Recycling water from municipal wastewater offers a reliable and sustainable solution to cities and regions facing shortage of water supply. Places including California and Singapore have developed ...advanced water reuse programs as an integral part of their water management strategy. Membrane technology, particularly reverse osmosis, has been playing a key role in producing high quality recycled water. This feature paper highlights the current status and future perspectives of advanced membrane processes to meet potable water reuse. Recent advances in membrane materials and process configurations are presented and opportunities and challenges are identified in the context of water reuse.
This study examined water quality, naturally-occurring radioactive materials (NORM), major ions, trace metals, and well flow data for water used and produced from start-up to operation of an oil and ...gas producing hydraulically-fractured well (horizontal) in the Denver-Julesburg (DJ) Basin in northeastern Colorado. Analysis was conducted on the groundwater used to make the fracturing fluid, the fracturing fluid itself, and nine flowback/produced water samples over 220days of operation. The chemical oxygen demand of the wastewater produced during operation decreased from 8200 to 2500mg/L, while the total dissolved solids (TDS) increased in this same period from 14,200 to roughly 19,000mg/L. NORM, trace metals, and major ion levels were generally correlated with TDS, and were lower than other shale basins (e.g. Marcellus and Bakken). Although at lower levels, the salinity and its origin appear to be the result of a similar mechanism to that of other shale basins when comparing Cl/Br, Na/Br, and Mg/Br ratios. Volumes of returned wastewater were low, with only 3% of the volume injected (11millionliters) returning as flowback by day 15 and 30% returning by day 220. Low levels of TDS indicate a potentially treatment-amenable wastewater, but low volumes of flowback could limit onsite reuse in the DJ Basin. These results offer insight into the temporal water quality changes in the days and months following flowback, along with considerations and implications for water reuse in future hydraulic fracturing or for environmental discharge.
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•Comparison of ground water, fracturing fluid, flowback, and produced water over time•TDS, metals, and anion data minimally changed over time in this DJ-Basin well.•COD declined overtime and only ~30% of the volume injected returned over the study.•Changing water quality impacts upon treatment and management were described.
Zero liquid discharge (ZLD)a wastewater management strategy that eliminates liquid waste and maximizes water usage efficiency has attracted renewed interest worldwide in recent years. Although ...implementation of ZLD reduces water pollution and augments water supply, the technology is constrained by high cost and intensive energy consumption. In this critical review, we discuss the drivers, incentives, technologies, and environmental impacts of ZLD. Within this framework, the global applications of ZLD in the United States and emerging economies such as China and India are examined. We highlight the evolution of ZLD from thermal- to membrane-based processes, and analyze the advantages and limitations of existing and emerging ZLD technologies. The potential environmental impacts of ZLD, notably greenhouse gas emission and generation of solid waste, are discussed and the prospects of ZLD technologies and research needs are highlighted.
The IWA Publishing journals Water Reuse and Water Science and Technology have been successfully enrolled in the catalog of high-quality journals in the field of environmental science in China. The ...catalog was organized by the China Association for Science and Technology. After a rigorous procedure of selection, evaluation, publicity, and review by the expert panel led by the Chinese Society for Environmental Sciences, 161 journals (including 115 English journals and 46 Chinese journals) were finally enrolled in the catalog.
This paper investigates the potential of graphene-coated sand (GCS) as an advanced filtration medium for improving water quality and mitigating chemicals of emerging concern (CECs) in treated ...municipal wastewater, aiming to enhance water reuse. The study utilizes three types of sand (Ottawa, masonry, and concrete) coated with graphene to assess the impact of surface morphology, particle shape, and chemical composition on coating and filtration efficiency. Additionally, sand coated with graphene and activated graphene coated sand were both tested to understand the effect of coating and activation on the filtration process. The materials were characterized using digital microscopy, Raman spectroscopy, scanning electron microscopy (SEM), and X-ray diffraction analysis. The material's efficiency in removing turbidity, nutrients, chemical oxygen demand (COD), bacteria, and specific CECs (Aciclovir, Diatrizoic acid, Levodopa, Miconazole, Carbamazepine, Diphenhydramine, Irbesartan, Lidocaine, Losartan, and Sulfamethoxazole) was studied. Our findings indicate that GCS significantly improves water quality parameters, with notable efficiency in removing turbidity, COD (14.1 % and 69.1 % removal), and bacterial contaminants (64.9 % and 99.9 % removal). The study also highlights the material's capacity to remove challenging CECs like Sulfamethoxazole (up to 80 % removal) and Diphenhydramine (up to 90 % removal), showcasing its potential as a sustainable solution for water reuse applications. This research contributes to the field by providing a comprehensive evaluation of GCS in water treatment, suggesting its potential for removing CECs from treated municipal wastewater.
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•Graphene Coated Sand (GCS) as filtration material to enhance water reuse•Effect of particle's shape and composition on GCS coating efficiency•GCS's activation improves its treatment capabilities by at least 10 %.•GCS's ability to remove turbidity, and bacteria (∼85 %)•Improved removal of Sulfamethoxazole and Diphenhydramine (80 & 90 %)
Although granular activated carbon (GAC) has been broadly applied in ozone-biologically activated carbon filtration (O3/BAC) systems for potable reuse of municipal wastewater, the mechanisms of ...various pollutant removal remain largely unknown as the regenerated GAC develops microbial populations resulting in biofiltration but loses significant adsorption capacity as it becomes spent GAC. Therefore, pilot-scale parallel performance comparisons of spent and regenerated GAC, along with a range of pre-oxidant ozone doses, were used to shed light on the mechanisms responsible for the removal of various types of treatment byproduct precursors and trace organic compounds. It was confirmed from this pilot-study that ozone alone can effectively degrade chlorinated trihalomethane (THM) and haloacetic acid (HAA) precursors, chloramine-reactive N-nitrosodimethylamine (NDMA) precursors, and 29 PPCPs. In contrast, biodegradation by microbial population on spent or regenerated GAC can remove NDMA and 22 PPCPs, while the adsorption by regenerated GAC can remove chlorinated THM and HAA precursors, PFAS, flame retardants, and 27 PPCPs. The results of this pilot study are intended to provide those interested in potable reuse with an example of the simultaneous removal capabilities and mechanisms that can be anticipated for treating a complex mixture of organics present in real municipal wastewater effluent.
