By investigating the petrology and chemical composition of type II (FeO-rich) chondrules in the Mighei-like carbonaceous (CM) chondrites we constrain their thermal histories and relationship to the ...Ornans-like carbonaceous (CO) chondrites. We identified FeO-rich relict grains in type II chondrules by their Fe/Mn ratios; their presence indicates chondrule recycling among type II chondrules. The majority of relict grains in type II chondrules are FeO-poor olivine grains. Consistent with previous studies, chemical similarities between CM and CO chondrite chondrules indicate that they had similar formation conditions and that their parent bodies probably formed in a common region within the protoplanetary disk. However, important differences such as mean chondrule size and the lower abundance of FeO-poor relicts in CM chondrite type II chondrules than in CO chondrites suggest CM and CO chondrules did not form together and they likely originate from distinct parent asteroids.
Despite being aqueously altered, many CM chondrites contain pre-accretionary anhydrous minerals (i.e., olivine) that are among the least thermally metamorphosed materials in chondrites according to the Cr2O3 content of their ferroan olivine. The presence of these minimally altered pre-accretionary chondrule silicates suggests that samples to be returned from aqueously altered asteroids by the Hayabusa2 and OSIRIS-REx asteroid sample return missions, even highly hydrated, may contain silicates that can provide information about the pre-accretionary histories and conditions of asteroids Ryugu and Bennu, respectively.
The Meteoritical Bulletin, No. 111 Gattacceca, Jérôme; McCubbin, Francis M.; Grossman, Jeffrey N. ...
Meteoritics & planetary science,
June 2023, 2023-06-00, 20230601, 2023-06, Volume:
58, Issue:
6
Journal Article
Peer reviewed
Open access
Meteoritical Bulletin 111 contains the 3094 meteorites approved by the Nomenclature Committee of the Meteoritical Society in 2022. It includes 11 falls (Antonin, Botohilitano, Cranfield, Golden, ...Great Salt Lake, Longde, Msied, Ponggo, Qiquanhu, Tiglit, Traspena), with 2533 ordinary chondrites, 165 HED, 123 carbonaceous chondrites (including 4 ungrouped), 82 lunar meteorites, 28 Rumuruti chondrites, 27 iron meteorites, 23 ureilites, 22 mesosiderites, 22 Martian meteorites, 21 primitive achondrites (one ungrouped), 17 ungrouped achondrites, 13 pallasites, 7 enstatite achondrites, 6 enstatite chondrites, and 5 angrites. Of the meteorites classified in 2022, 1787 were from Antarctica, 1078 from Africa, 180 from South America, 34 from Asia, 6 from North America, 4 from Europe, and 1 from Oceania.
Carbonaceous chondrites are meteoritic fragments of asteroids that avoided the geological reprocessing of larger planets and allow laboratory probing of early solar-nebula materials. Among these, ...Renazzo-type (CR) chondrites found in Antarctica appear remarkably pristine and are distinguished by abundant organic materials and water-soluble molecules such as amino acids and ammonia. We present a comprehensive analysis of the organic composition of selected CR meteorites of different petrographic classification and compare compounds’ abundance and distribution as they may relate to asteroidal aqueous processing and concomitant evolution of the mineral phases. We found that several CR compounds such as amino acids and sugar alcohols are fully represented in stones with no or minimal water exposure indicating a formation that, if solar, preceded parent body processes. The most pristine CRs also revealed natal enantiomeric excesses (ee) of up to 60%, much larger than ever recorded. However, aqueous alteration appears to affect CR soluble organic composition and abundances, in particular some diastereomeric amino acids may gauge its extent by the consequent racemization of their ee .
A close relationship between CM and CO chondrites has been suggested by previous petrologic and isotopic studies, leading to the suggestion that they may originate from similar precursor materials or ...even a common parent body. In this study, we evaluate the genetic relationship between CM and CO chondrites using Ti, Cr, and O isotopes. We first provide additional constraints on the ranges of ε50Ti and ε54Cr values of bulk CM and CO chondrites by reporting the isotopic compositions of CM2 chondrites Murchison, Murray, and Aguas Zarcas and the CO3.8 chondrite Isna. We then report the ε50Ti and ε54Cr values for several ungrouped and anomalous carbonaceous chondrites that have been previously reported to exhibit similarities to the CM and/or CO chondrite groups, including Elephant Moraine (EET) 83226, EET 83355, Grosvenor Mountains (GRO) 95566, MacAlpine Hills (MAC) 87300, MAC 87301, MAC 88107, and Northwest Africa (NWA) 5958, and the O-isotope compositions of a subset of these samples. We additionally report the Ti, Cr, and O isotopic compositions of additional ungrouped chondrites LaPaz Ice Field (LAP) 04757, LAP 04773, Lewis Cliff (LEW) 85332, and Coolidge to assess their potential relationships with known carbonaceous and ordinary chondrite groups. LAP 04757 and LAP 04773 exhibit isotopic compositions indicating they are low-FeO ordinary chondrites. The isotopic compositions of Murchison, Murray, Aguas Zarcas, and Isna extend the compositional ranges defined by the CM and CO chondrites in ε50Ti versus ε54Cr space. The majority of the ungrouped carbonaceous chondrites with documented similarities to the CM and/or CO chondrites plot outside the CM and CO group fields in plots of ε50Ti versus ε54Cr, Δ17O versus ε50Ti, and Δ17O versus ε54Cr. Therefore, based on differences in their Ti, Cr, and O isotopic compositions, we conclude that the CM, CO, and ungrouped carbonaceous chondrites likely represent samples of multiple distinct parent bodies. We also infer that these parent bodies formed from precursor materials that shared similar isotopic compositions, which may indicate formation in regions of the protoplanetary disk that were in close proximity to each other.
