The Tolmin Basin constitutes the western part of the Slovenian Basin, a large Mesozoic interplatform basin that was bounded to the north by the Julian Carbonate Platform and to the south by the ...Dinaric Carbonate Platform. Today, it is found along the structural boundary between the Southern Alps and the External Dinarides in northwestern Slovenia. After the drowning of the Julian Carbonate Platform, the Tolmin Basin was dominated by pelagic deposits, namely the Toarcian marlstones (Perbla Formation), the Aalenian to lower Tithonian siliceous limestones and radiolarites (Tolmin Formation), and the upper Tithonian to the Berriasian Biancone Limestone Formation. In this study, a basin-scale sedimentary evolution and calpionellid biostratigraphy of the latter is presented. The Biancone Limestone Formation is a calpionellid-bearing pelagic limestone typical of all deepened segments of the Adria microplate in this time interval. It is generally monotonous but shows considerable vertical and lateral variations. The lower boundary with radiolarites is sharp, revealing a pronounced and rapid overturn in pelagic sedimentation. The lower Berriasian slumps indicate a tectonic pulse. Rare beds of resedimented limestones, assigned to the middle Berriasian, are similar in composition to those intercalated in the underlying radiolarites. They thus show that the factors that led to a significant shift in pelagic sedimentation had little or no effect on shallow-marine carbonate production. In the upper Berriasian, an increase in clay content is evident in the formation, which is explained by the uplift and erosion of the propagating thrust belt in the Neotethys area, superimposed by humidification.
In the Slovenian part of the Gulf of Trieste/Trst, submarine springs occur as funnel-shaped depressions in the Holocene sandy-silt marine sediment that forms the seafoor. These springs exhibit both ...elevated temperatures (up to 29.6 °C) and sulphur content. Based on their location, they are divided into three groups: the Izola group (three springs), the Bele skale group (two springs), and the Ronek group (seven springs). Previous investigations linked these springs to the Izola anticline, characterized by its limestone core and fysch limbs, but no detailed explanation was provided. We propose that: A) sulphur groundwater springs from the limestone (karstic aquifer) at the stratigraphic boundary with the fysch and B) springs occur in the nearshore area, where the sedimentary cover of Quaternary deposits is thin enough to be penetrated by spring waters and washed out. According to existing data, the anticline axis is NW-SE directed, and the Izola group lies approximately on the seaward extension of the axis. Therefore, this interpretation fts perfectly for the Izola group, while the Ronek and Bele skale groups are of-axis extensions and require reinterpretation. In order to resolve the micro-locations of the Ronek and Bele skale groups, we conducted a sedimentological logging of the fysch deposits and detailed geological mapping. The investigations revealed that: A) limestone outcrops occur only in the town of Izola, B) two prominent calciturbidite megabeds that occur in the fysch enable very detailed geological mapping, and C) the axis of the Izola anticline is oriented in the WNW-ESE direction, and this moderate anti-clockwise rotation of the anticline axis explains the micro-locations of all springs. The Ronek and Bele skale groups are located on the southern side, and the Izola group is on the northern side of the limestone core of the Izola anticline.
The Miocene evolution of the area transitional from the Eastern Alps to the Pannonian Basin System was studied through the paleogeographic evolution of the Slovenj Gradec Basin in northern Slovenia. ...It is based on mapping, section logging, nannoplankton biostratigraphy, and petrography. The results are correlated with the lithological column of the borehole MD-1/05. The evolution of the basin is connected with the development of the Pannonian Basin System, and the global 3
order cycles, which influenced the connection with the Mediterranean Sea. Sedimentation started in the Karpatian in a fluvial to lacustrine environment and terminated at the end of the Early Badenian. During this period, three transgression–regression cycles were recorded. The first transgression occurred in the Karpatian and corresponds to the TB 2.2. cycle. The sediments reflect proximity of the hinterland. After a short break in sedimentation, the Early Badenian deposition followed. It marks the second transgression into the SGB, the first Badenian, correlated with the TB 2.3 cycle. There are signs of a transitional environment, which evolved to marine in advanced stages. At the high-stand system tract, the sea flooded the entire Slovenj Gradec Basin. Subsequent reduced quantity and diversity of the microfossils marks the onset of the second regression stage. It is followed by the third transgression, the second in the Badenian, correlated with the TB 2.4 cycle. The late Early Badenian deposition continued in the lower-energy, though occasionally still turbulent environment. Silty sediments with upward increasing content of organic matter indicate shallowing of the basin, until its final diminishing. Layers of fresh-water coal already bear witness to the existence of restricted swamps. After the Early Badenian, the area of the Slovenj Gradec Basin became dry land, exposed to erosion.
