Photocatalytic Hydroacylation of Alkenes by Directly Using Acyl Oximes

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Photocatalytic Hydroacylation of Alkenes by Directly Using Acyl Oximes

Zheng, Lan; Xia, Peng-Ju; Zhao, Qing-Lan; Qian, Yu-En; Jiang, Wen-Nian; Xiang, Hao-Yue; Yang, Hua

Journal of organic chemistry, 09/2020, Volume: 85, Issue: 18

Journal Article

Acyl oximes are directly used as the acyl radical precursors in the hydroacylation reactions for the first time. In this work, acyl radicals can be effectively generated via β-scission of a phosphoranyl radical under photocatalytic conditions. As a result, the hydroacylation of alkenes triggered by the resulting acyl radicals leads to facile syntheses of a range of valuable ketones.

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