Successful delivery of the United Nations sustainable development goals and implementation of the Paris Agreement requires technologies that utilize a wide range of minerals in vast quantities. Metal ...recycling and technological change will contribute to sustaining supply, but mining must continue and grow for the foreseeable future to ensure that such minerals remain available to industry. New links are needed between existing institutional frameworks to oversee responsible sourcing of minerals, trajectories for mineral exploration, environmental practices, and consumer awareness of the effects of consumption. Here we present, through analysis of a comprehensive set of data and demand forecasts, an interdisciplinary perspective on how best to ensure ecologically viable continuity of global mineral supply over the coming decades.
We present a map that correlates tectonic units between Alps and western Turkey accompanied by a text providing access to literature data, explaining the concepts used for defining the mapped ...tectonic units, and first-order paleogeographic inferences. Along-strike similarities and differences of the Alpine-Eastern Mediterranean orogenic system are discussed. The map allows (1) for superimposing additional information, such as e.g., post-tectonic sedimentary basins, manifestations of magmatic activity, onto a coherent tectonic framework and (2) for outlining the major features of the Alpine-Eastern Mediterranean orogen. Dinarides-Hellenides, Anatolides and Taurides are orogens of opposite subduction polarity and direction of major transport with respect to Alps and Carpathians, and polarity switches across the Mid-Hungarian fault zone. The Dinarides-Hellenides-Taurides (and Apennines) consist of nappes detached from the Greater Adriatic continental margin during Cretaceous and Cenozoic orogeny. Internal units form composite nappes that passively carry ophiolites obducted in the latest Jurassic–earliest Cretaceous or during the Late Cretaceous on top of the Greater Adriatic margin successions. The ophiolites on top of composite nappes do not represent oceanic sutures zones, but root in the suture zones of Neotethys that formed after obduction. Suturing between Greater Adria and the northern and eastern Neotethys margin occupied by the Tisza and Dacia mega-units and the Pontides occurred in the latest Cretaceous along the Sava-İzmir-Ankara-Erzincan suture zones. The Rhodopian orogen is interpreted as a deep-crustal nappe stack formed in tandem with the Carpatho-Balkanides fold-thrust belt, now exposed in a giant core complex exhumed in late Eocene to Miocene times from below the Carpatho-Balkan orogen and the Circum-Rhodope unit. Its tectonic position is similar to that of the Sakarya unit of the Pontides. We infer that the Rhodope nappe stack formed due to north-directed thrusting. Both Rhodopes and Pontides are suspected to preserve the westernmost relics of the suture zone of Paleotethys.
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•Tectonic map correlates tectonic units between Alps and western Turkey.•Profiles visualize architecture of Alpine-eastern Mediterranean orogens.•Review provides overview of Alpine-type orogens across national boundaries.
We review the geodynamic evolution of the Aegean–Anatolia region and discuss strain localisation there over geological times. From Late Eocene to Present, crustal deformation in the Aegean backarc ...has localised progressively during slab retreat. Extension started with the formation of the Rhodope Metamorphic Core Complex (Eocene) and migrated to the Cyclades and the northern Menderes Massif (Oligocene and Miocene), accommodated by crustal-scale detachments and a first series of core complexes (MCCs). Extension then localised in Western Turkey, the Corinth Rift and the external Hellenic arc after Messinian times, while the North Anatolian Fault penetrated the Aegean Sea. Through time the direction and style of extension have not changed significantly except in terms of localisation. The contributions of progressive slab retreat and tearing, basal drag, extrusion tectonics and tectonic inheritance are discussed and we favour a model (1) where slab retreat is the main driving engine, (2) successive slab tearing episodes are the main causes of this stepwise strain localisation and (3) the inherited heterogeneity of the crust is a major factor for localising detachments. The continental crust has an inherited strong heterogeneity and crustal-scale contacts such as major thrust planes act as weak zones or as zones of contrast of resistance and viscosity that can localise later deformation. The dynamics of slabs at depth and the asthenospheric flow due to slab retreat also have influence strain localisation in the upper plate. Successive slab ruptures from the Middle Miocene to the Late Miocene have isolated a narrow strip of lithosphere, still attached to the African lithosphere below Crete. The formation of the North Anatolian Fault is partly a consequence of this evolution. The extrusion of Anatolia and the Aegean extension are partly driven from below (asthenospheric flow) and from above (extrusion of a lid of rigid crust).
