Aerobic α‐Oxidation of N‐Substituted Tetrahydroisoquinolines to Dihydroisoquinolones via Organo‐photocatalysis

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Aerobic α‐Oxidation of N‐Substituted Tetrahydroisoquinolines to Dihydroisoquinolones via Organo‐photocatalysis

Aganda, Kim Christopher C.; Hong, Boseok; Lee, Anna

Advanced synthesis & catalysis, March 5, 2019, Volume: 361, Issue: 5

Journal Article

An efficient visible‐light‐induced α‐oxidation of N‐substituted tetrahydroisoquinolines to dihydroisoquinolones has been developed using eosin Y as an organo‐photocatalyst and oxygen as a green oxidant. The reactions were carried out under mild reaction conditions; the desired dihydroisoquinolones were obtained in up to 96% yield at room temperature under oxygen atmosphere. This transformation provides a convenient route to dihydroisoquinolones with a wide range of substrates.

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Aganda, Kim Christopher C. | Hong, Boseok | Lee, Anna

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