Sulfide minerals occur in many types of extraterrestrial samples and are sensitive indicators of the conditions under which they formed or were subsequently altered. Here we report that chemical and ...petrographic analyses of Fe,Ni sulfides can be used to determine the metamorphic type of the host LL chondrite, and constrain their alteration conditions. Our data show that the major- and minor-element compositions of the pyrrhotite-group sulfides (dominantly troilite) and pentlandite vary with degree of thermal metamorphism experienced by their host chondrite. We find that Fe,Ni sulfides in LL3 chondrites formed during chondrule cooling prior to accretion, whereas those in LL4 to LL6 chondrites formed during cooling after thermal metamorphism in the parent body, in agreement with previous work. High degrees of shock (i.e., ≥S5) caused distinct textural, structural, and compositional changes that can be used to identify highly shocked samples. Distinct pyrrhotite-pentlandite textures and minerals present in Appley Bridge (LL6) suggest that they cooled more slowly and therefore occurred at greater depth(s) in the host parent body than those of the other metamorphosed LL chondrites studied here. Sulfides in all LL chondrites studied formed under similar sulfur fugacities, and the metamorphosed LL chondrites formed under similar oxygen fugacities. The data reported here can be applied to the study of other LL chondrites and to sulfides in samples of asteroid Itokawa returned by the Hayabusa mission in order to learn more about the formation and alteration history of the LL chondrite parent body.
•We present the chemical compositions of the pyrrhotite-group sulfides in chondrites.•The at.% Fe/S ratio of pyrrhotite can trend with thermal or aqueous alteration.•The at.% Fe/S ratio trend varies ...among different chondrite groups.•There is a universal trend between the Fe/S ratio and oxygen fugacity of formation.•This data can be used to determine formation conditions of asteroid returned samples.
Determining compositional trends among individual minerals is key to understanding the thermodynamic conditions under which they formed and altered, and is also essential to maximizing the scientific value of small extraterrestrial samples, including returned samples and meteorites. Here we report the chemical compositions of Fe-sulfides, focusing on the pyrrhotite-group sulfides, which are ubiquitous in chondrites and are sensitive indicators of formation and alteration conditions in the protoplanetary disk and in small Solar System bodies. Our data show that while there are trends with the at.% Fe/S ratio of pyrrhotite with thermal and aqueous alteration in some meteorite groups, there is a universal trend between the Fe/S ratio and degree of oxidation. Relatively reducing conditions led to the formation of troilite during: (1) chondrule formation in the protoplanetary disk (i.e., pristine chondrites) and (2) parent body thermal alteration (i.e., LL4 to LL6, CR1, CM, and CY chondrites). Oxidizing and sulfidizing conditions led to the formation of Fe-depleted pyrrhotite with low Fe/S ratios during: (1) aqueous alteration (i.e., CM and CI chondrites), and (2) thermal alteration (i.e., CK and R chondrites). The presence of troilite in highly aqueously altered carbonaceous chondrites (e.g., CY, CR1, and some CM chondrites) indicates they were heated after aqueous alteration. The presence of troilite, Fe-depleted pyrrhotite, or pyrite in a chondrite can provide an estimate of the oxygen and sulfur fugacities at which it was formed or altered. The data reported here can be used to estimate the oxygen fugacity of formation and potentially the aqueous and/or thermal histories of sulfides in extraterrestrial samples, including those returned by the Hayabusa2 mission and due to be returned by the OSIRIS-REx mission in the near future.
To better understand the environment of chondrule formation and constrain the O-isotope composition of the ambient gas in the Renazzo-like carbonaceous (CR) chondrite chondrule-forming region, we ...studied the mineralogy, petrology, and in situ O-isotope compositions of olivine in 11 barred olivine (BO) chondrules and pyroxene and silica in three type I porphyritic chondrules from the CR chondrites Gao-Guenie (b), Graves Nunataks (GRA) 95229, Pecora Escarpment (PCA) 91082, and Shişr 033. BO chondrules experienced a higher degree of melting than porphyritic chondrules, and therefore, it has been hypothesized that they more accurately recorded the O-isotope composition of the gas in chondrule-forming regions. We studied the O-isotope composition of silica as it has been hypothesized to have formed via direct condensation from the gas.