Subduction of Neo-Tethys oceanic lithosphere beneath the Iranian plate during the Mesozoic formed several igneous bodies of ultramafic to intermediate and felsic composition. Intrusion of these ...magmas into a regional metamorphic sequence (the Sanandaj-Sirjan Zone) caused partial melting and formation of migmatites with meta-pelitic protoliths. The Alvand complex (west Iran) is a unique area comprising migmatites of both mafic and pelitic protoliths. In this area, the gabbroic rocks contain veins of leucosome at their contact with pyroxenite and olivine gabbro. These leucosomes are geochemically and mineralogically different from leucosomes of the meta-pelitic migmatites and clearly show properties of I-type granites. Microscopic observations and whole rock compositions of the mafic migmatite leucosomes show that migmatization occurred through partial melting of biotite, hornblende and plagioclase. Thermobarometric calculations indicate 800 °C and 3.7 kbar for partial melting, although phase diagram modeling demonstrates that the presence of water could decrease the solidus temperature by about 40 °C. Our results suggest an asthenospheric magma upwelling as the source of heat for partial melting of the gabbroic rock during subduction of Neo-Tethys oceanic crust under the western edge of the Iranian plate. The present study also reveals relationships between migmatization and formation of S- and I -type granites in the area.
•Cpx-bearing harzburgite occurs in ophiolite mélange in NW Iran.•Primary Cr-Spinel chemistry indicates an abyssal affinity for the peridotites.•Hydrothermally altered Cr-spinel shows reaction ...textures.•Cr-Chl, Cr-Grt and a ferrian chromite-silicate mixture formed by cation mobility.
The Late Cretaceous ophiolite mélange in the Salmas area of NW Iran is a part of the Neotethys ophiolites. The mélange includes serpentinized harzburgite, serpentinites, mafic rocks, radiolarite, layered red pelagic limestones and grey and white marbles. Harzburgite main primary mineral phases are olivine, orthopyroxene, clinopyroxene and Cr-spinel. Cr-spinel has Cr2O3 contents of 21.13 to 30.18 wt% and high Al2O3 (38.67–48.52 wt%), FeO (15.18–18.13 wt%) and MgO (15.18–17.51 wt%) contents. The 100 × Cr/(Cr + Al) ratios of 23 to 34 indicate 9 to 13 % partial melting in the Mid Ocean Ridge (MOR) environment for the origin of the peridotites. An alteration zone is developed around the altered Cr-spinel. Fine-grained minerals assemblage at the spinel crystals’ margin includes Cr-rich chlorite, Cr-rich garnet and spinel-silicate mixture. A 2–5 μm wide transitional zone is developed between the chromite-silicate assemblage and the Cr-rich garnet zone. The chemical variations of major oxides across the alteration zone are mainly diffusion controlled. Al, Cr and Mg have diffused out from the primary spinel and Fe and Mn have diffused into the spinel. Cr-spinel is altered in two stages due to serpentinization. During the first stage and following hydration, spinel reacted with olivine and orthopyroxene to form Cr-rich chlorite and ferrian chromite. Silica formed at this stage. At the second stage, the reaction between the chromite-silicate assemblage and Cr-rich chlorite plus silica form the first stage and Ca2+ in the fluid (released from clinopyroxene alteration) produced Cr-rich garnet and H2O-rich fluid, at temperature between 400 and 600 °C.
Understanding the relationships between density and spatio-thermal variations at convergent plate boundaries is important for deciphering the present-day dynamics and evolution of subduction zones. ...In particular, the interaction between densification due to mineralogical phase transitions and slab pull forces is subject to ongoing investigations. We have developed a two-dimensional subduction zone model that is based on thermodynamic equilibrium assemblage calculations and includes the effects of melting processes on the density distribution in the lithosphere. Our model calculates the “metamorphic density” of rocks as a function of pressure, temperature and chemical composition in a subduction zone down to 250km. We have used this model to show how the hydration, dehydration, partial melting and fractionation processes of rocks all influence the metamorphic density and greatly depend on the temperature field within the subduction system. These processes are largely neglected by other approaches that reproduce the density distribution within this complex tectonic setting. Our model demonstrates that the initiation of eclogitization (i.e., when crustal rocks reach higher densities than the ambient mantle) of the slab is not the only significant process that makes the descending slab denser and generates the slab pull force. Instead, the densification of the lithospheric mantle of the sinking slab starts earlier than eclogitization and contributes significantly to slab pull in the early stages of subduction. Accordingly, the complex metamorphic structure of the slab and the mantle wedge has an important impact on the development of subduction zones.
