The feldspar group is one of the most common types of minerals in the earth's crust. Feldspar alteration (including the whole processes of feldspar dissolution, transfer of released solutes, and ...secondary mineral precipitation) is ubiquitous and important in fields including resources and environmental sciences. This paper provides a critical review of feldspar alteration and its geological significance in shallow aquifers to deep hydrocarbon reservoirs, as assessed from peer-reviewed paper in the literature.
A variety of mechanisms such as the surface reaction-controlled dissolution mechanism, the preferential leaching-diffusion controlled mechanism, the diffusion-precipitation controlled dissolution mechanism and the interfacial dissolution-reprecipitation mechanism have been proposed to be responsible for the dissolution of feldspars. Feldspar dissolution rates can be affected by the crystal structure, Al/Si ordering, temperature, pH, surface area, organic acids, chemical affinity, and precipitation of secondary minerals. Five main dissolution rate laws have been used to describe feldspar dissolution rates, including the linear transition state theory (L-TST) rate law, non-linear TST rate law, parallel rate law, stepwave model rate law, and partial equilibrium law. The rate inconsistency between laboratory experiments and field observations is interpreted with hypotheses that include the armoring effects of the coating secondary minerals on feldspar surfaces, the possible effects of leached layers, the approach to saturation with respect to feldspars, the inhibition by absorbed Al3+ on the feldspar surface, and the inhibition by simultaneous slow clay precipitation rates.
The inorganic-original (meteoric water and deep hot water) and organic-original (kerogen and hydrocarbon degradation) hydrogen ion (H+) in a fluid can probably act as a significant catalyzer of fast dissolution of feldspars in shallow aquifers and deep hydrocarbon reservoirs. Various mineral assemblages including extensively leached feldspars with a wide range of associated amounts of clay minerals and quartz cements can be identified in subsurface reservoirs under different geological conditions. Feldspar dissolution can generate enhanced secondary porosities and rock permeability in open geochemical systems at shallow depth or at a moderate-deep depth where faults develop widely. While in closed geochemical systems at moderate-deep depth, feldspar dissolution is likely to generate redistributional secondary porosities and to decrease rock permeability. Authigenic clay minerals formed following feldspar dissolution alter rock wettability and affect the charging and entrapment of hydrocarbons in reservoir. Feldspar alteration may promote hydrocarbon degradation by promoting bioactivity or by consuming low molecular weight organic acids and CO2 produced via oil degradation. Further work should be conducted to study hydrocarbon-water-feldspar interactions in deeply buried hydrocarbon reservoirs. Feldspar alteration may promote CO2 sequestration by consumption of H+, generation of HCO3−, and pH buffering of formation water. K-feldspar alteration may also promote illitization in interbedded mudstones by supplying K+.
Helium, nitrogen and hydrogen are continually generated within the deep continental crust
. Conceptual degassing models for quiescent continental crust are dominated by an assumption that these gases ...are dissolved in water, and that vertical transport in shallower sedimentary systems is by diffusion within water-filled pore space (for example, refs.
). Gas-phase exsolution is crucial for concentrating helium and forming a societal resource. Here we show that crustal nitrogen from the crystalline basement alone-degassing at a steady state in proportion to crustal helium-4 generation-can reach sufficient concentrations at the base of some sedimentary basins to form a free gas phase. Using a gas diffusion model coupled with sedimentary basin evolution, we demonstrate, using a classic intracratonic sedimentary basin (Williston Basin, North America), that crustal nitrogen reaches saturation and forms a gas phase; in this basin, as early as about 140 million years ago. Helium partitions into this gas phase. This gas formation mechanism accounts for the observed primary nitrogen-helium gas discovered in the basal sedimentary lithology of this and other basins, predicts co-occurrence of crustal gas-phase hydrogen, and reduces the flux of helium into overlying strata by about 30 per cent because of phase solubility buffering. Identification of this gas phase formation mechanism provides a quantitative insight to assess the helium and hydrogen resource potential in similar intracontinental sedimentary basins found worldwide.
An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including ...porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (Th) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high Th (95∼115 °C) of AFI and low δ18O(SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ18O(SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds.
•Meteoric diagenesis in an open sandstone geochemical system is investigated.•Petrography, fluid inclusion, isotopic composition and pore water chemistry are applied to decipher freshwater leaching.•Significant uplift and development of faults promoted ancient incursion of meteoric freshwater into buried sandstones.•Meteoric freshwater leaching can generate significant porosity to improve reservoir quality.
Helium, nitrogen and hydrogen are continually generated within the deep continental crust1-9. Conceptual degassing models for quiescent continental crust are dominated by an assumption that these ...gases are dissolved in water, and that vertical transport in shallower sedimentary systems is by diffusion within water-filled pore space (for example, refs.7,8). Gas-phase exsolution is crucial for concentrating helium and forming a societal resource. Here we show that crustal nitrogen from the crystalline basement alone-degassing at a steady state in proportion to crustal helium-4 generation-can reach sufficient concentrations at the base of some sedimentary basins to form a free gas phase. Using a gas diffusion model coupled with sedimentary basin evolution, we demonstrate, using a classic intracratonic sedimentary basin (Williston Basin, North America), that crustal nitrogen reaches saturation and forms a gas phase; in this basin, as early as about 140 million years ago. Helium partitions into this gas phase. This gas formation mechanism accounts for the observed primary nitrogen-helium gas discovered in the basal sedimentary lithology ofthis and other basins, predicts co-occurrence of crustal gas-phase hydrogen, and reduces the flux of helium into overlying strata by about 30 per cent because of phase solubility buffering. Identification of this gas phase formation mechanism provides a quantitative insight to assess the helium and hydrogen resource potential in similar intracontinental sedimentary basins found worldwide.
