In this study, a micro-porous titania (TiO sub(2)) layer was synthesized on commercial pure Ti using the microplasma oxidation (MPO) method. Ti/Ti, MPO-TiO sub(2) (MPO-Ti)/Ti and MPO-Ti/MPO-Ti were ...successfully active soldered using this Sn3.5Ag4Ti(Ce) active filler metal at 250 degree C for 60 s. The microstructure and mechanical properties of the active soldered joints were investigated. Results indicate that trace Ce reacts with the MPO-Ti layer to form both CeO sub(2) and Ti, corresponding to the reaction between Ti and Sn to form Ti sub(6)Sn sub(5), and nano-sizes Ag sub(3)Sn phases adsorb at the active filler/MPO-Ti interfaces. Shear strength of soldered Ti/Ti, MPO-Ti/Ti, and MPO-Ti/MPO-Ti specimens were measured to be 16.3 plus or minus 1.39, 11.3 plus or minus 1.56, and 9.5 plus or minus 1.24 MPa, respectively. The fracture of Ti/Ti specimen was found to produce along the Ti sub(2)Sn sub(3) and solder matrix. In the MPO-Ti/MPO-Ti specimen, the fractures occurred through the active filler/MPO-Ti interface. In the MPO-Ti/Ti specimen, the fracture failure mode transferred from MPO layer/Ti interfacial fracture to fracture within the active filler.
Due to the strong horizontal orientation tendency of hexagonal boron nitride (hBN) platelets, hBN/polymer composites generally exhibit high in-plane thermal conductivity while low through-plane ...thermal conductivity. In this work, hBN platelets and aluminum nitride (AlN) particles are used as hybrid fillers to improve the thermal conductivity of polytetrafluoroethylene (PTFE). AlN particles effectively disrupt the alignment of hBN platelets along the lateral direction during the compression processing, which can be proved by the results of SEM and XRD. At 30 vol% filler loading, a high through-plane thermal conductivity as 1.04 W/mK is achieved, which is 3.8 times that of neat PTFE. The significantly increased thermal conductivity is related not only to the synergetic effect of hybrid fillers, but also the reduced in-plane orientation degree of hBN. Hashin-Shtrikman model is also used to quantify the filler connectivity within polymer matrix. The result suggests that filler morphology and orientation influence the filler connectivity and both control the effective thermal conductivity of composites.
Cosmetic fillers are frequently used these days for enhancing beauty and to treat wrinkles or sagging skin. However, information on the history of injections may be difficult to obtain, and there is ...a growing number of reports on complications with these agents. In contrast to other imaging techniques, sonography has been successfully used for detecting and identifying common types of cosmetic fillers and has become the first-line imaging modality to deal with these exogenous components.
Dental resin composites (DRCs) with diverse fillers added are widely-used restorative materials to repair tooth defects. The addition of fillers brings an improvement in the mechanical properties of ...DRCs. In the past decade, diverse fillers have emerged. However, the change of emerging fillers mainly focuses on the chemical composition, while the morphologic characteristics changes are often ignored. The fillers with new morphologies not only have the advantages of traditional fillers (particles, fibrous filler, etc.), but also endow some additional functional characteristics (stronger bonding ability to resin matrix, polymerization resistance, and wear resistance, drug release control ability, etc.). Moreover, some new morphologies are closely related to the improvement of traditional fillers, porous filler vs. glass particles, core-sheath fibrous vs. fibrous, etc. Some other new morphology fillers are combinations of traditional fillers, UHA vs. HA particles and fibrous, tetrapod-like whisker vs. whisker and fibrous filler, mesoporous silica vs. porous and silica particles. In this review, we give an overall description and a preliminary summary of the fillers, as well as our perspectives on the future direction of the development of novel fillers for next-generation DRCs.
To evaluate the influence of filler geometry and viscosity of luting composites on marginal adhesive gap width (MGW) and occlusal surface height (OSH) of all-ceramic partial crowns.
