Triggered by the growing needs of developing semiconductor devices at ever‐decreasing scales, strain engineering of 2D materials has recently seen a surge of interest. The goal of this principle is ...to exploit mechanical strain to tune the electronic and photonic performance of 2D materials and to ultimately achieve high‐performance 2D‐material‐based devices. Although strain engineering has been well studied for traditional semiconductor materials and is now routinely used in their manufacturing, recent experiments on strain engineering of 2D materials have shown new opportunities for fundamental physics and exciting applications, along with new challenges, due to the atomic nature of 2D materials. Here, recent advances in the application of mechanical strain into 2D materials are reviewed. These developments are categorized by the deformation modes of the 2D material–substrate system: in‐plane mode and out‐of‐plane mode. Recent state‐of‐the‐art characterization of the interface mechanics for these 2D material–substrate systems is also summarized. These advances highlight how the strain or strain‐coupled applications of 2D materials rely on the interfacial properties, essentially shear and adhesion, and finally offer direct guidelines for deterministic design of mechanical strains into 2D materials for ultrathin semiconductor applications.
The strain engineering of 2D materials is particularly exciting, because an individual sheet can survive remarkably large mechanical strain and its atomic thinness allows mechanical deformations like a piece of paper. These exceptional circumstances create opportunities for the study of new fundamental physics and applications of 2D materials emerging at the large strain level.
As classical 1D nanoscale structures, carbon nanotubes (CNTs) possess remarkable mechanical, electrical, thermal, and optical properties. In the past several years, considerable attention has been ...paid to the use of CNTs as building blocks for novel high‐performance materials. In this way, the production of macroscopic architectures based on assembled CNTs with controlled orientation and configurations is an important step towards their application. So far, various forms of macroscale CNT assemblies have been produced, such as 1D CNT fibers, 2D CNT films/sheets, and 3D aligned CNT arrays or foams. These macroarchitectures, depending on the manner in which they are assembled, display a variety of fascinating features that cannot be achieved using conventional materials. This review provides an overview of various macroscopic CNT assemblies, with a focus on their preparation and mechanical properties as well as their potential applications in practical fields.
Macroscopic architectures based on assembled carbon nanotubes (CNTs) with controlled orientation and configuration are fabricated. This is an important step towards their application. This review provides an overview of various macroscopic CNT assemblies (e.g., fibers, films, arrays), with a focus on their preparation and mechanical properties as well as their potential applications in practical fields.
Electrically responsive electrochemical actuators that contain a polymer electrolyte membrane laminated between two electrodes have attracted great attention due to their potential applications in ...smart electronics, wearable devices, and soft robotics. However, some challenges such as the achievement of large bending strain under low applied voltage and fast ion diffusion and accumulation still exist to be resolved. The key to the solution lies in the choice of electrode materials and the design of electrode structures. In this study, an engineering electrochemical actuator that presents large bending strain under low applied voltage based on MXene/polystyrene-MXene hybrid electrodes is developed. The developed electrochemical actuator based on the MXene/polystyrene-MXene 3D-structure is found to exhibit large bending strain (ca. 1.18%), broad frequency bandwidth, good durability (90% retention after 10,000 cycles) and considerable Young’s modulus (ca. 246 MPa). The high-performance actuation mainly stems from the excellent properties of MXene and 3D-structure of the electrode. The MXene provides excellent mechanical strength and high electrical conductivity which facilitate strong interaction and rapid electron transfer in electrodes. The 3D architectures formed by polystyrene microspheres generate unimpeded ion pathways for ionic short diffusion and fast injection. This study reveals that the 3D-structure hybrid electrodes play a crucial role in promoting the performance of such electrochemical actuators.
Abstract
Although layered van der Waals (vdW) materials involve vast interface areas that are often subject to contamination, vdW interactions between layers may squeeze interfacial contaminants into ...nanopockets. More intriguingly, those nanopockets could spontaneously coalesce into larger ones, which are easier to be squeezed out the atomic channels. Such unusual phenomena have been thought of as an Ostwald ripening process that is driven by the capillarity of the confined liquid. The underlying mechanism, however, is unclear as the crucial role played by the sheet’s elasticity has not been previously appreciated. Here, we demonstrate the coalescence of separated nanopockets and propose a cleaning mechanism in which both elastic and capillary forces are at play. We elucidate this mechanism in terms of control of the nanopocket morphology and the coalescence of nanopockets via a mechanical stretch. Besides, we demonstrate that bilayer graphene interfaces excel in self-renewal phenomena.
Certain plant leaves, such as the lotus leaf, are known to be superhydrophobic due to the hierarchical structures on the leaf surfaces. In this paper, two kinds of superhydrophobic plants leaves with ...hierarchical structured surface, including aged lotus and loropetalum chinense leaves, were introduced. Further, the surface structural models were established for the introduced leaves corresponding to their surface micromorphologies. More importantly, the theoretical modes for predicting sliding angles of liquid droplets on the introduced leaf surfaces were formulated. In addition, the role of surface parameters in determining the superhydrophobicity of hierarchical structured leaves was demonstrated effective. The results of this paper could be used as a guidance for designing desired superhydrophobic property of hierarchical surfaces.
