Silicate hydration is prevalent in natural and technological processes, such as, mineral weathering, glass alteration, zeolite syntheses and cement hydration. Tricalcium silicate (Ca3SiO5), the main ...constituent of Portland cement, is amongst the most reactive silicates in water. Despite its widespread industrial use, the reaction of Ca3SiO5 with water to form calcium-silicate-hydrates (C-S-H) still hosts many open questions. Here, we show that solid-state nuclear magnetic resonance measurements of (29)Si-enriched triclinic Ca3SiO5 enable the quantitative monitoring of the hydration process in terms of transient local molecular composition, extent of silicate hydration and polymerization. This provides insights on the relative influence of surface hydroxylation and hydrate precipitation on the hydration rate. When the rate drops, the amount of hydroxylated Ca3SiO5 decreases, thus demonstrating the partial passivation of the surface during the deceleration stage. Moreover, the relative quantities of monomers, dimers, pentamers and octamers in the C-S-H structure are measured.
This research aims at gaining a further understanding of the impact of accelerating admixtures on the reactivity of supplementary cementitious materials (SCMs), which are widely used as a clinker ...replacement in blended cements. This was done on synthetic glasses with controlled composition and structure that mimic two types of real SCMs (slag and calcium-rich fly ash). The effects of DEIPA, TIPA, NaSCN and Na
S
O
on the glass dissolution, hydration kinetics and reaction products were investigated. The obtained results concluded that the pH of the NaOH solution and the composition of the synthetic glass play a key role on the effect of the admixtures. In 0.1 M NaOH (pH = 13.0), all the studied admixtures inhibited the dissolution of slag-like glasses while they enhanced the dissolution of Ca-rich fly ash-like glasses, being Na
S
O
the admixture that led to the highest increase of the dissolution rate of the Ca-rich fly ash-type glasses. In 1 M NaOH solutions (pH = 13.8), only the alkali admixtures (NaSCN and Na
S
O
) enhanced the degree of reaction of both glasses. In slag-type glasses pastes mixed with 1 M NaOH, the addition of 2% Na
S
O
induced the highest increase of their reactivity as inferred by the total heat release and the amount of bound water. This is related to the formation of a high amount of S(II)-AFm, in addition to C-A-S-H, that would increase the aluminium undersaturation of the pore solution and consequently the further dissolution of the glass.
Munk's pygmy devil rays (Mobula munkiana) are medium-size, zooplanktivorous filter feeding, elasmobranchs characterized by aggregative behavior, low fecundity and delayed reproduction. These traits ...make them susceptible to targeted and by-catch fisheries and are listed as Vulnerable on the IUCN Red List. Multiple studies have examined fisheries impacts, but nursery areas or foraging neonate and juvenile concentrations have not been examined. This study describes the first nursery area for M. munkiana at Espiritu Santo Archipelago, Mexico. We examined spatial use of a shallow bay during 22 consecutive months in relation to environmental patterns using traditional tagging (n = 95) and acoustic telemetry (n = 7). Neonates and juveniles comprised 84% of tagged individuals and their residency index was significantly greater inside than outside the bay; spending a maximum of 145 consecutive days within the bay. Observations of near-term pregnant females, mating behavior, and neonates indicate an April to June pupping period. Anecdotal photograph review indicated that the nursery area is used by neonates and juveniles across years. These findings confirm, for the first time, the existence of nursery areas for Munk's pygmy devil rays and the potential importance of shallow bays during early life stages for the conservation of this species.
During gestation, essential and non-essential trace elements are transferred from the pregnant females to embryos. This study aimed to determine and compare the concentrations of seven essential ...trace elements (Fe, Zn, Se, Cu, Mn, Cr, Co) and six non-essential trace elements (As, Cd, V, U, Tl, Ag) in the muscle and the liver of a Munk’s pygmy devil ray pregnant female,
Mobula munkiana
, and its embryo. Transfer evidence of essential and non-essential trace elements was detected in
M. munkiana
tissues. Arsenic was found in elevated concentrations in the pregnant female and the embryo tissues. Elevated levels of Cd, V, U, and Ag were found in the pregnant female liver, but were minimal in the embryo tissue. This is the first study to investigate maternal transfer of essential and non-essential trace elements in these species and their reproductive strategy.
Manta and devil rays are filter-feeding elasmobranchs that are found circumglobally in tropical and subtropical waters. Although relatively understudied for most of the 20th century, public awareness ...and scientific research on these species has increased dramatically in recent years. Much of this attention has been in response to targeted fisheries, international trade in mobulid products, and a growing concern over the fate of exploited populations. Despite progress in mobulid research, major knowledge gaps still exist, hindering the development of effective management and conservation strategies. We assembled 30 leaders and emerging experts in the fields of mobulid biology, ecology and conservation to identify pressing knowledge gaps that must be filled to facilitate improved science-based management of these vulnerable species. We highlight focal research topics in the subject areas of taxonomy and diversity, life history, reproduction and nursery areas, population trends, bycatch and fisheries, spatial dynamics and movements, foraging and diving, pollution and contaminants, and sub-lethal impacts. Mobulid rays remain a poorly studied group, and therefore our list of important knowledge gaps is extensive. However, we hope that this identification of high priority knowledge gaps will stimulate and focus future mobulid research.
