Chlorine-free Platinum/nitrogen-doped graphene oxygen reduction reaction catalysts were synthesized by a one step method of annealing a mixture of platinum acetylacetonate and graphene oxide under ...ammonia atmosphere. Nanoparticles with close to the ideal particle size for oxygen reduction reaction (ORR) were formed, i.e., with diameter of 3–4 nm (500 and 600 °C) and 6 nm (700 °C). X-ray photoelectron spectroscopy confirmed the successful introduction of both pyridinic and pyrrolic type nitrogen moieties into the graphene layers, which indicates a strong interaction between the nanoparticles and the graphene layers. The electrocatalytic activity of glassy carbon electrodes (GCE) modified with the synthesized Pt/NG samples for oxygen reduction was compared to that of a platinum/carbon black catalyst modified electrode in acidic and alkaline media. Based on the measured limiting current densities and calculated electron transfer number, the highest activity was measured in acidic and alkaline media on the samples annealed at 600 and 700 °C, respectively.
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Liposomal formulations, as versatile nanocarrier systems suitable for targeted delivery, have a highly focused role in the therapy development of unmet clinical needs and diagnostic imaging ...techniques. Formulating nanomedicine with suitable zeta potential is an essential but challenging task. Formulations with a minimum ±30 mV zeta potential are considered stable. The charge of the phospholipid bilayer can be adjusted with membrane additives. The present Quality by Design-derived study aimed to optimise liposomal formulations prepared via the thin-film hydration technique by applying stearylamine (SA) or dicetyl phosphate (DCP) as charge imparting agents. This 32 fractional factorial design-based study determined phosphatidylcholine, cholesterol, and SA/DCP molar ratios for liposomes with characteristics meeting the formulation requirements. The polynomials describing the effects on the zeta potential were calculated. The optimal molar ratios of the lipids were given as 12.0:5.0:5.0 for the SA-PBS pH 5.6 (optimised sample containing stearylamine) and 8.5:4.5:6.5 for the DCP-PBS pH 5.6 (optimised sample containing dicetyl phosphate) particles hydrated with phosphate-buffered saline pH 5.6. The SA-PBS pH 5.6 liposomes had a vesicle size of 108 ± 15 nm, 0.20 ± 0.04 polydispersity index, and +30.1 ± 1.2 mV zeta potential, while these values were given as 88 ± 14 nm, 0.21 ± 0.02, and −36.7 ± 3.3 mV for the DCP-PBS pH 5.6 vesicles. The prepared liposomes acquired the requirements of the zeta potential for stable formulations.
Ion-exchangable titanate nanotubes synthesized by the alkali treatment of TiO
2 (anatase) were rendered photochemically active by decorating them with CdS nanoparticles through a simple wet chemical ...process. HRTEM, Raman and IR observations suggest that the activation could be caused by the strong coupling between the nanotube and the nanoparticles.
•Many adsorbent–adsorbate pairs exhibit a similar electrical conductivity response.•This is a universal phenomenon, which is not yet explained in the literature.•Calculations simulating water ...adsorption on a titanate nanowire network were run.•Our results indicate that the mobility of the adsorbate on the surface may cause the universality.
The variation of conductance during sorption in a variety of different materials exhibits a similar response. However, the detailed understanding of the surface conduction during adsorption still has to be achieved. A simple theoretical framework is presented here, in which we were able to model adsorption-induced conductance changes and obtain the well-known shape of the characteristics. Our model calculations revealed that the unexpected similarity of the response is the consequence of the dynamic nature of adsorption processes in real systems.
Considerable effort has been devoted recently to replace platinum-based catalysts with their non-noble-metal counterparts in the oxygen reduction reaction (ORR) in fuel cells. Nitrogen-doped carbon ...structures emerged as possible candidates for this role, and their earth-abundant metal-decorated composites showed great promise. Here, we report on the simultaneous formation of nitrogen-doped graphene and iron nitride from the lyophilized mixture of graphene oxide and iron salt by high-temperature annealing in ammonia atmosphere. A mixture of FeN and Fe2N particles was formed with average particle size increasing from 23.4 to 127.0 nm and iron content ranging from 5 to 50 wt %. The electrocatalytic oxygen reduction activity was investigated via the rotating disk electrode method in alkaline media. The highest current density of 3.65 mA cm–2 at 1500 rpm rotation rate was achieved in the 20 wt % catalyst via the four-electrode reduction pathway, exceeding the activity of both the pristine iron nitride and the undecorated nitrogen-doped graphene. Since our catalysts showed improved methanol tolerance compared to the platinum-based ones, the formed non-noble-metal system offers a viable alternative to the platinum-decorated carbon black (Pt/CB) ORR catalysts in direct methanol fuel cells.
Direct liquid fuel cells are very appealing alternatives for fighting climate change, particularly in the field of personal mobility solutions. This is especially true for direct methanol fuel cells ...(DMFCs) that use and burn safe fuels that are readily available from sustainable sources using well-established C1 chemistry. However, DMFCs also have some serious competitive disadvantages, like the high cost of the noble metal catalysts, the difficulties of the catalyst application, and the poisoning of the catalyst due to carbon monoxide formation. Here we demonstrate that depositing platinum on TiO2 by atomic layer deposition (ALD) is an easy, reproducible method for the synthesis of TiO2-supported platinum catalyst for methanol oxidation with superior anti-poisoning properties.
The implementation of gas diffusion electrodes is a prerequisite to achieving industrially relevant reaction rates in gas-phase electrochemical CO2 reduction (CO2RR). In the state-of-the-art anion ...exchange membrane flow electrolyzers, however, there is a substantial loss of reactants due to a nonelectrochemical CO2 consumption at the cathode and the transport of its products to the anode. Our detailed analysis of CO2 crossover in a zero-gap CO2-to-CO flow electrolyzer showed a change in the chemical nature of the transported ionic species through the membrane. With the increasing reaction rate, a continuous shift from HCO3 – to CO3 2– conduction was found to be similar to pure carbonate conduction in the high current density region (>100 mA cm–2). As competing hydrogen evolution takes over the cathodic reaction in a CO2-rich environment, hydroxide conduction becomes more pronounced. This reveals an alteration in the chemical CO2 consumption, the so-called CO2 hydration (CO2 + OH– ↔ HCO3 – + OH– ↔ CO3 2–), implying an unidentical environment for the hydroxide ions generated in CO2RR and hydrogen evolution reaction under a CO2 atmosphere. Our work draws attention to the incomplete description of CO2 hydration at the confined cathode/membrane interface in membrane electrode assembly-type zero-gap CO2 electrolyzers.
The one‐step synthesis and characterization of a new and robust titanium‐based metal–organic framework, ACM‐1, is reported. In this structure, which is based on infinite Ti−O chains and ...4,4′,4′′,4′′′‐(pyrene‐1,3,6,8‐tetrayl) tetrabenzoic acid as a photosensitizer ligand, the combination of highly mobile photogenerated electrons and a strong hole localization at the organic linker results in large charge‐separation lifetimes. The suitable energies for band gap and conduction band minimum (CBM) offer great potential for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.
A new metal–organic framework (MOF), based on infinite Ti−O chains and 4,4′,4′′,4′′′‐(pyrene‐1,3,6,8‐tetrayl)tetrabenzoic acid, shows great promise for a wide range of photocatalytic reactions, from hydrogen evolution to the selective oxidation of organic substrates.