Luminescent materials with engineered optical properties have been developed for multiplexed labeling detection, where encoding capacity plays a pivotal role in the efficiency. However, ...multi‐dimensional optical identities are usually not independent which essentially hinder the practical encoding numbers to access theoretical capacity. In this work, we carefully studied the sensitizer gradient doping structure in near‐infrared (NIR) excitable upconversion nanoparticles (UCNPs) and managed to achieve independent emission intensity and lifetime tuning. With the orthogonally tunability, it breaks the constraint of intensity (k) and lifetime (n) correlation and expands the practical encoding number to theoretical value as (k+1)n−1 in binary encoding. This method can also be combined with previous lifetime engineering as well to realize high level multiplexing.
The lanthanide sensitizer gradient doping structure in near‐infrared (NIR) excitable upconversion nanoparticles (UCNPs) was studied. With gradient doping, independent emission intensity and lifetime tuning is realized.
The lithium metal battery is strongly considered to be one of the most promising candidates for high-energy-density energy storage devices in our modern and technology-based society. However, ...uncontrollable lithium dendrite growth induces poor cycling efficiency and severe safety concerns, dragging lithium metal batteries out of practical applications. This review presents a comprehensive overview of the lithium metal anode and its dendritic lithium growth. First, the working principles and technical challenges of a lithium metal anode are underscored. Specific attention is paid to the mechanistic understandings and quantitative models for solid electrolyte interphase (SEI) formation, lithium dendrite nucleation, and growth. On the basis of previous theoretical understanding and analysis, recently proposed strategies to suppress dendrite growth of lithium metal anode and some other metal anodes are reviewed. A section dedicated to the potential of full-cell lithium metal batteries for practical applications is included. A general conclusion and a perspective on the current limitations and recommended future research directions of lithium metal batteries are presented. The review concludes with an attempt at summarizing the theoretical and experimental achievements in lithium metal anodes and endeavors to realize the practical applications of lithium metal batteries.
Solid‐state batteries enabled by solid‐state polymer electrolytes (SPEs) are under active consideration for their promise as cost‐effective platforms that simultaneously support high‐energy and safe ...electrochemical energy storage. The limited oxidative stability and poor interfacial charge transport in conventional polymer electrolytes are well known, but difficult challenges must be addressed if high‐voltage intercalating cathodes are to be used in such batteries. Here, ether‐based electrolytes are in situ polymerized by a ring‐opening reaction in the presence of aluminum fluoride (AlF3) to create SPEs inside LiNi0.6Co0.2 Mn0.2O2 (NCM) || Li batteries that are able to overcome both challenges. AlF3 plays a dual role as a Lewis acid catalyst and for the building of fluoridized cathode–electrolyte interphases, protecting both the electrolyte and aluminum current collector from degradation reactions. The solid‐state NCM || Li metal batteries exhibit enhanced specific capacity of 153 mAh g−1 under high areal capacity of 3.0 mAh cm−2. This work offers an important pathway toward solid‐state polymer electrolytes for high‐voltage solid‐state batteries.
Solid‐state batteries are under active consideration for their promise as cost‐effective platforms that simultaneously support high‐energy and safe electrochemical energy storage. In this work, ether‐based solid‐state polymer electrolytes are created inside a battery using ring‐opening polymerization in the presence of aluminum fluoride (AlF3). The electrolytes are shown to mitigate cathode corrosion and to enable solid‐state LiNi0.6Co0.2 Mn0.2O2 (NCM)||Li batteries with high capacities.
Solid‐state lithium (Li) metal batteries (SSLMBs) have become a research hotspot in the energy storage field due to the much‐enhanced safety and high energy density. However, the SSLMBs suffer from ...failures including dendrite‐induced short circuits and contact‐loss‐induced high impedance, which are highly related to the Li plating/stripping kinetics and hinder the practical application of SSLMBs. The maximum endurable current density of lithium battery cycling without cell failure in SSLMB is generally defined as critical current density (CCD). Therefore, CCD is an important parameter for the application of SSLMBs, which can help to determine the rate‐determining steps of Li kinetics in solid‐state batteries. Herein, the theoretical and practical meanings for CCD from the fundamental thermodynamic and kinetic principles, failure mechanisms, CCD identifications, and influence factors for improving CCD performances are systematically reviewed. Based on these fundamental understandings, a series of strategies and outlooks for future researches on SSLMB are presented, endeavoring on increasing CCD for practical SSLMBs.
The critical current density (CCD) is an important standard for future solid‐state Li metal batteries (SSLMBs), which is highly related to power density and fast charge capability. The CCD can help to unravel the rate determining factors of Li kinetics including special mass transport and charge transfer at solid–solid interfaces.
Fast charging enables electronic devices to be charged in a very short time, which is essential for next‐generation energy storage systems. However, the increase of safety risks and low coulombic ...efficiency resulting from fast charging severely hamper the practical applications of this technology. This Review summarizes the challenges and recent progress of lithium batteries for fast charging. First, it describes the definition of fast charging and proposes a critical value of ionic and electrical conductivity of electrodes for fast charging in a working battery. Then based on this definition, the requirements and optimization strategies of the electrode, electrolyte, and electrode/electrolyte interface for fast charging are proposed. Finally, a general conclusion and perspectives on the better understanding of lithium batteries with fast charging capability are presented.