We examined the reproductive behavior (courtship and mating), seasonality and its distribution in three Mobula species, spinetail, bentfin, and Munk’s devil rays (
M. mobular, M. thurstoni,
and
M. ...munkiana
) in the southwestern Gulf of California, Mexico, using boat surveys (with drone and in-water observations) (
n
= 69 survey days), spotter planes (
n
= 428 flights), and citizen science observations (
n
= 31). We examined whether (1) reproductive grounds existed within the area for any of these species, (2) whether reproductive behavior followed seasonal patterns, and (3) if this behavior was similar among all mobula rays. We observed reproductive behavior in 221 events in 2017 and 2021–2022, for
M. mobular
(
n
= 10),
M. thurstoni
(
n
= 3), and
M. munkiana
(
n
= 208) dispersed along 312 km of the eastern Baja California Peninsula between 4 m and 6.3 km away from the coast. Most events (
n
= 209) occurred in the La Ventana and Ensenada de Muertos areas. Courtship was observed for
M. mobular
and
M. thurstoni
and a copulation attempt for
M. munkiana
, with reproductive behavior following a seasonal pattern occurring from March to August, with a peak during May (81.9% of the events).
Mobula munkiana
displayed previously undescribed behaviors, such as the “piggyback leaps” as a pre-copulatory position and the “courtship vortex”, where 122 individuals were observed circling in a clockwise direction for 5 h with courtship groups joining and leaving the main vortex formation. This study highlights the areas of La Ventana and Ensenada de Muertos as critical habitats for reproductive behavior of two endangered and one vulnerable devil ray species.
The incidental capture of non-target species (bycatch) in tuna fisheries impacts some marine vertebrates, particularly species with vulnerable life histories such as manta and devil rays (mobulids). ...There is broad interest in reducing mobulid bycatch in tuna purse seine fisheries, with existing efforts mainly focusing on reducing post-capture mortality rates. We explore a novel potential pre-capture mobulid bycatch avoidance strategy for the tuna purse seine fishery using communication between fishing vessels and associated spotter helicopters. We conducted a survey of tuna purse seine helicopter pilots, spotters, and fishers operating in the eastern Pacific Ocean (n = 33) to ascertain the ability of helicopter crew to detect mobulids prior to capture and communicate bycatch avoidance with vessel crew. Results indicate over half of the helicopter crew report being “always” or “sometimes” able to sight and identify mobulids and that helicopter crew regularly communicate mobulid sightings to the vessel already. Given that an average of 63% of class-6 vessel trips between 2017 to 2022 carried onboard helicopters, our results suggest that helicopter-vessel communication could be feasible and scalable for mobulid bycatch detection, enabling potential bycatch avoidance and early alerts for proper handling protocols. We also identify the potential use of helicopter detection to improve research efforts for mobulid conservation (e.g., data collection of population and habitat observations). This study is the first to investigate the utility of helicopter-vessel communication as a bycatch mitigation strategy for elasmobranchs and identifies research and management directions that could be further investigated to avoid bycatch of mobulids.
We report the preparation of different surface patterns based on the photo-cross-linking/degradation kinetics of polystyrene (PS) by using UV light. Upon exposure to UV light, PS can be initially ...cross-linked, whereas an excess of the exposure time or intensity provokes the degradation of the material. Typically photolithography employs either positive or negative photoresist layers that upon removal of either the exposed or the nonexposed areas transfer the pattern of the mask. Herein, we present a system that can be both negative and positive depending on several aspects, including the irradiation time, intensity, or presence of absorbing active species (photoinitiators) using a general setup. As a result of the optimization of the time of exposure and the use of an appropriate cover or the incorporation of an appropriate amount of photoinitiator (in this particular case IRG 651), different tailor-made surface patterns can be obtained. Moreover, changes of the chemical composition of the polystyrene using, for instance, block copolymers can lead to surface patterns with variable functional groups. In this study we describe the formation of surface patterns using polystyrene-block-poly(2,3,4,5,6-pentafluorostyrene) block copolymers. The introduction of fluorinated moieties clearly modifies the wettability of the films when compared with that of the same structures obtained with PS. As a consequence we present herein a patterning methodology that can simultaneously vary not only the morphology but also the surface chemical composition.
The effect of two precursors (slag and fly ash), different particle size distribution, and three types of aggregate (siliceous sand, limestone, and recycled concrete) on alkali-activated material ...(AAM) mortar rheology were studied and compared to their effect on an ordinary Portland Cement (OPC) mortar reference. Stress growth and flow curve tests were conducted to determine plastic viscosity and static and dynamic yield stress of the AAM and OPC mortars. In both OPC and AAM mortars, a reduction of the aggregate size induces a rise of the liquid demand to preserve the plastic consistency of the mortar. In general terms, an increase of the particle size of the siliceous aggregates leads to a decrease of the measured rheological parameters. The AAM mortars require higher liquid/solid ratios than OPC mortars to attain plastic consistency. AAM mortars proved to be more sensitive than OPC mortars to changes in aggregate nature. The partial replacement of the siliceous aggregates with up to 20% of recycled concrete aggregates induced no change in mixing liquid uptake, in either AAM or OPC mortars. All the AAM and OPC mortars studied fitted to the Bingham model.
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