Gas hydrates stored on continental shelves are susceptible to dissociation triggered by environmental changes. Knowledge of the timescales of gas hydrate dissociation and subsequent methane release ...are critical in understanding the impact of marine gas hydrates on the ocean-atmosphere system. Here we report a methane efflux chronology from five sites, at depths of 220-400 m, in the southwest Barents and Norwegian seas where grounded ice sheets led to thickening of the gas hydrate stability zone during the last glaciation. The onset of methane release was coincident with deglaciation-induced pressure release and thinning of the hydrate stability zone. Methane efflux continued for 7-10 kyr, tracking hydrate stability changes controlled by relative sea-level rise, bottom water warming and fluid pathway evolution in response to changing stress fields. The protracted nature of seafloor methane emissions probably attenuated the impact of hydrate dissociation on the climate system.
There is a lack of high-resolution records of hydroclimate variability in the Eastern Mediterranean from the late glacial and early Holocene. More knowledge of the speed of climate shifts and the ...degree to which they were synchronous with changes in the North Atlantic or elsewhere is required to understand better the controls on Eastern Mediterranean climate. Using endogenic carbonate from a sediment sequence from Nar Gölü, a maar lake in central Turkey, dated by varve counting and uranium-thorium methods, we present high-resolution (∼25 years) oxygen (δ18O) and carbon isotope records, supported by carbonate mineralogy data, spanning the late glacial and Holocene. δ18Ocarbonate at Nar Gölü has been shown previously to be a strong proxy for regional water balance. After a dry period (i.e. evaporation far exceeding precipitation) in the Younger Dryas, the data show a transition into the relatively wetter early Holocene. In the early Holocene there are two drier periods that appear to peak at ∼9.3 ka and ∼8.2 ka, coincident with cooling ‘events’ seen in North Atlantic records. After this, and as seen in other records from the Eastern Mediterranean, there is a millennial-scale drying trend through the Mid Holocene Transition. The relatively dry late Holocene is punctuated by centennial-scale drought intervals, at the times of 4.2 ka ‘event’ and Late Bronze Age societal ‘collapse’. Overall, we show that central Turkey is drier when the North Atlantic is cooler, throughout this record and at multiple timescales, thought to be due to a weakening of the westerly storm track resulting from reduced cyclogenesis in the North Atlantic. However, some features, such as the Mid Holocene Transition and the fact the early Holocene dry episodes at Nar Gölü are of a longer duration than the more discrete ‘events’ seen in North Atlantic records, imply there are additional controls on Eastern Mediterranean hydroclimate.
•Sub-centennial resolution late glacial and Holocene isotope record from Turkey.•Rapid transition from a dry late glacial into a wet early Holocene.•Drier anomalies apparently at times of 9.3 ka and 8.2 ka events but last longer at Nar.•Droughts at times of 4.2 ka event and Late Bronze Age societal ‘collapse’.•Strong teleconnection with North Atlantic, but additional other drivers.
Integrated petrography, mineralogy, geochronology and geochemistry of cold seep carbonate crusts and free gas from the Alvheim channel elucidate diagenetic carbonate precipitation and related seepage ...histories in the central North Sea. Free gas isotope characteristics coupled with carbonate δ13C values as low as −66‰ VPDB, indicate a predominantly microbial methane source with minor thermogenic contribution. We estimate that ~70% of the carbon sequestered into carbonate precipitates was derived from local oxidation of methane. The early stage of crust growth is represented by microcrystalline aragonite and Mg-calcite (10 to 40% mol MgCO3) cementing seafloor sediments consisting of clays, quartz, feldspar, and minor detrital low Mg-calcite and dolomite. Typical association of aragonite cement with coarse-grained detritus may reflect elevated fluid flow and flushing of fine particles prior to cementation close to the seafloor. Middle rare earth element enrichment in early generation microcrystalline cements containing framboidal pyrite indicates diagenetic precipitation within the zone of anaerobic methane oxidation contiguous to iron reduction. The later generation diagenetic phase corresponds to less abundant radial fibrous and botryoidal aragonite which lines cavities developed within the crusts. In contrast to early generation cements, late generation cavity infills have rare earth elements and Y patterns with small negative Ce anomalies similar to seawater, consistent with carbonate precipitation in a more open, seawater dominated system. Aragonite U–Th ages indicate carbonate precipitation between 6.09 and 3.46kyr BP in the northern part of the channel, whereas in the southern part precipitation occurred between 1.94 and 0.81kyr BP reflecting regional changes in fluid conduit position.