Forty-eight ...all-ceramic partial crowns (Celtra Duo, Dentsply) were created and divided into six groups (n = 8). Restorations were bonded using universal adhesive (Prime & Bond Active, Dentsply) in combination with low-viscosity composites (LV) containing amorphous fillers (Calibra Ceram, Dentsply) (LV-AF), heterogeneous fillers (Tetric EvoFlow, Ivoclar Vivadent) (LV-HF) vs. high-viscosity composites (HV) containing spherical fillers (Ceram.x, Dentsply) (HV-SF) or heterogeneous fillers (Tetric EvoCeram, Ivoclar Vivadent) (HV-HF). HV materials were used either with or without sonication. MGW µm was measured by SEM. Displacements of the restorations after luting, such as changes (Δ) in OSH µm, tilting and rotation °, were measured using a dial gauge and 3D-analytical software (OraCeck, Cyfex). Statistical analysis was by Mann-Whitney U-test and t-test with α = 0.05.
MGW (p = 0.002) and tilting (p = 0.001) were significantly smaller with LV (228.0 ± 112.35 µm; 0.89 ± 1.25°) than with HV (338.1 ± 97.26 µm; 1.95 ± 1.26°). Sonication had no effect on MGW in HV-HF (332.32 ± 91.39 µm) and HV-SF (343.85 ± 105.48 µm; p = 0.74). Sonication decreased ΔOSH by ~50% with HV-SF (64.21 ± 27.90 µm) but remained unchanged with HV-HF (39.06 ± 14.08 µm; p = 0.004). There was no difference in rotation between HV (0.82 ± 0.81°) and LV (0.61 ± 0.74°; p = 0.29). The LV-AF and LV-HF groups showed no statistical differences in MGW, ΔOSH, tilting or rotation (p > 0.05).
Irrespective of filler geometry and insertion technique, the use of high-viscosity composites for the adhesive cementation of modern all-ceramic partial crowns increases displacement, marginal misfit and occlusal surface height.
•Using high-viscosity composites for luting ceramic partial crowns causes marginal misfit•Viscosity of the luting material determines occlusal surface height after luting•Low-viscosity luting materials facilitate seating of ceramic partial crowns
Thermal management is critical to the performance, lifetime, and reliability of electronic devices. With the miniaturization, integration and functionalization of electronics and the emergence of new ...applications such as light emitting diodes, thermal dissipation becomes a challenging problem. Addressing this challenge requires the development of novel polymer-based composite materials with enhanced thermal conductivity. In this review, the fundamental design principles of highly thermally conductive composites were discussed. The key factors influencing the thermal conductivity of polymers, such as chain structure, crystallinity, crystal form, orientation of polymer chains, and orientation of ordered domains in both thermoplastics and thermosets were addressed. The properties of thermally conductive fillers (carbon nanotubes, metal particles, and ceramic particles such as boron nitride or aluminum oxide) are summarized at length. The dependence of thermal conductivity of composites on the filler loading, filler aggregate morphology and overall composite structure is also discussed. Special attention is paid to recent advances in controlling the microstructure of polymer composites to achieve high thermal conductivity (novel approaches to control filler orientation, special design of filler agglomerates, formation of continuous filler network by self-assembly process, double percolation approach, etc.). The review also summarizes some emerging applications of thermally conductive polymer composites. Finally, we outline the challenges and outlook for thermally conductive polymer composites.
Background
Treatment of a sunken appearance of the temporal region using injectable fillers is a popular procedure. The temporal fossa has very complex anatomy due to multiple vessels running in the ...different tissue layers. A severe complication in the form of non-thrombotic pulmonary embolism (NTPE) can occur as a result of an inadvertent injection in the middle temporal vein (MTV) while performing temporal fossa filler procedures. Therefore, in-depth knowledge and understanding of the MTV anatomy are essential for successful and safer injectable procedures of the temporal fossa.
Objectives
While there have been many studies to describe the arteries in this region, there is limited information about the location and course of the middle temporal vein. This literature review is aimed at providing detailed information about the course, depth, and size of the MTV to help aesthetic practitioners in performing safer temporal fossa filler injections. This information is imperative to delineate the ‘venous danger zone’ in the temple region.