•Roles of spent and regenerated GAC were for the first time compared.•Pathways for the removal of a wide spectrum of compounds were identified.•Biodegradation can remove NDMA and 22 PPCPs.•Adsorption can remove THM and HAA precursors, PFAS, flame retardants, and 27 PPCPs.•Ozone can remove THM, HAA, chloramine-reactive NDMA precursors, and 29 PPCPs.
During the production of high quality recycled water by reverse osmosis membrane filtration secondary effluent must be disinfected to limit biofouling on the membrane surface. Advanced Water ...Treatment Plants in South East Queensland, Australia use disinfectant contact times ranging from 30 min up to 24 h. Disinfectants such as chlorine and chloramines react with effluent organic matter to generate disinfection by-products (DBPs) which could be potentially hazardous to human health if the water is destined for supplementing public water supplies. In this context, secondary effluents are of concern because of their high total organic carbon content which can act as DBP precursors. Also, effluent organic matter may form different DBPs to those formed from natural organic matter during conventional drinking water treatment, either in quantity, identity or simply in the abundance of different DBPs relative to each other. It cannot be assumed per se with certainty that DBP formation will be affected in the same way by operational changes as in drinking water production.
Response surface modelling has been employed in this study at the bench scale to investigate the effect of reaction time (0–24 h), pH (5.5–8.5), temperature (23–35 °C), disinfection strategy (chlorine vs chloramines used prior to membrane treatment) and the interaction between these different parameters on DBP formation during disinfection of secondary effluent.
The concentration of halogenated DBPs formed during the first 24 h of reaction with the different disinfectants followed the order chlorination >> in line-formed monochloramine > pre-formed monochloramine. Contact time with chlorine was the major influencing factor on DBP formation during chlorination, except for the bromine-containing trihalomethanes and dibromoacetonitrile for which pH was more significant. Chlorination at high pH led to an increased formation of chloral hydrate, trichloronitromethane, dibromoacetonitrile and the four trihalomethanes while the opposite effect was observed for the other targeted DBPs. Temperature was identified as the least influencing parameter compared to pH and reaction time for all DBPs in all the disinfection strategies, except for the formation of chloral hydrate where pH and temperature had a similar significance and bromoform that was similarly affected by temperature and reaction time. Chloramines employed at pH 8.5 reduced the concentration of all studied DBPs compared to pH 5.5. Furthermore, reaction time was the most significant factor for trichloronitromethane, chloroform, trichloroacetonitrile, dichloroacetonitrile and bromochloroacetonitrile formation while pH was the most influencing factor affecting the formation of the remaining DBPs.
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•Formation of trihalomethanes, haloacetonitriles, haloketones, trichloronitromethane, and chloral hydrate was investigated.•Significant DBP formation is expected from disinfection of secondary effluent.•Reaction time and pH are both identified as significant factors during chlorination and chloramination.•Temperature is the least influencing parameter compared to pH and reaction time.
Recycled water has been widely recognized in the world as an effective approach to relieve the issue of water shortage. Meanwhile, with several decades of development, the insufficiency of technology ...is no longer the primary factor that restricts the popularization of recycled water. What makes it difficult to promote the concept of reusing recycled water in China? To solve this issue, a special experiment on the public’s attitude towards the reuse of recycled water was designed based on a Single Category Implicit Association Test (SC-IAT), so as to avoid factors like social preference that can influence the survey results, and to gain the public’s negative implicit attitude towards reusing recycled water reuse, which is close to the public’s real attitude to it. From the perspective of implicit attitude, this research testifies the “spiritual contagion” phenomenon of the public, which refers to refusing recycled water reuse because recycled water is made from sewage treatment. By comparing the implicit attitude to recycled water reuse with the explicit attitude that is acquired from self-reporting questionnaires about reusing recycled water, this research finds that the implicit attitude is more positive than the explicit attitude, which accounts for the phenomenon of “best game no one played” in the promotion of the recycled water reuse, that is, the public though applauding the environment-friendly policy, will not actually use the recycled water.
Approximately, seventy (70) percent of world water use including all the water diverted from rivers and pumped from underground is used for agricultural irrigation, so that the reuse of treated ...municipal wastewater for purposes such as agricultural and landscape irrigation reduces the amount of water that needs to be extracted from natural water sources as well as reducing discharge of wastewater to the environment. Thus, treated municipal wastewater is a valuable water source for recycling and reuse in the Mediterranean countries and other arid and semi-arid regions which are confronting increasing water shortages. Treated wastewater reuse in agriculture is a common practice in the Mediterranean countries and there is a considerable interest in the long-term effects of treated wastewater on crops intended for human consumption. This paper reviews the fundamentals of agricultural irrigation using treated municipal wastewater and the status of municipal wastewater reuse in Greece and Spain with studies related to the effects on soils and plants.
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