“Fata Morgana” or “Mirage” phenomena have long been captivated as optical illusions, which actually relies on gradient‐density air or vapor. Man‐made optical illusions have witnessed significant ...progress by resorting to artificially structured metamaterials. Nevertheless, two long‐standing challenges remain formidable: first, exotic parameters (negative or less than unity) become inevitable; second, the signature of original object is altered to that of a virtual counterpart. It is thus not able to address the holy grail of illusion per se, since a single virtual object still exposes the location. In this study, those problems are successfully addressed in a particular setup—illusion thermotics, which identically mimics the exterior thermal behavior of an equivalent reference and splits the interior original heat source into many virtual signatures. A general paradigm to design thermal illusion metadevices is proposed to manipulate thermal conduction, and empower robust simultaneous functions of moving, shaping, rotating, and splitting heat sources of arbitrary cross sections. The temperature profile inside the thermal metadevice can mislead the awareness of the real location, shape, size, and number of the actual heat sources. The present concept may trigger unprecedented development in other physical fields to realize multiple functionalized illusions in optics, electromagnetics, etc.
Existing optical/thermal illusions fail to address the holy grail of illusion per se, since a single virtual object still exposes the location. A solution to this problem is found in illusion thermotics, which identically mimics the exterior thermal behavior of an equivalent reference and splits the interior original heat source into many virtual signatures to enhance the deceptiveness unprecedentedly.
The ability to harvest thermal energy and manipulate heat fluxes has recently attracted a great deal of research interest because this is critical to achieve efficient solar-to-thermal energy ...conversion in the technology of concentrated solar thermal collectors. Thermal metamaterials with engineered thermal conduction are often utilized to control the diffusive heat flow in ways otherwise not possible with naturally occurring materials. In this work, we adopt the transformation thermodynamics approach to design an annular fan-shaped thermal metamaterial which is capable of guiding heat fluxes and concentrating thermal energy to the central region of the metamaterial device without disturbing the temperature profile outside the structure--a fascinating and unique feature impossibly achieved with homogeneous materials. In experiment, this rationally-designed metamaterial structure demonstrates extreme heat flux compression from both line-shaped and point thermal sources with measured concentration efficiency up to 83.1%, providing the first experimental realization of our recent theoretical prediction (T. Han et al., Energy Environ. Sci., 2013, 6, 3537-3541). These unprecedented results may open up new possibilities for engineering thermal materials with desired properties that can be used for dramatically enhancing the efficiency of the existing solar thermal collectors.
The geometry and dimension of a gold nanorod (GNR) are optimally designed to enhance the fluorescence intensity of a lanthanide-doped upconversion nanocrystal placed in close proximity to the GNR. A ...systematic study of the electromagnetic interaction between the upconversion emitter of three energy levels and the GNR shows that the enhancement effect arising from localized electric field-induced absorption can be balanced by the negative effect of electronic transition from an intermediate state to the ground state of the emitter. The dependence of fluorescence enhancement on the emitter-GNR separation is investigated, and the results demonstrate a maximum enhancement factor of 120 folds and 160 folds at emission wavelengths 650 and 540 nm, respectively. This is achieved at the emitter-GNR separation ranging from 5 to 15 nm, depending on the initial quantum efficiency of the emitter. The modified upconversion luminescence behavior by adjusting the aspect ratio of the GNR and the relative position of the emitter indicates the dominate role of excitation process in the total fluorescence enhancement. These findings are of great importance for rationally designing composite nanostructures of metal nanoparticles and upconversion nanocrystals with maximized plasmonic enhancement for bioimaging and sensing applications.
Improving the ferromagnetism property of graphene materials is particularly important for a wide range of applications such as spintronics, magnetic memory, and other electromagnetic devices. ...Pyrrolic nitrogen (N) doping is an effective means to enhance the ferromagnetism of graphene materials. Here we report the synthesis of N-doped graphene with 6.02at.% doping concentration through a high-throughput hydrothermal method. X-ray photoelectron spectroscopy reveals that the pyrrolic N bonding configuration dominates over the other bonding types observed in our samples, which is in good agreement with the Raman spectroscopy and first-principle calculations. The vibrating sample magnetometer and SQUID are employed to further analyze the magnetic properties of the pyrrolic N-doped graphene. At room temperature, the sample exhibits significant ferromagnetism with a high saturation magnetic moment (1.4×10−2emu/g) among graphene materials and a narrow coercivity (181.4Oe). Our results have not only extended the synthesis method of N-doped graphene materials but also deepened the fundamental understanding of the N doping behaviors in enhancing their magnetism.
Plasmon‐induced hot carriers have vast potential for light‐triggered high‐efficiency carrier generation and extraction, which can overcome the optical band gap limit of conventional ...semiconductor‐based optoelectronic devices. Here, it is demonstrated that Au/TiO2 dumbbell nanostructures assembled on a thin Au film serve as an efficient optical absorber and a hot‐carrier generator in the visible region. Upon excitation of localized surface plasmons in such coupled particle‐on‐film nanocavities, the energetic conduction electrons in Au can be injected over the Au/TiO2 Schottky barrier and migrated to TiO2, participating in the chemical reaction occurring at the TiO2 surface. Compared with the same dumbbell nanostructures on an indium tin oxide (ITO) film, such nanocavities exhibit remarkable enhancement in both photocurrent amplitude and reaction rate that arise from increased light absorption and near‐field amplification in the presence of the Au film. The incident‐wavelength‐dependent photocurrent and reaction rate measurements jointly reveal that Au‐film‐mediated near‐field localization facilitates more efficient electron–hole separation and transport in the dumbbells and also promotes strong d‐band optical transitions in the Au film for generation of extra hot electrons. Such nanocavities provide a new plasmonic platform for effective photoexcitation and extraction of hot carriers and also better understanding of their fundamental science and technological implications in solar energy harvesting.
