Polymer gels are the only viable class of synthetic materials with a Young's modulus below 100 kPa conforming to biological applications, yet those gel properties require a solvent fraction. The ...presence of a solvent can lead to phase separation, evaporation and leakage on deformation, diminishing gel elasticity and eliciting inflammatory responses in any surrounding tissues. Here, we report solvent-free, supersoft and superelastic polymer melts and networks prepared from bottlebrush macromolecules. The brush-like architecture expands the diameter of the polymer chains, diluting their entanglements without markedly increasing stiffness. This adjustable interplay between chain diameter and stiffness makes it possible to tailor the network's elastic modulus and extensibility without the complications associated with a swollen gel. The bottlebrush melts and elastomers exhibit an unprecedented combination of low modulus (∼100 Pa), high strain at break (∼1,000%), and extraordinary elasticity, properties that are on par with those of designer gels.
Halide perovskites are an intriguing class of materials that have recently attracted considerable attention for use as the active layer in thin film optoelectronic devices, including thin-film ...transistors, light-emitting devices, and solar cells. The “soft” nature of these materials, as characterized by their low formation energy and Young’s modulus, and high thermal expansion coefficients, not only enables thin films to be fabricated via low-temperature deposition methods but also presents rich opportunities for manipulating film formation. This comprehensive review explores how the unique chemistry of these materials can be exploited to tailor film growth processes and highlights the connections between processing methods and the resulting film characteristics. The discussion focuses principally on methylammonium lead iodide (CH3NH3PbI3 or MAPbI3), which serves as a useful and well-studied model system for examining the unique attributes of halide perovskites, but various other important members of this family are also considered. The resulting film properties are discussed in the context of the characteristics necessary for achieving high-performance optoelectronic devices and accurate measurement of physical properties.
Efforts to obtain high-strength graphene sheets by near-room-temperature assembly have been frustrated by the misalignment of graphene layers, which degrades mechanical properties. While in-plane ...stretching can decrease this misalignment, it reappears when releasing the stretch. Here we use covalent and π-π inter-platelet bridging to permanently freeze stretch-induced alignment of graphene sheets, and thereby increase isotropic in-plane sheet strength to 1.55 GPa, in combination with a high Young's modulus, electrical conductivity and weight-normalized shielding efficiency. Moreover, the stretch-bridged graphene sheets are scalable and can be easily bonded together using a commercial resin without appreciably decreasing the performance, which establishes the potential for practical applications.
We study in this paper the rheological requirements for printable concrete in terms of yield stress, viscosity, elastic modulus, critical strain, and structuration rate. We first discuss the ...extrusion/deposition process at the level of the nozzle from a material perspective. We then focus on the rheological requirements needed to prevent the flow of one layer or the strength-based failure of the rising printed element. We moreover discuss the rheological requirements needed to control the final geometrical dimensions of one layer and of the entire object, including buckling stability and surface cracking. We finally describe the requirement for a proper intermixing of the layers interface and also note that drying of the upper surface of the layer at rest could also play a major role on the interlayer bond. Finally, we evaluate the effect of the use of printing supports (i.e. non-direct printing) on the above rheological requirements.
Leveraging the elastic bodies of soft robots promises to enable the execution of dynamic motions as well as compliant and safe interaction with an unstructured environment. However, the exploitation ...of these abilities is constrained by the lack of appropriate control strategies. This work tackles for the first time the development of closed-loop dynamic controllers for a continuous soft robot. We present two architectures designed for dynamic trajectory tracking and surface following, respectively. Both controllers are designed to preserve the natural softness of the robot and adapt to interactions with an unstructured environment. The validity of the controllers is proven analytically within the hypotheses of the model. The controllers are evaluated through an extensive series of simulations, and through experiments on a physical soft robot capable of planar motions.
Amorphous materials inherit short- and medium-range order from the corresponding crystal and thus preserve some of its properties while still exhibiting novel properties
. Due to its important ...applications in technology, amorphous carbon with sp
or mixed sp
-sp
hybridization has been explored and prepared
, but synthesis of bulk amorphous carbon with sp
concentration close to 100% remains a challenge. Such materials inherit the short-/medium-range order of diamond and should also inherit its superior properties
. Here, we successfully synthesized millimetre-sized samples-with volumes 10
-10
times as large as produced in earlier studies-of transparent, nearly pure sp
amorphous carbon by heating fullerenes at pressures close to the cage collapse boundary. The material synthesized consists of many randomly oriented clusters with diamond-like short-/medium-range order and possesses the highest hardness (101.9 ± 2.3 GPa), elastic modulus (1,182 ± 40 GPa) and thermal conductivity (26.0 ± 1.3 W m
K
) observed in any known amorphous material. It also exhibits optical bandgaps tunable from 1.85 eV to 2.79 eV. These discoveries contribute to our knowledge about advanced amorphous materials and the synthesis of bulk amorphous materials by high-pressure and high-temperature techniques and may enable new applications for amorphous solids.