Display omitted
•Approximately 70% of carbon in carbonates is derived from microbial methane carbon.•Distinct REY patterns differ with carbonate phases rather than mineralogy.•U–Th ages constrain two distinct seepage events between 6.1 and 0.8ka BP.•Late generation aragonites correspond to carbonate hosted methanotrophy.
Submarine groundwater discharge could impact the transport of critical solutes to the ocean. However, its driver(s), significance over geological time scales, and geographical coverage are poorly ...understood. We characterize a submarine groundwater seep from the continental slope off northern Norway where substantial amount of meteoric water was detected. We reconstruct the seepage history from textural relationships and U‐Th geochronology of authigenic minerals. We demonstrate how glacial‐interglacial dynamics have promoted submarine groundwater circulation more than 100 km offshore and result in high fluxes of critical solutes to the ocean. Such cryosphere‐hydrosphere coupling is likely common in the circum‐Arctic implying that future decay of glaciers and permafrost in a warming Arctic is expected to attenuate such a coupled process and thus decreases the export of critical solutes.
Plain Language Summary
Occurrence of meteoric groundwater (freshwater originated from precipitation such as rain and snow) in the global ocean is an unexpected but seemingly common phenomenon. Here, we report evidence for meteoric groundwater flow at ~800‐m water depth from the coast of northern Norway. Dating of the chemically formed carbonate rocks on the seafloor, an oxidation product of methane, reveals that the groundwater flow was strongest when large ice sheets occupied the nearby shelf. Our results confirm the temporal and geographical scales of meteoric groundwater flow in the Arctic region and highlight its impact on carbon cycling and ocean chemistry.
Key Points
We document the connection between glacial dynamics and the discharge of meteoric water from the eastern Norwegian Sea
A large quantity of critical solutes discharge to the ocean as a result of water circulation
Offshore presence/discharge of freshwater is a common phenomenon in the circum‐Arctic Ocean that have profound impact on ocean chemistry
A significant discrepancy of up to 0.6 Myr exists between radio‐isotopically calibrated and astronomically tuned time scales of the late Eocene‐Oligocene. We explore the possible causes of this ...discrepancy through the acquisition of “high‐precision” 206Pb/238U dating of zircons from 11 volcanic ash beds from the Umbria‐Marche sedimentary succession, which hosts the Global Stratotype Section and Point for the base of the Oligocene. Our results indicate that the four 40Ar/39Ar dates from the Umbria‐Marche succession, which underpin the late Eocene‐Oligocene portion of the Paleogene geomagnetic polarity time scale in the 2012 edition of the Geological Time Scale, are anomalously old by up to 0.5 Myr. Conversely, when integrated with the established magnetic polarity record of the Umbria‐Marche succession, 206Pb/238U (zircon) data from this study result in Oligocene magnetic reversal ages that are generally equivalent to those obtained through the tuning of Ocean Drilling Program (ODP) Site 1218 (equatorial Pacific). Furthermore, our results indicate that the late Eocene tuning of ODP Site 1218, and International Ocean Discovery Program (IODP) Sites U1333–1334 (equatorial Pacific), to the 405 kyr eccentricity signal is accurate, at least back to 36 Ma. Propagating the full uncertainty of our radio‐isotopic data set and, where appropriate, taking into account locally derived astronomical time scales, we arrive at an age of 34.09 ± 0.08 Ma for the Eocene‐Oligocene boundary and 28.11 ± 0.17 Ma for the base of the Chattian.