•Calculation of a 2D metamorphic density model of a subduction zone.•Investigation of the impact of hydration, partial melting and fractionation on density.•Comparing the buoyancy of the subducted crust and subducted lithospheric mantle.•Contribution of eclogitization to slab pull is overestimated at the early stages.•Lithosphere densification makes higher contribution to slab pull at the early stages.
Tectonic blocks and slabs of mafic–ultramafic rocks are distributed discontinuously in the Yuli metamorphic belt of Taiwan. The blocks include rare omphacite metagabbros and garnet–epidote ...blueschists in the Wanjung and Juisui (Tamayen) areas, respectively. Such high-pressure (HP) mineral assemblages have been attributed to a mid-Miocene subduction event. However, the surrounding psammitic, pelitic and chloritic schists are the dominant greenschist-facies lithologies of the Yuli belt. In the Chinshuichi area, tectonic blocks are enclosed in garnet-bearing metapelites, suggesting elevated pressures. In this area, we recently discovered meta-plagiogranite containing the assemblage glaucophane+omphacite (XJd up to 0.39)+rutile+quartz, indicating P–T conditions near 13kbar/550°C. New equilibrium phase modeling of a garnet–paragonite mica schist and compositional isopleths for peak assemblage minerals garnet and phengite (Si=3.33–3.37pfu) indicate metamorphic conditions of 15.5–17kbar/530–550°C. These P–T estimates are higher than previously reported in the Yuli belt and suggest that both tectonic blocks and host metapelites underwent HP metamorphism. The juxtaposition of tectonic blocks and metapelites apparently occurred during the formation of a subduction–accretionary complex, followed by exhumation facilitated by a collisional event. These new findings imply that HP metamorphism was not limited to tectonic blocks, and instead played a significant role attending orogenesis in eastern Taiwan.
•First report of high-pressure metamorphism in metasediments of the Yuli belt•Garnet–paragonite mica schist yields P–T estimates of 15.5–17kbar/530–550°C.•HP metamorphism affected tectonic blocks and metasediments of the Yuli belt.•Yuli belt formed by the exhumation of subducted material from depths of ~55km.
We provide new insights into the prograde evolution of H
P
/L
T
metasedimentary rocks on the basis of detailed petrologic examination, element-partitioning analysis, and thermodynamic modelling of ...well-preserved Fe–Mg–carpholite- and Fe–Mg–chloritoid-bearing rocks from the Afyon Zone (Anatolia). We document continuous and discontinuous compositional (ferromagnesian substitution) zoning of carpholite (overall
X
Mg
= 0.27–0.73) and chloritoid (overall
X
Mg
= 0.07–0.30), as well as clear equilibrium and disequilibrium (i.e., reaction-related) textures involving carpholite and chloritoid, which consistently account for the consistent enrichment in Mg of both minerals through time, and the progressive replacement of carpholite by chloritoid. Mg/Fe distribution coefficients calculated between carpholite and chloritoid vary widely within samples (2.2–20.0). Among this range, only values of 7–11 correlate with equilibrium textures, in agreement with data from the literature. Equilibrium phase diagrams for metapelitic compositions are calculated using a newly modified thermodynamic dataset, including most recent data for carpholite, chloritoid, chlorite, and white mica, as well as further refinements for Fe–carpholite, and both chloritoid end-members, as required to reproduce accurately petrologic observations (phase relations, experimental constraints, Mg/Fe partitioning). Modelling reveals that Mg/Fe partitioning between carpholite and chloritoid is greatly sensitive to temperature and calls for a future evaluation of possible use as a thermometer. In addition, calculations show significant effective bulk composition changes during prograde metamorphism due to the fractionation of chloritoid formed at the expense of carpholite. We retrieve
P
–
T
conditions for several carpholite and chloritoid growth stages (1) during prograde stages using unfractionated, bulk-rock XRF analyses, and (2) at peak conditions using compositions fractionated for chloritoid. The
P
–
T
paths reconstructed for the Kütahya and Afyon areas shed light on contrasting temperature conditions for these areas during prograde and peak stages.
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