A Au/TiO2‐dumbbell‐on‐Au‐film‐nanocavity system is presented herein. This system features a dual hot electron injection channel recognized as an efficient localized plasmon resonance mechanism and a d‐band optical transition mechanism.
A rapid increase in urbanization has caused severe urban heat island (UHI) effects in China over the past few years. Zhengzhou is one of the emerging cities of China where residents are facing strong ...impact of UHI. By utilizing MODIS data on land surface temperature (LST) and employing 3S technology, this study investigates the UHI phenomenon in Zhengzhou over a 10-year period (2012–2021), aiming to analyze the spatio-temporal evolution characteristics of the UHI effect and the associated land cover changes. To the best of our knowledge, this study represents the first attempt to investigate annual and seasonal changes in different areas of Zhengzhou. It is noted that in the night-time, the intensity of the heat island is stronger than in daytime, which has moderate and weak heat island areas. Seasonal variation showed that in autumn, Zhengzhou has the strong heat island intensity, followed by summer, and the lowest is in winter and spring. The analysis reveals that built-up (construction) areas exhibit the highest LST, whereas forested land and water bodies have the lowest temperature levels. The findings of this study can serve as reference for reducing UHI and increasing thermal comfort in cities.
The development of a new nanolithographic strategy, named scanning nanowelding lithography (SNWL), for the one‐step fabrication of arbitrary high‐aspect‐ratio nanostructures of metal is reported in ...this study. Different from conventional pattern transfer and additive printing strategies which require subtraction or addition of materials, SNWL makes use of a sharp scanning tip to reshape metal thin films or existing nanostructures into desirable high‐aspect‐ratio patterns, through a cold‐welding effect of metal at the nanoscale. As a consequence, SNWL can easily fabricate, in one step and at ambient conditions, sub‐50 nm metal nanowalls with remarkable aspect ratio >5, which are found to be strong waveguide of light. More importantly, SNWL outweighs the existing strategies in terms of the unique ability to erase the as‐made nanostructures and rewrite them into other shapes and orientations on‐demand. Taking advantages of the serial and rewriting capabilities of SNWL, the smart information storage–erasure of Morse codes is demonstrated. SNWL is a promising method to construct arbitrary high‐aspect‐ratio nanostructure arrays that are highly desirable for biological, medical, optical, electronic, and information applications.
Scanning nanowelding lithography is developed to enable one‐step fabrication of arbitrary high‐aspect‐ratio nanostructures of metal through a cold welding mechanism of metal nanostructures.
Chirality is a universal geometric property in both micro‐ and macroworlds. Recently, optical chiral effects have drawn increased attention due to their great potential in fundamental studies and ...practical applications. Significantly, the optical chiral response of artificial structures can be enhanced by orders of magnitude compared to that of their naturally occurring counterparts. These man‐made structures generally exhibit two types of optical chirality: extrinsic chirality and intrinsic chirality. The former relies on external illumination conditions, while the latter arises from the geometric characteristics of 3D objects. Herein, this review mainly focuses on the intrinsic chirality of artificial structures and discusses the existing realizations based on their design principles. In particular, an overview is given of the recent demonstrations of nonlinear optical effects in chiral structures and active chiral structures. Lastly, some promising prospects for future studies in the field are outlined.
3D metaphotonic structures with intrinsic chirality support both optical rotation and circular dichroism, which are orders of magnitude higher than that of their naturally occurring counterparts. They have drawn increased attention due to their potential in fundamental studies in physics, chemistry and biology, and in practical applications, such as negative refractive index media, molecule sensors, and modulators.
Paclitaxel (PTX) is among the most commonly used first-line drugs for cancer chemotherapy. However, its poor water solubility and indiscriminate distribution in normal tissues remain clinical ...challenges. Here we design and synthesize a highly water-soluble nucleolin aptamer-paclitaxel conjugate (NucA-PTX) that selectively delivers PTX to the tumor site. By connecting a tumor-targeting nucleolin aptamer (NucA) to the active hydroxyl group at 2' position of PTX via a cathepsin B sensitive dipeptide bond, NucA-PTX remains stable and inactive in the circulation. NucA facilitates the uptake of the conjugated PTX specifically in tumor cells. Once inside cells, the dipeptide bond linker of NucA-PTX is cleaved by cathepsin B and then the conjugated PTX is released for action. The NucA modification assists the selective accumulation of the conjugated PTX in ovarian tumor tissue rather than normal tissues, and subsequently resulting in notably improved antitumor activity and reduced toxicity.
Emerging evidence indicates that osteoclasts direct osteoblastic bone formation. MicroRNAs (miRNAs) have a crucial role in regulating osteoclast and osteoblast function. However, whether miRNAs ...mediate osteoclast-directed osteoblastic bone formation is mostly unknown. Here, we show that increased osteoclastic miR-214-3p associates with both elevated serum exosomal miR-214-3p and reduced bone formation in elderly women with fractures and in ovariectomized (OVX) mice. Osteoclast-specific miR-214-3p knock-in mice have elevated serum exosomal miR-214-3p and reduced bone formation that is rescued by osteoclast-targeted antagomir-214-3p treatment. We further demonstrate that osteoclast-derived exosomal miR-214-3p is transferred to osteoblasts to inhibit osteoblast activity in vitro and reduce bone formation in vivo. Moreover, osteoclast-targeted miR-214-3p inhibition promotes bone formation in ageing OVX mice. Collectively, our results suggest that osteoclast-derived exosomal miR-214-3p transfers to osteoblasts to inhibit bone formation. Inhibition of miR-214-3p in osteoclasts may be a strategy for treating skeletal disorders involving a reduction in bone formation.
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