With increasing environmental and ecological concerns due to the use of petroleum-based chemicals and products, the synthesis of fine chemicals and functional materials from natural resources is of ...great public value. Nanocellulose may prove to be one of the most promising green materials of modern times due to its intrinsic properties, renewability, and abundance. In this review, we present nanocellulose-based materials from sourcing, synthesis, and surface modification of nanocellulose, to materials formation and applications. Nanocellulose can be sourced from biomass, plants, or bacteria, relying on fairly simple, scalable, and efficient isolation techniques. Mechanical, chemical, and enzymatic treatments, or a combination of these, can be used to extract nanocellulose from natural sources. The properties of nanocellulose are dependent on the source, the isolation technique, and potential subsequent surface transformations. Nanocellulose surface modification techniques are typically used to introduce either charged or hydrophobic moieties, and include amidation, esterification, etherification, silylation, polymerization, urethanization, sulfonation, and phosphorylation. Nanocellulose has excellent strength, high Young’s modulus, biocompatibility, and tunable self-assembly, thixotropic, and photonic properties, which are essential for the applications of this material. Nanocellulose participates in the fabrication of a large range of nanomaterials and nanocomposites, including those based on polymers, metals, metal oxides, and carbon. In particular, nanocellulose complements organic-based materials, where it imparts its mechanical properties to the composite. Nanocellulose is a promising material whenever material strength, flexibility, and/or specific nanostructuration are required. Applications include functional paper, optoelectronics, and antibacterial coatings, packaging, mechanically reinforced polymer composites, tissue scaffolds, drug delivery, biosensors, energy storage, catalysis, environmental remediation, and electrochemically controlled separation. Phosphorylated nanocellulose is a particularly interesting material, spanning a surprising set of applications in various dimensions including bone scaffolds, adsorbents, and flame retardants and as a support for the heterogenization of homogeneous catalysts.
•A series of compression and tensile tests for UHPC and Normal strength concrete was carried out.•The module elasticity and average compression and tensile strength of the materials were evaluated.•A ...calibrated Finite Element model using Concrete Damage Plasticity (CDP) was developed to predict the behavior of the UHPC.•Experimental and numerical results were compared and the effects of the mesh sizes were discussed.
Ultra-High Performance Concrete (UHPC) is an advanced technology in concrete industry with superior characteristics such as high strength in compression and tension, ductility, and durability. This paper determines the tensile and compressive behavior of UHPC and a comparison is made with Normal Strength Concrete (NC) for the development of a numerical model to simulate the behavior of UHPC using the Finite Element (FE). The experimental tests including a cylinder and cube compressive test, flexural, briquette and splitting tension tests to evaluate the ultimate capacity of the material in compression and tension and its modulus of elasticity. The primary focus of this research, however, was to simulate material properties of UHPC through commercial FE software allowing the study of the structures including UHPC. The numerical analysis provides the mechanical properties of UHPC that can be used in FE software using Concrete Damage Plasticity model (CDP) to define ductal UHPC in the absence of sufficient experimental data. The numerical and the experimental results were generally in good agreement.
•New methodology to determine static Modulus of Elasticity for mortar specimens.•This methodology is adapted from the standard used for concrete specimens.•Specimens made from either cement, ...hydraulic lime or air lime were tested.•Analyses on the ratios between static and dynamic Modulus of Elasticity values.•This methodology solves most of the experimental problems of mortar specimen’s tests.
The analysis and control of deformability of wall coating mortars contributes to minimize crack development and propagation, one of the most common anomalies in building facades. Many of these cracks appear due to internal stresses in the coating mortar, because of imposed deformations or of imposed restrictions by the substrate. These deformability studies should include one or more experimental methods to determine the modulus of elasticity (E) of the coating mortars in question.
There are two approaches to experimentally determine E for mortar specimens: static and dynamic experimental methodologies. For civil engineering applications, the results obtained from static methodologies are more adequate than those obtained with dynamic methodologies. However, since static E results are scarce due to a lack of an established static methodology for mortars, mainly due to their lower mechanical resistance, friable behaviour and higher frailty when compared to concrete, engineers are led to use the established dynamic methodologies.
This paper proposes an experimental methodology to determine the static E for moulded mortars specimens. The methodology was adapted from the standard procedure used for concrete specimens, to accommodate the specific characteristics of mortar specimens, namely: provide reliable displacement and applied load data; solve issue related to specific mechanical characteristics of mortar specimens, such as low strength and friable behaviour. This methodology was applied to standard moulded mortar specimens made from multiple mineral binders (cement, hydraulic lime and air lime). In order to validate it, the obtained results were compared with two, well-established, dynamic experimental methodologies (Resonance Frequency and Ultrasonic methodologies) as well as with reference values from relevant bibliography. Using the previous data, this paper also includes a preliminary analysis on the ratios between static and dynamic E values for the studied mortars, representing another objective of this study.
Lattice structures, which are also known as architected cellular structures, have been applied in various industrial sectors, owing to their fascinated performances, such as low elastic modulus, high ...stiffness-to-weight ratio, low thermal expansion coefficient, and large specific surface area. The lattice structures fabricated by conventional manufacturing technologies always involve complicated process control, additional assembly steps, or other uncontrollable factors. Furthermore, limited types of unit cells can be used to construct lattice structures when using conventional processes. Fortunately, additive manufacturing technology, based on a layer-by-layer process from computer-aided design models, demonstrates the unique capability and flexibility and provides an ideal platform in manufacturing complex components like lattice structures, resulting in an effective reduction in the processing time to actual application and minimum of material waste. Therefore, additive manufacturing relieves the constraint of structure design and provides accurate fabrication for lattice structures with good quality. This work systematically presents an overview of conventional manufacturing methods and novel additive manufacturing technologies for metallic lattice structures. Afterward, the design, optimization, a variety of properties, and applications of metallic lattice structures produced by additive manufacturing are elaborated. By summarizing state-of-the-art progress of the additively manufactured metallic lattice structures, limitations and future perspectives are also discussed.