Methods
The preferred reporting items for systematic reviews and meta-analyses guidelines were used for this review. A literature search was performed to find the articles providing details about the MTV anatomy and the measurements related to its course and size.
Results
A review of the literature showed that the MTV displays a consistent course and depth in the temporal region, with high variability in its diameter. The middle temporal vein width varied between 0.5 and 9.1 mm in various studies. The middle temporal vein receives many subfascial tributaries from the surface of the temporalis muscle, and for most of its course runs in the fat pad enclosed between superficial and deep layers of the deep temporal fascia. A ‘venous danger zone,’ in the interfascial planes of the temporal fossa, which contain the main part of the MTV and its tributaries, has been proposed in this paper.
Conclusions
The temporal fossa filler procedures need great caution, and knowledge of the depth and course of the MTV is essential for avoiding NTPE.
Level of Evidence III
This journal requires that authors assign a level of evidence to each article. For a full description of these Evidence-Based Medicine ratings, please refer to the Table of Contents or the online Instructions to Authors
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Biophysical and biochemical data on hyaluronan (HA)-based dermal fillers strongly support their optimal use and design to meet specific requisites. Here, four commercially available (in Europe) HA ..."volumetric" fillers, among the most used in the clinical practice, have been characterized in vitro. Analyses revealed the highest amounts of water-soluble HA reported so far and provided hydrodynamic data for these soluble polymeric fractions. Volumetric gels exhibit a wide range of rigidity with most of them showing G' values around 200-300Pa. They greatly differ in cohesivity. 1mL of gel hydrates up to 2.4-3.2mL. The products completely solubilize due to Bovine Testicular Hyaluronidase (BTH)'s action, thus predicting in vivo complete resorption. For the first time, filler degradation due to reactive oxygen species (ROS) was studied by rheological measurements and a rank in stability was established. Studies using Human Dermal Fibroblasts (HDF) indicated a positive biological response to the HA networks. Further, gel capacity to prompt collagen I, elastin and aquaporin3 synthesis was demonstrated, thus suggesting a positive effect on skin elasticity and hydration, besides the physical volumetric action. The findings are the first wide assessment of features for the volumetric class of HA-fillers and include first data on their resistance to degradation by ROS and biological effects on HDF. The study represents a valuable contribution to the understanding of HA-fillers, useful to optimize their use and manufacture.
In restorative dentistry, dental composites have become a popular material of choice due to the increasing aesthetic demands and address challenges like recurrent cavities and restorative bulk ...fracture, which are the most common causes of dental composite failure. To address these issues, various types and shapes of reinforcement fillers were researched to enhance the mechanical properties of composite formulations over conventional composites. Furthermore, antibacterial agents and ion-releasing fillers are used to prevent secondary caries and promote the remineralisation of dental tissue. This review article aims to review the literature of dental resin composites, focusing on various filler categories and their impact on the materials' performance, to aid future development of dental resin composites for clinical applications with optimal properties that can overcome current limitations.
Demand for non-surgical rejuvenating procedure is constantly increasing due to the aging population, increasing expense of aesthetics and beauty procedures, introduction of new applications and ...rising demand for noninvasive aesthetic procedures over surgical procedures. Skin necrosis is a rare but severe potential complication. It is caused by impediment of the blood supply to the skin area by compression and/or obstruction of the vessel with filler material, and/or direct injury to the vessel. We report the case of a young patient who presented an acute and severe complication after a dermal filler injection by an unlicensed therapist. High-dose corticosteroids i.v. therapy among others helped in the process of healing. Skin necrosis left the patient with a full thickness scar on the forehead region. Dermal fillers are to be considered safe only when handled by trained doctors.
Level of Evidence V
This journal requires that authors assign a level of evidence to each article. For a full description of these Evidence-Based Medicine ratings, please refer to the Table of Contents or the online Instructions to Authors
www.springer.com/00266
.