In the field of organic light‐emitting diodes, organo‐boron based thermally activated delayed fluorescence (TADF) emitters have witnessed outstanding achievements. However, it is still challenging to achieve pure blue color (CIE y < 0.20) along with high efficiencies. To overcome these hurdles, the hyperfluorescence (HF) system suggests a key strategy for future display applications. Here, two TADF host materials, pMDBA‐DI and mMDBA‐DI, and a pure blue multi‐resonance type tert‐butyl substituted TADF fluorescence emitter t‐Bu‐ν‐DABNA are reported, for efficient HF devices. Among the synthesized TADF sensitized host materials, the mMDBA‐DI HF device exhibits a high external quantum efficiency of 39.1% along with narrow emission with full width at half maximum of 19 nm (CIE y = 0.15). The high device efficiency is mainly attributed to the high molecular orientation factor, enhanced photoluminescence quantum yield, and a good TADF characteristic of t‐Bu‐ν‐DABNA with efficient Förster energy transfer. By using organo‐boron based emitters, an excellent hyperfluorescence (HF) OLED system is designed. As a result, a high external quantum efficiency (EQE) of over 40% and pure blue color with a CIE y coordinate of 0.15 are achieved. Further, a long lifetime (LT50) of 440 h with the designed HF systems is reached. Additionally, the detailed parameters for such high EQE values are analyzed.