The aim of this study was to explore the function of miR-138 in the pathogenesis of degenerative calcific aortic valve disease (DCAVD).Aortic valve calcification tissue and normal tissue from DCAVD ...patients were collected to detect the expression of miR-138 by qRT-PCR, and immunohistochemical staining was performed to identify the phenotype of valve interstitial cells. QRT-PCR was performed to analyze the expression of miR-138, Runx2, MSX2, and ALP at day 7 after osteogenic differentiation. Alkaline phosphatase activity assay was performed at day 14 after osteogenic differentiation. Alizarin red staining was used to analyze the calcium nodule formation. TargetScan was used to predict potential targets of miR-138. QRT-PCR and Western blotting were performed to analyze the expression of FOXC1 in valve interstitial cells (VICs). The aortic valve calcification was evaluated by quantitative analysis of the velocity in the aortic annulus and transvalvular pressure gradients.In this study, we demonstrated the role of miR-138 in VIC osteogenesis. QRT-PCR results revealed miR-138 was significantly down-regulated in calcified aortic valves compared with non-calcified valves. MiR-138 overexpression inhibited VIC osteogenic differentiation in vitro, while down-regulation of miR-138 enhanced the process. Target prediction analysis and dual-luciferase reporter assay confirmed FOXC1 was a direct target of miR-138. Further research found FOXC1 overexpression promoted VIC osteogenic differentiation. In addition, animal experiments validated indirectly miR-138 could suppress aortic valve calcification.Our findings suggest miR-138 could function as a new inhibitor of VIC osteogenic differentiation, which may act by targeting FOXC1.
The Global Positioning System (GPS) yields good precision and availability in open outdoor environment. However, the errors of GPS may suffer degradation in some complex environments, such as forests ...and urban canyons. To solve this problem, a new positioning method is designed integrating GPS, Digital Terrestrial Multimedia Broadcast (DTMB) and frequency-modulated (FM) radio signal. In this method, the DTMB transmitter acts as a pseudo-satellite to assist GPS positioning. Furthermore, the FM fingerprint positioning is used to correct the positioning bias. An adaptive selection scheme is proposed to provide an optimal integration mode of the sensors. Field experiments in complex environment were carried out for evaluation. Comparing to the GPS-only and GPS + DTMB approach, positioning accuracy was improved by at least 68.21 % and 21.27 % with the proposed method, respectively.
Carbon nanotubes have unprecedented mechanical properties as defect-free nanoscale building blocks, but their potential has not been fully realized in composite materials due to weakness at the ...interfaces. Here we demonstrate that through load-transfer-favored three-dimensional architecture and molecular level couplings with polymer chains, true potential of CNTs can be realized in composites as initially envisioned. Composite fibers with reticulate nanotube architectures show order of magnitude improvement in strength compared to randomly dispersed short CNT reinforced composites reported before. The molecular level couplings between nanotubes and polymer chains results in drastic differences in the properties of thermoset and thermoplastic composite fibers, which indicate that conventional macroscopic composite theory fails to explain the overall hybrid behavior at nanoscale.
Spintronic device is the fundamental platform for spin-related academic and practical studies. However, conventional techniques with energetic deposition or boorish transfer of ferromagnetic metal ...inevitably introduce uncontrollable damage and undesired contamination in various spin-transport-channel materials, leading to partially attenuated and widely distributed spintronic device performances. These issues will eventually confuse the conclusions of academic studies and limit the practical applications of spintronics. Here we propose a polymer-assistant strain-restricted transfer technique that allows perfectly transferring the pre-patterned ferromagnetic electrodes onto channel materials without any damage and change on the properties of magnetism, interface, and channel. This technique is found productive for pursuing superior-quality spintronic devices with high controllability and reproducibility. It can also apply to various-kind (organic, inorganic, organic-inorganic hybrid, or carbon-based) and diverse-morphology (smooth, rough, even discontinuous) channel materials. This technique can be very useful for reliable device construction and will facilitate the technological transition of spintronic study.
Two epoxy resins with widely different mechanical properties were used as matrices in which functionalized carbon nanotubes were randomly dispersed to produce nanocomposites. In both cases, strong ...covalent bonds were created as a bridge between the nanotubes and matrix, but due to differences in viscosity, the nanotubes dispersion was much better in the rubbery epoxy resin than in glassy epoxy. A 28% increase in tensile Young’s modulus was observed in the rubbery system using 1
wt.% functionalized nanotubes, compared to the unreinforced rubbery epoxy. As to glassy epoxy based composites, no improvement in modulus could be observed but a significant 50% improvement in impact toughness was observed, compared to the unreinforced glassy epoxy resin.
PDF
