Tin Phosphide as a Promising Anode Material for Na-Ion Batteries

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Tin Phosphide as a Promising Anode Material for Na-Ion Batteries

Kim, Youngjin; Kim, Yongil; Choi, Aram; Woo, Sangwon; Mok, Duckgyun; Choi, Nam-Soon; Jung, Yoon Seok; Ryu, Ji Heon; Oh, Seung M.; Lee, Kyu Tae

Advanced materials (Weinheim), June 25, 2014, Volume: 26, Issue: 24

Journal Article

Sn4P3 is introduced for the first time as an anode material for Na‐ion batteries. Sn4P3 delivers a high reversible capacity of 718 mA h g−1, and shows very stable cycle performance with negligible capacity fading over 100 cycles, which is attributed to the confinement effect of Sn nanocrystallites in the amorphous phosphorus matrix during cycling.

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