, and 100%. The Automated Bonding Evaluation System (ABES) was used to evaluate and compare adhesive bond strengths. The larch, beech, and oak samples exhibited greater single-lap shear strength than the control samples from spruce. There was no statistically significant difference in shear strength regarding the adhesive coverage from 100% to 20% on the surface of the samples, for almost all wood species. The results of the project provide basic information about the bonding strengths with different coverage in the adhesive layer, comparing non-commonly used wood species in wood-based composites such as oriented strand board and particleboard.
An alternative approach to producing a wood-plastic composite (WPC) from wood particles, aluminium trihydrate-filled poly(methyl methacrylate) (PMMA/ATH) waste powder, and melamine-urea-formaldehyde ...(MUF) resin is described. The surface of PMMA/ATH powder was modified with ureido- and amino-functional silane coupling agents at four different degrees of modification: 0.3%, 0.5%, 1.0%, and 2.0%. An X-ray photoelectron spectroscopy (XPS) analysis was executed on a silane-modified PMMA/ATH material, and the results revealed the presence of chemically bonded silanes on the PMMA/ATH surface. Contact angle measurements were also performed to calculate the surface free energies of the modified powders. Water contact angles of modified powders slightly decreased as surface free energy increased with the degree of surface modification. Mechanical tests of the composites showed that different degrees of surface modification had a significant influence on modulus of elasticity (MOE) and modulus of rupture (MOR) of the composite boards. However, there were no significant differences between the silanes used.
Invasive alien plant species pose a significant challenge to European ecosystems. They displace native vegetation, damage agricultural land, and annually cost the European economy billions of euros. ...Many of them are removed daily and mainly burned, although some of them produce lignocellulosic material that could be used in place of native wood species. In this study, the bonding properties of selected invasive wood species in Slovenia were tested using standard methods. Wood lamellas were produced according to the SIST EN 205 standard from Ailanthus altissima, Aesculus hippocastanum, Robinia pseudoacacia, Gleditsia triacanthos and Acer negundo and glued with polyvinyl acetate (PVAc) and one-component polyurethane (PU) adhesive. The results showed that selected wood species can be bonded well with both adhesives (bond shear strengths from 7.2 to 15.1 N/mm2), although there were large variations due to the heterogeneity of the wood material. The differences in the shear strength of the bonds were mainly due to the different densities of the wood (479 to 702 kg/m3) species and the high variability in material properties (for example porosity from 0.54 to 0.68 and shear strength in tangential direction from 11.2 to 21.1 N/mm2), which are related to the anatomical characteristics of the individual wood species.
In the process of wood bonding, the usage of aged and inactivated wooden elements can cause a reduction in mechanical properties of products containing wood-adhesive joints. Treating wood with an ...atmospheric air plasma represents a sophisticated technique for surface activation. With this regard, to enhance the bondability of normal beech wood (
Fagus sylvatica
L.) with urea-formaldehyde (UF) adhesive, a dielectric barrier discharge plasma in floating electrode configuration was implemented. In this study, fresh and aged wood specimen both, untreated and plasma treated, were investigated. X-ray photoelectron spectroscopy revealed promotion of carbon-rich species with ageing, but generation of a new functional oxygen-containing functional groups after plasma treatment. Microscopic observations with scanning electron microscope showed no obvious changes in the wood structure after plasma treatment. Surface oxidation consequently improved the wettability of the wood surface with water and UF adhesive. However, this enhanced wettability slightly diminished over time. As shown with dynamic mechanical analysis, the rheological properties of the UF adhesive in wood-adhesive joints were not affected by aging nor by plasma treatment. The positive influence of plasma treatment and negative impact of substrate ageing to the shear strengths of wood lap-joints were determined using an automated bonding evaluation system. Similarly, the negative effect of wood ageing and the positive effect of plasma pre-treatment were reflected in the bending strengths of the produced laminated veneer lumbers. Results showed that plasma treatment of beech wood improves the bonding performance of both fresh and aged wood.
Graphic abstract
Specimens of European beech wood (Fagus sylvatica L.) charred at 250 °C (4 min), 300 °C (2 min), and 350 °C (1 min) in combination with linseed oil coating were studied. The influence of the surface ...charring process and artificial weathering on surface discoloration, water absorption, and decay resistance were analyzed. Discoloration analysis showed a decrease in all parameters L*, a*, and b* due to the charring process. Coating with linseed oil caused a decrease in the L* parameter. An influence on parameters a* and b* was also demonstrated. As a result of the artificial weathering, the L* parameter increased in almost all groups. The group charred at 350 °C showed a decrease in L*. The parameters a* and b* were also affected. The effect of oil coating on discoloration during artificial weathering was negligible. The average water absorption of uncoated charred specimens decreased more than 50%. Damage due to artificial weathering disrupted the effect of the charring process. The effect of oil coating decreased depending on the length of partial immersion. Surface charring and oil impregnation slightly reduced the loss of beech wood mass caused by T. versicolor and P. placenta but could not fully protect the wood.
Combinations of wood and metal are interesting hybrid composite materials, joining together the low density of wood with the stiffness and strength of metals. Different types of adhesives are used to ...connect wood and metal elements, but the compatibility between adhesives used and load-bearing materials must be sufficient, which often is challenging. In adhesive bonding technology, surface treatments are a crucial step in the process. In this study, an atmospheric plasma discharge was employed to enhance the adhesion strength of joints between common beech (
Fagus sylvatica
L.) wood, metals (steel and aluminum alloy), and four different types of adhesives. The optical properties of plasma discharges and its influence on treated substrates’ surface morphology depended on the inherent properties of the treated materials. X-ray photoelectron spectroscopy revealed the surface oxidation of all the materials after plasma treatment. Consequently, the surface free energy of all materials increased as well. The positive effect of the plasma treatment on the tensile shear strength of single-lap joints shows a high potential of atmospheric plasma treatment technology for enhancement of adhesives strength of joints combining wooden elements, wood and steel, or wood and aluminum alloys. In addition to that, expensive epoxy and polyurethane adhesives could be replaced by more affordable polyvinyl acetate and melamine-urea-formaldehyde adhesives, and still perform at equal levels if the plasma was applied prior to bonding.
A non-isocyanate-based polyurethane (NIPU) wood adhesive was produced from organosolv lignin, which is a bio-sourced raw material, available in large quantities and produced as a by-product of the ...paper industry. The formulation of this new lignin-based NIPU adhesive, which is presented,
was chemically characterised by Matrix-Assisted Laser Desorption Ionization Time of Flight (MALDI ToF) mass spectrometry and by Fourier Transform Infra-Red (FTIR) spectrometry analyses. The oligomers formed were determined and showed that the three species involved in the NIPU adhesive preparation
were formed by the co-reaction of the three reagents used: lignin, dimethyl carbonate, and hexamethylene diamine. Linear and branched structures were both identified. Mechanical properties of the adhesive were determined using the Automated Bonding Evaluation System (ABES) and internal bond
(IB) strength test of the laboratory particleboard bonded with it. The adhesive has shown satisfactory mechanical properties after hot pressing at 230°C. Such a temperature is used industrially in the most modern particleboard factories, but since it is hardly feasible for more conventional
wood bonding equipment, the reactivity of the NIPU adhesive was successfully increased with the addition of a small percentage of a silane coupling agent. With the addition of the silane, the proposed NIPU adhesive could also be used at a hot-pressing temperature lower than 200°C.
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