The northern slopes of the Vipava Valley are defined by a thrust front of Mesozoic carbonates over Tertiary flysch deposits. These slopes are characterized by a variety of different surface forms, ...among which recent and fossil polygenetic landslides are the most prominent mass movements. We used the height variability method as a morphometric indicator, which proved to be the most useful among the various methods for quantifying and visualizing fossil landslides. Height variability is based on the difference in elevations derived from a high-resolution lidar-derived DEM. Based on geologic field mapping and geomorphometric analysis, we distinguished two main types of movements: structurally induced movement along the fault zone and movements caused by complex Quaternary gravitational slope processes. The most pronounced element is the sliding of the huge rotational carbonate massif, which was displaced partly along older fault structures in the hinterland of fossil rock avalanches and carbonate blocks. In addition to the material properties of the lithology, the level of surface roughness also depends on the depositional processes of the individual sedimentary bodies. These were formed by complex sedimentary events and are intertwined in the geological past. The sedimentary bodies indicate two large fossil rock avalanches, while the smaller gravity blocks indicate translational–rotational slides of carbonate and carbonate breccia.
The Bay of Koper is influenced by agricultural, urban, and port activities, therefore pollution from trace metals is a concern. A total of 20 sediment samples obtained from four 10-cm sediment cores ...were analyzed. Element concentration in the sediment of the bay was determined spatially and temporally from the recent surface to depth. The results were correlated with the composition and diversity of the benthic foraminiferal assemblages. Major element concentrations indicate natural lithogenic origin (which is also confirmed by mineralogical features). The benthic foraminiferal assemblages in sediment samples, although mainly composed of representatives of the Rotaliida, show moderate to high species diversity and are dominated by the pollution tolerant species
Ammonia pakinsoniana
,
Haynesina
sp.,
Valvulineria bradyana
and the non-keel
Elphidium
sp. and subordinated by
Ammonia tepida
and
Haynesina depressula
. Canonical correspondence analysis (CCA) on foraminiferal species and trace element concentrations shows a possible control of some potential toxic elements (i.e., Cu, Ni, Pb, Zr, Cr, As) on the diversity and taxonomic composition of foraminiferal assemblages. Nevertheless, foraminiferal diversity and dominance in the bay are related to sediment characteristics such as sediment grain size, and the amount of terrigenous inflow rather than to the element concentrations of sediments. This study evaluated ecological conditions by using the Foram-AMBi and EcoQS indices. The values of the Foram-AMBI index reflect the good to moderate quality of ecological conditions, whereas high to poor ecological statuses were interpreted by calculating EcoQS.
The Marof archaeological site, which dates back to the 1st–5th centuries ce, lies 10 km SE of the Roman settlement of Emona of Regio X (Venetia and Histria). In addition to other artefacts, several ...stone blocks were recovered. The blocks include worked (shaped) and unworked (natural forms) objects. The provenance of these stones was determined based on their lithological characteristics. The analysis shows that the stone is of Early Jurassic age. While the worked blocks are lithologically diverse and extracted from several sources located within a 10 km radius, the unworked blocks are lithologically homogeneous and originate from the site.