The fast charging of rechargeable batteries is reviewed and the critical values of ionic and electrical conductivity of electrodes that are employed in fast charging are also proposed. The requirements of electrode, solid electrolytes, and their interfaces are also presented to meet the practical application in fast charging batteries.
Lithium Bonds in Lithium Batteries Chen, Xiang; Bai, Yun‐Ke; Zhao, Chen‐Zi ...
Angewandte Chemie International Edition,
July 6, 2020, Volume:
59, Issue:
28
Journal Article
Peer reviewed
Lithium bonds are analogous to hydrogen bonds and are therefore expected to exhibit similar characteristics and functions. Additionally, the metallic nature and large atomic radius of Li bestow the ...Li bond with special features. As one of the most important applications of the element, Li batteries afford emerging opportunities for the exploration of Li bond chemistry. Herein, the historical development and concept of the Li bond are reviewed, in addition to the application of Li bonds in Li batteries. In this way, a comprehensive understanding of the Li bond in Li batteries and an outlook on its future developments is presented.
Lithium bonds that are present in lithium batteries are discussed in this Viewpoint, including historical developments, comparisons with hydrogen bonds, and their potential applications. Discourse on the chemistry of the Li bond can provide fruitful insight into the fundamental interactions within Li batteries and thus deliver a deeper understanding of their working mechanism.
In recent years, the rapid development of modern society is calling for advanced energy storage to meet the growing demands of energy supply and generation. As one of the most promising energy ...storage systems, secondary batteries are attracting much attention. The electrolyte is an important part of the secondary battery, and its composition is closely related to the electrochemical performance of the secondary batteries. Lithium‐ion battery electrolyte is mainly composed of solvents, additives, and lithium salts, which are prepared according to specific proportions under certain conditions and according to the needs of characteristics. This review analyzes the advantages and current problems of the liquid electrolytes in lithium‐ion batteries (LIBs) from the mechanism of action and failure mechanism, summarizes the research progress of solvents, lithium salts, and additives, analyzes the future trends and requirements of lithium‐ion battery electrolytes, and points out the emerging opportunities in advanced lithium‐ion battery electrolytes development.
This review analyzes the advantages and current problems of the liquid electrolytes in lithium‐ion batteries from the mechanism of action and failure mechanism, summarizes the research progress of solvents, lithium salts, and additives, analyzes the future trends and requirements of lithium‐ion battery electrolytes, and points out the emerging opportunities in advanced lithium‐ion battery electrolytes development.
Lithium (Li) metal has been pursued as “Holy Grail” among various anode materials due to its high specific capacity and the lowest reduction potential. However, uncontrolled growth of Li dendrites ...and extremely unstable interfaces during repeated Li plating/stripping ineluctably plague the practical applications of Li metal batteries. Herein, an artificial protective layer with synergistic soft–rigid feature is constructed on the Li metal anode to offer superior interfacial stability during long‐term cycles. By suppressing random Li deposition and the formation of isolated Li, such a protective layer enables a dendrite‐free morphology of Li metal anode and suppresses the depletion of Li metal and electrolyte. Additionally, sufficient ionic conductivity is guaranteed through the synergy between soft and rigid structural units that are uniformly dispersed in the layer. Dendrite‐free and dense Li deposition, as well as a greatly reduced interfacial resistance after cycling, is achieved owing to the stabilized interface, accounting for significantly prolonged cycle life of Li metal batteries. This work highlights the ability of synergistic organic/inorganic protective layer in stabilizing Li metal anode and provides fresh insights into the energy chemistry and mechanics of anode in a working battery.
An artificial protective layer based on the manipulation in the mechanical properties of soft–rigid and organic–inorganic hybrids is proposed for safe lithium metal anodes. The soft organic or polymeric materials offer stretchability to tolerate the volume fluctuation, while the rigid inorganic materials provide mechanical reinforcement and suppress the growth of lithium dendrites.
Lithium–sulfur (Li–S) batteries promise great potential as high‐energy‐density energy‐storage devices due to their ultrahigh theoretical energy density of 2600 Wh kg−1. Evaluation and analysis on ...practical Li–S pouch cells are essential for achieving actual high energy density under working conditions and affording developing directions for practical applications. This review aims to afford a comprehensive overview of high‐energy‐density Li–S pouch cells regarding 7 years of development and to point out further research directions. Key design parameters to achieve actual high energy density are addressed first, to define the research boundaries distinguished from coin‐cell‐level evaluation. Systematic analysis of the published literature and cutting‐edge performances is then conducted to demonstrate the achieved progress and the gap toward practical applications. Following that, failure analysis as well as promotion strategies at the pouch cell level are, respectively, discussed to reveal the unique working and failure mechanism that shall be accordingly addressed. Finally, perspectives toward high‐performance Li–S pouch cells are presented regarding the challenges and opportunities of this field.
High‐energy‐density lithium–sulfur pouch cells are cpomprehensively reviewed regarding the key design parameters, the current performances, and recent advances on failure analysis and promotion strategies on cathode, electrolyte, and anode.
Li dendrite‐free growth is achieved by employing glass fiber with large polar functional groups as the interlayer of Li metal anode and separator to uniformly distribute Li ions. The evenly ...distributed Li ions render the dendrite‐free Li deposits at high rates (10 mA cm−2) and high lithiation capacity (2.0 mAh cm−2).