Key Points
Published 40Ar/39Ar data from biotite‐rich layers from the Umbria‐Marche sedimentary succession too old by approximately 0.5 Myr
U‐Pb (zircon) dating of the Umbria‐Marche biotite‐rich layers in agreement with the astronomically tuned Oligocene time scale
New U‐Pb calibrated age for the Eocene‐Oligocene boundary (34.09 ± 0.08 Ma) and the Rupelian‐Chattian boundary (28.11 ± 0.17 Ma)
The origin of modern seafloor methane emissions in the Barents Sea is tightly connected to the glacio-tectonic and oceanographic transformations following the last ice age. Those regional events ...induced geological structure re-activation and destabilization of gas hydrate reservoirs over large areas of the European continental margins, sustaining widespread fluid plumbing systems. Despite the increasing number of new active seep discoveries, their accurate geochronology and paleo-dynamic is still poorly resolved, thus hindering precise identification of triggering factors and mechanisms controlling past and future seafloor emissions. Here, we report the distribution, petrographic (thin section, electron backscatter diffraction), isotopic (δ
13
C, δ
18
O) and lipid biomarker composition of methane-derived carbonates collected from Leirdjupet Fault Complex, SW Barents Sea, at 300 m depth during an ROV survey in 2021. Carbonates are located inside a 120 x 220 m elongated pockmark and form <10 m
2
bodies protruding for about 2 m above the adjacent seafloor. Microstructural analyses of vein-filling cements showed the occurrence of three–five generations of isopachous aragonitic cement separated by dissolution surfaces indicative of intermittent oxidizing conditions. The integration of phase-specific isotopic analysis and U/Th dating showed δ
13
C values between −28.6‰ to −10.1‰ and δ
18
O between 4.6‰ and 5.3‰, enabling us to track carbonate mineral precipitation over the last ∼8 ka. Lipid biomarkers and their compound-specific δ
13
C analysis in the bulk carbonate revealed the presence of anaerobic methanotrophic archaea of the ANME-2 clade associated with sulfate-reducing bacteria of the Seep-SRB1 clade, as well as traces of petroleum. Our results indicate that methane and petroleum seepage in this area followed a similar evolution as in other southernmost Barents Sea sites controlled by the asynchronous deglaciation of the Barents Sea shelf, and that methane-derived carbonate precipitation is still an active process at many Arctic locations.
The hydrocarbon seepage chronology during deglaciation across the formerly glaciated Barents Sea was established using uranium-thorium (U–Th) dating of seep carbonates. Seep carbonates were sampled ...with remotely operated vehicles (ROV) from the seafloor at three active hydrocarbon seeps (water depth 156–383 m), located in the north-west (Storfjordrenna), north-central (Storbanken High), and south-west (Loppa High) Barents Sea. Overall, the U–Th dates range from 13.5 to 1.2 thousand years (ka) before present, indicating episodic seep carbonate formation since the late Pleistocene throughout the Holocene. The new U–Th dates indicate protracted post-glacial gas seepage, congruent with previously published seep carbonate ages from the south-west Barents Sea. Gas hydrate dissociation and associated seep carbonate formation occurred at Storfjordrenna between ≈6 and 1.2 ka, and around 13.5 and 6 ka at Storbanken. Early and late Holocene seep carbonate ages from Loppa High support post-glacial seismic activity as potential seepage trigger mechanism.
Multibeam bathymetric mapping of the Santa Monica Basin in the eastern Pacific has revealed the existence of a number of elevated bathymetric features, or mounds, harboring cold seep communities. ...During 2013-2014, mounds at ~600 m water depth were observed for the first time and sampled by Monterey Bay Aquarium Research Institute’s ROV Doc Ricketts. Active cold seeps were found, but surprisingly one of these mounds was characterized by massive deposits composed of fossil serpulid worm tubes (Annelida: Serpulidae) exhibiting various states of mineralization by authigenic carbonate. No living serpulids with equivalent tube morphologies were found at the site; hence the mound was termed ‘Fossil Hill’. In the present study, the identity of the fossil serpulids and associated fossil community, the ages of fossils and authigenic carbonates, the formation of the fossil serpulid aggregation, and the geological structure of the mound are explored. Results indicate that the tubes were most likely made by a deep-sea serpulid lineage, with radiocarbon dating suggesting that they have a very recent origin during the Late Pleistocene, specifically to the Last Glacial Maximum ~20,000 years ago. Additional U-Th analyses of authigenic carbonates mostly corroborate the radiocarbon dates, and also indicate that seepage was occurring while the tubes were being formed. We also document similar, older deposits along the approximate trajectory of the San Pedro Basin Fault. We suggest that the serpulid tube facies formed in situ, and that the vast aggregation of these tubes at Fossil Hill is likely due to a combination of optimal physical environmental conditions and chemosynthetic production, which may have been particularly intense as a result of sea-level lowstand during the Last Glacial Maximum.