Data from around the world (Australia, Austria, Bahrain, Brazil, Canada, the Netherlands, Poland, the UK and the USA) show that more than four million onshore hydrocarbon wells have been drilled ...globally. Here we assess all the reliable datasets (25) on well barrier and integrity failure in the published literature and online. These datasets include production, injection, idle and abandoned wells, both onshore and offshore, exploiting both conventional and unconventional reservoirs. The datasets vary considerably in terms of the number of wells examined, their age and their designs. Therefore the percentage of wells that have had some form of well barrier or integrity failure is highly variable (1.9%–75%). Of the 8030 wells targeting the Marcellus shale inspected in Pennsylvania between 2005 and 2013, 6.3% of these have been reported to the authorities for infringements related to well barrier or integrity failure. In a separate study of 3533 Pennsylvanian wells monitored between 2008 and 2011, there were 85 examples of cement or casing failures, 4 blowouts and 2 examples of gas venting. In the UK, 2152 hydrocarbon wells were drilled onshore between 1902 and 2013 mainly targeting conventional reservoirs. UK regulations, like those of other jurisdictions, include reclamation of the well site after well abandonment. As such, there is no visible evidence of 65.2% of these well sites on the land surface today and monitoring is not carried out. The ownership of up to 53% of wells in the UK is unclear; we estimate that between 50 and 100 are orphaned. Of 143 active UK wells that were producing at the end of 2000, one has evidence of a well integrity failure.
•Oil and gas well barrier elements can fail.•The percentage of wells with barrier element failure is between 1.9% and 75%.•Pennsylvanian shale wells have well barrier and failures rates of 6.3% or less.
Catastrophic failure of a tailings dam at an iron ore mine complex in Brumadinho, Brazil, on 25th January 2019 released 11.7 million m
3
of tailings downstream. Although reportedly monitored using an ...array of geotechnical techniques, the collapse occurred without any apparent warning. It claimed more than 200 lives and caused considerable environmental damage. Here we present the Intermittent Small Baseline Subset (ISBAS) technique on satellite-based interferometric synthetic aperture radar (InSAR) data to assess the course of events. We find that parts of the dam wall and tailings were experiencing deformation not consistent with consolidation settlement preceding the collapse. Furthermore, we show that the timing of the dam collapse would have been foreseeable based on this observed precursory deformation. We conclude that satellite-based monitoring techniques may help mitigate similar catastrophes in the future.
Ground deformation and a sudden acceleration of movement in the final two months preceded the catastrophic collapse of the Brumadinho Tailings Dam in Brazil, according to advanced analyses of InSAR remote sensing data.
The differential interferometric synthetic aperture radar (DInSAR) remote sensing technique has proven to be invaluable in the remote monitoring of earth surface movements associated with the ...extraction and geostorage (subsurface injection) of natural resources (water, oil, gas). However, a significant limitation of this technique is the low density and uneven coverage that may be achieved over vegetated rural environments. The Intermittent Small Baseline Subset (ISBAS) method, an amended version of the established SBAS algorithm, has been designed to improve coverage over rural, vegetated, land cover classes by allowing for the intermittent coherence that is predominant in such areas. In this paper we perform a validation of the ISBAS method over an area of gas production and geostorage in North Holland, the Netherlands. Forty-two ERS-2 (SAR) C-band images (1995–2000) and 63 ENVISAT (ASAR) C-band images (2003–2010) were processed using the ISBAS technique and the derived measurements enabled the identification of subsidence patterns in rural and urban areas alike. The dominant feature was an area of subsidence to the west of Alkmaar, attributed to natural gas production from the Bergermeer reservoir, where subsidence rates in the region of 3 mm/year were measured. Displacements derived using linear and non-linear surface deformation models were validated with respect to the first order system of levelling benchmarks which form the Amsterdam Ordnance Datum (NAP). It was established that ISBAS products were accurate to within 1.52 mm/year and 1.12 mm/year for the ERS and ENVISAT data sets respectively. Errors achieved were comparable to results using persistent scatterers interferometry (PSI) during a validation activity carried out in the European Space Agency Terrafirma project. These results confirm the capability of the ISBAS method to provide a more regular sampling of land motion measurements over gas fields that may be critically used in future to infer the properties of buried, fluid-filled, porous rock.
•The ISBAS method can detect land motion over gas fields for all land cover types.•The density of measurements was uniform over almost the entire land surface.•The coverage appears significant when compared to PSI surveys of the same area.•The accuracy is better than 1.52 mm/year when compared to ground levelling data.•The ISBAS method improves the capability to infer the properties of buried cavities.
Abstract Organic-inorganic interactions regulate the dynamics of hydrocarbons, water, minerals, CO 2 , and H 2 in thermal rocks, yet their initiation remains debated. To address this, we conducted ...isotope-tagged and in-situ visual thermal experiments. Isotope-tagged studies revealed extensive H/O transfers in hydrous n -C 20 H 42 -H 2 O-feldspar systems. Visual experiments observed water microdroplets forming at 150–165 °C in oil phases near the water-oil interface without surfactants, persisting until complete miscibility above 350 °C. Electron paramagnetic resonance (EPR) detected hydroxyl free radicals concurrent with microdroplet formation. Here we propose a two-fold mechanism: water-derived and n- C 20 H 42 -derived free radicals drive interactions with organic species, while water-derived and mineral-derived ions trigger mineral interactions. These processes, facilitated by microdroplets and bulk water, blur boundaries between organic and inorganic species, enabling extensive interactions and mass transfer. Our findings redefine microscopic interplays between organic and inorganic components, offering insights into diagenetic and hydrous-metamorphic processes, and mass transfer cycles in deep basins and subduction zones.
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