BO chondrules constitute ∼4% of the total CR chondrule population by volume. On a three-isotope oxygen diagram (δ17O vs. δ18O), olivine phenocrysts in type I and type II BO chondrules plot along ∼slope-1 line; with the exception of a type II BO chondrule that plots along ∼slope-0.5 line. Olivine phenocrysts in type I and type II BO chondrules have similar but more restricted ranges of Δ17O values (∼−3.8‰ to ∼−1.3‰ and ∼−0.8‰ to ∼+1.4‰, respectively) than those in type I and type II porphyritic chondrules (∼−4.6‰ to ∼−0.3‰ and ∼−1.8‰ to ∼+0.9‰, respectively). The observation that olivine grains in type I BO chondrules have similar chemical and O-isotope compositions to those of olivine in their porphyritic counterparts argues against the hypothesis that olivine grains in type I porphyritic chondrules are xenocrysts and represent relict fragments of early formed planetesimals.
The compositional and O-isotope data suggest that BO chondrules experienced more extensive, but incomplete exchange with the ambient gas than porphyritic chondrules. We suggest that CR chondrules formed from relatively 16O-enriched solids in the presence of relatively 16O-depleted gaseous H2O. The O-isotope compositions of chondrule olivine likely result from differences in the O-isotope composition of both the chondrule precursors and the ambient gas during chondrule formation. The inferred O-isotope composition of this gas (Δ17O ranges from ∼−3‰ to +3‰) is inconsistent with a high abundance of water from the outer Solar System, which has been predicted to be isotopically heavy.
The background temperature of the protoplanetary disk is a fundamental but poorly constrained parameter that strongly influences a wide range of conditions and processes in the early Solar System, ...including the widespread process(es) by which chondrules originate. Chondrules, mm-scale objects composed primarily of silicate minerals, were formed in the protoplanetary disk almost entirely during the first four million years of Solar System history but their formation mechanism(s) are poorly understood. Here we present new constraints on the sub-silicate solidus cooling rates of chondrules at <873 K (600 °C) using the compositions of sulfide minerals. We show that chondrule cooling rates remained relatively rapid (∼100 to 101 K/hr) between 873 and 503 K, which implies a protoplanetary disk background temperature of <503 K (230 °C) and is consistent with many models of chondrule formation by shocks in the solar nebula, potentially driven by the formation of Jupiter and/or planetary embryos, as the chondrule formation mechanism. This protoplanetary disk background temperature rules out current sheets and resulting short-circuit instabilities as the chondrule formation mechanism. More detailed modeling of chondrule cooling histories in impacts is required to fully evaluate impacts as a chondrule formation model. These results motivate further theoretical work to understand the expected thermal evolution of chondrules at ≤873 K under a variety of chondrule formation scenarios.
•We present cooling rates of chondrules at <873 K (600 °C) using sulfide minerals.•These are the lowest temperature cooling rates determined for chondrules to date.•These cooling rates are relatively rapid (∼100 to 101 K/hr) between 873 and 503 K.•The rates imply a protoplanetary disk background temperature of <503 K (230 °C).•These results motivate further theoretical work for chondrule formation models.
To better understand the effects of aqueous alteration in the Renazzo-like carbonaceous (CR) chondrite parent asteroid, a minor body in the early Solar System, we studied the petrology and O-isotope ...compositions of fine-grained matrix from 14 different CR chondrites. The O-isotope compositions of matrix from Queen Alexandra Range 99177 confirm that this sample is the least aqueously altered CR chondrite, provides the best approximation of the primary anhydrous matrix, and suggests matrix is not a byproduct of chondrule formation. Matrix O-isotope compositions within individual CR chondrites are heterogeneous, varying up to ∼5‰ in both δO18 and δO17, as a result of the heterogeneous nature of the matrix and diverse range of aqueous alteration recorded by each sample. Aqueous alteration resulted in matrix that is progressively more 16O-depleted and Ca-carbonate rich. Due to the fine-grained nature of matrix its O-isotope composition is a more sensitive indicator of a chondrite's overall degree of aqueous alteration than whole-rock O-isotope compositions, which are typically dominated by the compositions of type I (FeO-poor) chondrule phenocrysts. Petrographic signatures correlate with the degree of aqueous alteration and the wide range of matrix O-isotope compositions indicate that some regions of the CR chondrite parent asteroid were relatively dry, while others were heavily hydrated with water. The O-isotope composition of aqueously altered matrix is consistent with asteroidal water being near ΔO17∼0‰, which suggests an inner Solar System origin for the water. The diverse range of aqueous alteration recorded by a single asteroid has a range of implications for spectral studies of the asteroid belt, and the arrival of Dawn at 1 Ceres, Hayabusa-2 at 162173 1999 JU3, and OSIRIS-REx at 101955 Bennu.
•We present the O-isotope compositions and petrology of CR chondrite matrix.•CR chondrite matrix is a distinct component, not a byproduct of chondrule formation.•Fine-grained matrix is a sensitive indicator of aqueous alteration.•More aqueously altered matrix is relatively 16O-depleted and Ca-carbonate rich.•The CR chondrite parent asteroid recorded a diverse range of aqueous alteration.
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