Inelastic interactions of quantum systems with the environment usually wash coherent effects out. In the case of Friedel oscillations, the presence of disorder leads to a fast decay of the ...oscillation amplitude. Here we show both experimentally and theoretically that in three-dimensional topological insulator Bi2Te3 there is a nesting-induced splitting of coherent scattering vectors which follows a peculiar evolution in energy. The effect becomes experimentally observable when the lifetime of quasiparticles shortens due to disorder. The amplitude of the splitting allows an evaluation of the lifetime of the electrons. A similar phenomenon should be observed in any system with a well-defined scattering vector regardless of its topological properties.
The Cosmic Microwave Background (CMB) radiation is the only observable that allows studying the earliest stage of the Universe. Radioastronomy instruments for CMB investigation require low working ...temperatures around 100 mK to get the necessary sensitivity. On-chip electron cooling of receivers is a pathway for future space missions due to problems of dilution fridges at low gravity. Here, we demonstrate experimentally that in a Cold-Electron Bolometer (CEB) a theoretical limit of electron cooling down to 65 mK from phonon temperature of 300 mK can be reached. It is possible due to effective withdrawing of hot electrons from the tunnel barrier by double stock, special traps and suppression of Andreev Joule heating in hybrid Al/Fe normal nanoabsorber.
It is well known that superconductivity in quasi-one-dimensional (Q1D) materials is hindered by large fluctuations of the order parameter. They reduce the critical temperature and can even destroy ...the superconductivity altogether. Here it is demonstrated that the situation changes dramatically when a Q1D pair condensate is coupled to a higher-dimensional stable one, as in recently discovered multiband Q1D superconductors. The fluctuations are suppressed even by vanishingly small pair-exchange coupling between different band condensates and the superconductor is well described by the mean field theory. In this case the low dimensionality effects enhance the coherence of the system instead of suppressing it. As a result, the critical temperature of the multiband Q1D superconductor can increase by orders of magnitude when the system is tuned to the Lifshitz transition with the Fermi level close to the edge of the Q1D band.
Cluster formation is a focus of interdisciplinary research in both chemistry and physics. Here we discuss the exotic example of this phenomenon in the vortex matter of a thin superconductor. In ...superconducting films, the clustering takes place because of particular properties of the vortex interactions in the crossover or intertype regime between superconductivity types I and II. These interactions are controlled by the two parameters that are responsible for the crossover, Ginzburg–Landau parameter κ, which specifies the superconducting material of the film, and film thickness d, which controls effects due to stray magnetic fields outside the sample. We demonstrate that their competition gives rise to a complex spatial dependence of the interaction potential between vortices, favoring the formation of chainlike vortex clusters.
The presence of magnetic fields and/or transport currents can cause penetration of vortices in superconductors. Their motion leads to dissipation and resistive state arises, which in turn strongly ...affects the performance of superconducting devices such as single-photon and single-electron detectors. Therefore, an understanding of the dissipation mechanisms in mesoscopic superconductors is not only of fundamental value but also very important for further technological advances. In the present work, we analyzed the contributions and interplay of the dissipative mechanisms due to the locally induced electric field and an intrinsic relaxation of the superconducting order parameter, Ψ, in mesoscopic samples by using the time-dependent Ginzburg–Landau theory. Although often neglected, we show that the dissipated energy due to relaxation of Ψ must be taken into account for an adequate description of the total dissipated energy. The local increase of the temperature due to vortex motion and its diffusion in the sample were also analyzed, where the joint effect of thermal relaxation and vortex dynamics plays an important role for the dissipative properties presented by the superconducting systems.
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•Dissipation mechanisms in superconductors are size-dependent.•Relaxation of the order parameter influences local temperature increases.•The generalization of the free energy theorem is of experimental relevance.
Heterojunctions of metal oxides have attracted a great deal of attention as photo (electro) catalysts owing to their excellent photoactivity. While multiple fundamental studies have been dedicated to ...heteroaggregation, self-assembly of oppositely charged particles to obtain heterojunctions for energy applications has been underexplored. Herein, we report the synthesis of ZnO-TiO2 heterojunctions using the electrostatic self-assembly approach. The synthesized ZnO-TiO2 heterojunctions were characterized by using multiple experimental techniques. Density functional theory calculations were conducted to establish the heterojunction formation mechanism and electronic properties. The ZnO-TiO2 nanohybrid was tested for the photodegradation of rhodamine B dye and water splitting applications. The photocatalytic performance of the ZnO-TiO2 nanohybrid is 3.5 times higher than that of bare ZnO. In addition, the heterostructure exhibited an excellent photocurrent density of 2.4 mA cm–2 at a low onset potential during photoelectrochemical oxygen evolution. The performance improvements are attributed to the formation of the type II heterojunction between ZnO and TiO2, which suppresses carrier recombination and enhances carrier transport, boosting the catalytic activity.
Further improving the activity and selectivity of photocatalytic CO2 reduction remains a challenge. Herein, we propose a new strategy for synergistically promoting photocatalytic CO2 reduction by ...combining two-dimensional (2D) ferroelectric polarization and single-atom catalysis. Our calculations showed that the ferroelectric polarization of CuBiP2Se6 provides the internal driving force for the separation and migration of photogenerated carriers, which provides a prerequisite for enhancing the photocatalytic efficiency. In addition, the introduction of single Ag atoms can act as an electron reservoir to significantly modify the bonding configurations on the surface through proper static electron transfer, thus effectively promoting the adsorption and activation of CO2 molecules. More importantly, we found that switching the ferroelectric polarization can synergistically optimize the limiting potential as well as control the final products. This study provides a new approach for enhancing the catalytic activity and selectivity of photocatalytic CO2 reduction.
Further improving the activity and selectivity of photocatalytic CO
reduction remains a challenge. Herein, we propose a new strategy for synergistically promoting photocatalytic CO
reduction by ...combining two-dimensional (2D) ferroelectric polarization and single-atom catalysis. Our calculations showed that the ferroelectric polarization of CuBiP
Se
provides the internal driving force for the separation and migration of photogenerated carriers, which provides a prerequisite for enhancing the photocatalytic efficiency. In addition, the introduction of single Ag atoms can act as an electron reservoir to significantly modify the bonding configurations on the surface through proper static electron transfer, thus effectively promoting the adsorption and activation of CO
molecules. More importantly, we found that switching the ferroelectric polarization can synergistically optimize the limiting potential as well as control the final products. This study provides a new approach for enhancing the catalytic activity and selectivity of photocatalytic CO
reduction.
A theoretical model for an electrical discharge in a cavitating liquid is developed and compared with experiments for the optimization of the water treatment device. The calculations based on ...solution of the NoltingkNeppiras equation support the hypothesis that the electric field promotes the formation of vapor microchannels inside a liquid gap between the electrodes, where at a low gas pressure Paschen’s conditions of rupture and abnormal glow discharge maintenance in those microchannels are fulfilled. Theoretical analysis of the cavitation processes and the discharge formation processes is in qualitative agreement with the experimental data obtained in this work in a water treatment device using a hydrodynamic emitter. The following graphic illustrates the experimental setup: (1) feeding tank, (2) hydrodynamic emitter, (3) zone of cavitation inside the plasma reactor, (4) high-frequency generator of electric impulses, and (5) outlet.
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