We aimed to explore the relationship between the systemic immune-inflammation index (SII) and rheumatoid arthritis (RA) using NHANES from 1999 to 2018.
We collected data from the NHANES database from ...1999 to 2018. The SII is calculated from the counts of lymphocytes (LC), neutrophils (NC), and platelets (PC). The RA patients were derived from questionnaire data. We used weighted multivariate regression analysis and subgroup analysis to explore the relationship between SII and RA. Furthermore, the restricted cubic splines were used to explore the non-linear relationships.
Our study included a total of 37,604 patients, of which 2642 (7.03%) had rheumatoid arthritis. After adjusting for all covariates, the multivariate logistic regression analysis showed that high SII (In-transform) levels were associated with an increased likelihood of rheumatoid arthritis (OR=1.167, 95% CI=1.025-1.328, P=0.020). The interaction test revealed no significant effect on this connection. In the restricted cubic spline regression model, the relationship between ln-SII and RA was non-linear. The cutoff value of SII for RA was 578.25. The risk of rheumatoid arthritis increases rapidly when SII exceeds the cutoff value.
In general, there is a positive correlation between SII and rheumatoid arthritis. Our study shows that SII is a novel, valuable, and convenient inflammatory marker that can be used to predict the risk of rheumatoid arthritis in US adults.
To develop highly efficient synthetic reactions is quite important in organic chemistry. Cross dehydrogenative couplings (CDC) utilize C−H bonds of substrates to construct new C−X (X=C, S, O, N, P) ...bonds. For CDC, the pre‐functionalization of reaction substrates can be avoided and the C−X (X=C, S, O, N, P) bonds can be newly formed by simple and efficient synthesis routes. Meanwhile, water is increasingly used as a substitute for organic solvents in cross‐dehydrogenative coupling because of its rich content, non‐toxicity, and non‐ flammability. In recent years, organic chemists are devoted their efforts to explore the cross dehydrogenative couplings (CDC) in aqueous phase which feature high atom utilization rate and environmental friendliness. Herein, we summarized the recent advances in the construction of C−C, C−S, C−O, C−N, and C−P bonds through CDC reactions of C−H bonds in water.
Abstract
Photocatalytic water splitting is attracting enormous interest for the storage of solar energy but no practical method has yet been identified. In the past decades, various systems have been ...developed but most of them suffer from low activities, a narrow range of absorption and poor quantum efficiencies (Q.E.) due to fast recombination of charge carriers. Here we report a dramatic suppression of electron-hole pair recombination on the surface of N-doped TiO
2
based nanocatalysts under enhanced concentrations of H
+
and OH
−
, and local electric field polarization of a MgO (111) support during photolysis of water at elevated temperatures. Thus, a broad optical absorption is seen, producing O
2
and H
2
in a 1:2 molar ratio with a H
2
evolution rate of over 11,000 μmol g
−1
h
−1
without any sacrificial reagents at 270 °C. An exceptional range of Q.E. from 81.8% at 437 nm to 3.2% at 1000 nm is also reported.
Natural kaolinite clays with different dimensionalities (including kaolinite nanoflakes and nanorods) supported TiO2 nanoparticles were successfully prepared via a facile sol-gel method. Moreover, ...comparisons between FK/TiO2 and RK/TiO2 nanocomposites are conducted in terms of matrix morphology, surface property, energy band structure and interfacial interaction. The effects of kaolinite microstructure, morphology and dimensionality on the interfacial characteristics and photocatalytic properties of the nanocomposites were investigated in detail. The results showed that TiO2 nanoparticles are more easily attached on the kaolinite nanoflakes, and possess more uniform distribution and smaller particle size than that of kaolinite nanorods. In particular, the FK/TiO2 nanocatalysts exhibit higher photocatalytic activity for the degradation of tetracycline hydrochloride than that of RK/TiO2 and bare TiO2, which is attributed to the stronger surface adsorptivity, higher loading efficiency and smaller grain size. Additionally, FK/TiO2 composites show excellent stability, which is ascribed to the intimate interfacial contact between two-dimensional kaolinite nanoflakes and TiO2 nanoparticles. Overall, the enhanced catalytic performance for FK/TiO2 composites is the synergistic effect of two-dimensional morphology, better adsorption capability and more active photocatalysis TiO2 species.