Sediment-filled caves, conduits and voids are common in many karst regions. These voids and the sediment they contain are important palaeoclimatic and palaeoenvironmental archives, but often have an ...adverse impact on engineering projects, mineral extraction and hydrogeology. Most studies into fluvial sedimentation in karst aquifers have focussed on more traditional karst areas. However, the nature and extent of fluvial sedimentation within caves and conduits in the important Upper Cretaceous Chalk Group aquifer (NW and Central Europe), and their impacts are less well known. This is principally due to a lack of accessible Chalk caves with exposed 3D sediment archives for study. Fortunately, the discovery of the World's longest Chalk cave system by underground quarrying at Caumont in the Seine valley near Rouen, northern France, has exposed numerous sediment sections along 2.4 km of passage. Detailed analysis of the stratigraphy, mineralogy, sedimentology, provenance and the chronology of the exposed sediments including the novel use of Gamma-ray spectrometry, reveals complex stratigraphy and lateral facies distribution along a karst conduit. The depositional model comprises five allostratigraphical units since the mid-Chibanian, separated by periods of erosion. The units are derived from hyper-concentrated and sediment-laden flows, and include thalweg, channel, slackwater, backswamp speleothem facies and debris flow deposits that are interbedded. Speleothems precipitated during MIS 7, 6, 5e and 1. During MIS 7–6, detrital sediments filled almost all Chalk conduits, similar to other caves in the European Atlantic Margin, coevally with the Penultima (Saalian) Glacial Cycle and a maximum of the Earth eccentricity. Detrital sediments are derived from the erosion of local Chalk bedrocks as well as metamorphic and igneous rocks of remote areas, such as Morvan massif and Massif Central. The depositional model is consistent with the conception of the Chalk as a karst aquifer. Significant sediment aggradation caused upwards dissolution (paragenesis), conduit occlusion and subsequent genesis of new conduits by flow diversion, potentially altering the functioning of the chalk aquifer and the interpretation of Chalk hydrogeology (e.g., dye-tracing tests).
•First identification of Quaternary fluvial facies association within a Chalk aquifer.•Novel application of gamma-ray spectrometry for stratigraphic correlation in caves.•Sedimentary evidence supports the conception of Chalk aquifer as a karst media.•Chalk cave deposition depends on conduit network, provenance and paleoclimate.•Cave detrital sedimentation impacts on Chalk aquifers.
Pleistocene glacial activity was a major influence on runoff and sediment supply in many river systems across the Mediterranean. The geomorphological impacts of changes in sediment supply between ...glaciated headwater terrains and downstream depocentres spanning several glacial cycles are, however, poorly understood. By applying uranium-series and optically stimulated luminescence dating to fluvial and glacial sediments preserved on Mount Chelmos (2355 m a.s.l.) in southern Greece, we show how changes in the long-term coupling between glacial and fluvial systems are preserved within a major glaciofluvial outwash fan system that functioned during multiple cold stages. We also present evidence in the form of a cemented till unit, stratigraphically below younger Middle Pleistocene glacial deposits, yielding a U-series age close to the limit of the technique, indicating glaciation during Marine Isotope Stage (MIS) 16 - one of the most severe cold stages recorded in the Mediterranean. This is the first time such early glaciation has been directly recorded in Greece and the wider Balkans and is defined here as the Valvousian Stage based on glacial deposits on Mount Chelmos. Geomorphological and geochronological data point to the formation of a more extensive plateau ice field over Chelmos during MIS 12, another severe glacial period in the Balkans that corresponds with the Skamnellian Stage glaciation of Northern Greece. During this phase, very strong coupling of glacial and fluvial systems led to meltwater flood events transferring large volumes of sediment to lower valley zones culminating in the formation of an extensive glaciofluvial outwash fan complex and glaciofluvial terraces. A smaller plateau ice field during MIS 6 and localised valley glaciers between MIS 5d to 5c correlate with the Vlasian and early Tymphian Stage glaciations in Greece, respectively. The delivery of much less meltwater and sediment through a single valley during MIS 6 and MIS 5b to MIS 4 signalled the transition to progressively weaker glacial and fluvial system coupling. After MIS 4 the uncoupling of depositional zones from sediment sources in glaciated catchments led to fluvial incision of glaciofluvial outwash deposits in several valleys. Despite this incision, the glaciofluvial outwash fans preserve a record of glacial and fluvial system interactions during the Middle Pleistocene and early stages of the Late Pleistocene.
•U-series ages provide the first chronology for moraines and glaciofluvial outwash in southern Greece.•U-series ages indicate that Mount Chelmos was glaciated multiple times during the Pleistocene.•Glaciation during MIS 12 marked a period of very strong glacial-fluvial system coupling.•Glacial–fluvial system coupling was controlled by the preferential transfer of sediment through specific valley systems.•Glaciofluvial outwash fans preserve a detailed record of glacial-fluvial system interactions.
PDF