We present an integrated approach to characterizing the Žvepovnik sulphur spring, comprising detailed basic geological (mapping), geochemical (physico-chemical, elementary), isotopic (δ2H, δ18O, ...δ13CDIC, δ34S and 3H), and microbiological analyses. We used a multi-parameter approach to determine the origin of the water (meteoric or deeper infiltration), the origin of the carbon and sulphur, and water retention times. Our special research interest is the origin of the sulphur, as sulphur springs are rare and insufficiently investigated. Our results show that the Žvepovnik spring occurs along the fault near the contact between the dolomite aquifer and overlying shales and volcanoclastic beds. The spring water is the result of the mixing of (1) deeper waters in contact with gypsum and anhydrite and (2) shallow waters originating from precipitation and flowing through the surface carbonate aquifer. The results of δ2H and δ18O confirm local modern precipitation as the main source of the spring. δ13CDIC originates from the degradation of organic matter and the dissolution of carbonates. We therefore propose four possible sources of sulphur: (1) the most probable is the dissolution of gypsum/anhydrite; (2) barite may be a minor source of sulphur; (3) the microbial dissimilatory sulfate reduction; and (4) the oxidation of pyrite as the least probable option.
Submarine springs near Izola, in the Northern Adriatic Sea, appear in funnel-shaped depressions and smell strongly of sulfur. Along the Mediterranean coast there are many submarine karst springs ...containing brackish or fresh water, but submarine sulfur springs are not particularly common. Three submarine sulfur springs and one terrestrial sulfur spring were investigated to better understand the water properties, water–rock interaction within the aquifer, and to explore the origin of the spring water. Groundwater and seawater samples were also collected for comparison. Based on the geological setting, physicochemical parameters, hydrogeochemical data, and stable isotope data (
δ
18
O,
δ
2
H,
δ
13
C
DIC
,
δ
34
S
SO4
,
δ
18
O
SO4
), we can affirm that (1) the large concentration of seawater in the submarine springs samples is due to sampling challenges; (2) springs recharge from precipitation where confined karst aquifers outcrop; (3) deep water circulation is indicated; (4) redox conditions can provide a suitable environment for bacterial reduction of the marine or organic sulfate to the odorous H
2
S; (5) geological data suggests that the coals beneath the alveolinic-nummulitic limestones are the source of sulfur. A multi-parameter and interdisciplinary approach has proven important in assessing submarine sulfur springs affected by seawater input.
The research area is located in south-eastern Slovenia and belongs to the eastern extensions of the Slovenian Basin adjacent to the Adriatic Carbonate Platform. The studied section is 25 m thick and ...consists of grey, brownish and reddish pelagic limestones and calciturbidites, and two bentonite layers 110 and 10 cm thick. Both volcanoclastic horizons consist of greenish, fine-grained muddy material. To date, no other bentonites of similar age are known in the wider Southern Alpine and Dinaridic region. The late Campanian to Campanian/Maastrichtian age of the succession was determined from planktonic foraminifera and calcareous nanoplankton assemblages. XRD analysis revealed the presence of calcite, quartz, muscovite/illite and smectite, which prevails in the clay fraction and is indicative of bentonite clays. We interpret these bentonite horizons as resulting from direct deposition of volcanic ash in a marine environment with a concomitant admixture of detrital material (quartz, muscovite) and later diagenetic carbonatization. The geochemical composition suggests a felsic volcanic origin. The most likely source is the Late Cretaceous–Paleogene bimodal rhyolitic/basaltic volcanism documented along the Sava Suture Zone in present-day Croatia, Bosnia and Herzegovina, Serbia, and North Macedonia. In the Central Apennines three locations with bentonites have been documented. Further spatial and temporal analysis of similar volcanogenic horizons could yield important data on the paleogeographic and tectonic evolution of the Adria/Apulia continental margin.
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•Important discovery of upper Campanian bentonite layers on the eastern Adria margin.•Volcanic ash deposition in a deeper-marine, carbonate dominated environment.•Correlates with Campanian rhyolitic volcanic activity in the Sava Suture Zone.