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Arrowsmith, Merle; Braunschweig, Holger; Stennett, Tom E.
Angewandte Chemie, January 2, 2017, Volume: 56, Issue: 1Journal Article
Recent years have seen rapid advances in the chemistry of small molecules containing electron‐precise boron–boron bonds. This Review provides an overview of the latest methods for the controlled synthesis of B−B single and multiple bonds as well as the ever‐expanding range of reactivity displayed by B−B multiple bonds. B, B bonding: The chemistry of boron–boron bond containing compounds has seen rapid advances in recent years. This Review provides a comprehensive overview of the historical background, the increasingly varied and selective methods for the synthesis of electron‐precise B–B single and multiple bonds, and their ever‐expanding range of reactivity.