High surface area tin oxide nanocrystals prepared by a facile hydrothermal method are evaluated as electrocatalysts toward CO2 reduction to formate. At these novel nanostructured tin catalysts, CO2 ...reduction occurs selectively to formate at overpotentials as low as ∼340 mV. In aqueous NaHCO3 solutions, maximum Faradaic efficiencies for formate production of >93% have been reached with high stability and current densities of >10 mA/cm2 on graphene supports. The notable reactivity toward CO2 reduction achieved here may arise from a compromise between the strength of the interaction between CO2 •– and the nanoscale tin surface and subsequent kinetic activation toward protonation and further reduction.
Perovskite LaFeO3/montmorillonite nanocomposites (LaFeO3/MMT) have been successfully prepared via assembling LaFeO3 nanoparticles on the surface of montmorillonite with citric acid assisted sol-gel ...method. The results indicated that the uniform LaFeO3 nanoparticles were densely deposited onto the surface of montmorillonite, mainly ranging in diameter from 10 nm to 15 nm. The photocatalytic activity of LaFeO3/MMT was evaluated by the degradation of Rhodamine B (RhB) under visible light irradiation, indicating that LaFeO3/MMT exhibited remarkable adsorption efficiency and excellent photocatalytic activity with the overall removal rate of RhB up to 99.34% after visible light irradiation lasting for 90 min. The interface characteristic and possible degradation mechanism were explored. The interface characterization of LaFeO3/MMT suggested that LaFeO3 nanoparticles could be immobilized on the surface of montmorillonite with the Si-O-Fe bonds. The abundant hydroxyl groups of montmorillonite, semiconductor photocatalysis of LaFeO3 and Fenton-like reaction could enhance the photocatalytic degradation through a synergistic effect. Therefore, the LaFeO3/MMT is a very promising photocatalyst in future industrial application to treat effectively wastewater of dyes.
To fully understand the influence of water on rockburst proneness from energy storage viewpoint of rock and to check the performance of energy-related rockburst proneness indexes, several groups of ...uniaxial compression tests at different stress levels are performed on three types of red sandstone specimens (i.e., the saturated, natural, and oven-dried specimens). The method of combining strain energy calculations and experimental observations is used to assess the rockburst proneness. The progressive failure of the three types of specimens is recorded by a high-speed (H-S) camera, and the rockburst proneness is comprehensively assessed by considering the failure features of the rock specimens (including the fracture sound, fragment ejection, fragment distribution, and far-field ejection mass ratio). The laboratory results reveal that the rockburst proneness of the natural and oven-dried sandstone specimens is similar. However, compared with the natural and oven-dried specimens, the water-saturated specimens exhibit a visible weaker rockburst proneness. It is also evident that the linear energy storage and dissipation laws are applicable to the saturated, natural, and oven-dried specimens. Most interestingly, the energy storage and energy dissipation coefficients are nearly immune to the presence of water in the red sandstone. Based on this, the definitions of absolute energy storage capacity and relative energy storage capacity are adopted to describe the influence of water on the energy storage performance of rocks. It is found that water dramatically weakens the absolute energy storage capacity, but has little and negligible effect on the relative energy storage capacity of sandstone. Considering the direct and indirect indexes, the accuracy of several representative energy-related rockburst proneness indexes is comprehensively compared in terms of the far-field ejection mass ratio, and their performance is discussed from the relative and absolute energy storage aspects. According to their performance, it is strongly recommended to use the direct index for determination of rockburst proneness when energy-related indexes are used.
•The rockburst proneness of oven-dried, natural, water-saturated sandstone specimens is analyzed.•The linear energy storage and dissipation laws are applicable for the sandstone under different contained water conditions.•The concepts of relative energy storage and dissipation capacities are proposed.•The performance of several representative energy-related rockburst proneness indexes is discussed
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